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材料导报  2024, Vol. 38 Issue (17): 23060044-9    https://doi.org/10.11896/cldb.23060044
  高分子与聚合物基复合材料 |
螺吡喃类刺激响应变色聚合物的研究进展
鲍艳1,2,*, 韩旆1,2, 张文博3,*, 刘锋4, 高璐1,2, 马建中1
1 陕西科技大学轻工科学与工程学院,西安 710021
2 陕西科技大学轻化工程国家级实验教学示范中心,西安 710021
3 陕西科技大学陕西省轻化工助剂化学与技术协同创新中心,西安 710021
4 杭州棕榈地科技开发有限公司,杭州 311215
Research Progress of Spiropyrans Stimuli-responsive Chromotropic Polymers
BAO Yan1,2,*, HAN Pei1,2, ZHANG Wenbo3,*, LIU Feng4, GAO Lu1,2, MA Jianzhong1
1 College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China
2 National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science and Technology, Xi'an 710021, China
3 Key laboratory of the Ministry of Education of Industrial Auxiliary Chemistry & Technology, Shaanxi University of Science and Technology, Xi'an 710021, China
4 Hangzhou Palmland Technology Development Co., Ltd., Hangzhou 311215, China
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摘要 螺吡喃是一类可以对各种外部刺激做出反应而表现出不同性质的化合物。这些刺激可以是物理的、化学的或生物的,它们会导致螺吡喃化合物的结构、形状和性质发生变化。螺吡喃具有两个异构体:闭环的螺吡喃结构(SP)和开环的部花菁结构(MC)。螺吡喃化合物因结构简单、易于修饰和能够对多种刺激做出反应的优点,被广泛应用于制备刺激响应型聚合物和化学传感器。这些聚合物和传感器可应用于各个领域,如建筑、变色织物、光学防伪和离子检测等。本文综述了螺吡喃的合成途径,包括传统的三步合成法、一锅法以及较新的超声和微波合成法,还对螺吡喃聚合物的光致变色、机械力致变色、溶剂致变色、酸致变色、压致变色和热致变色等进行了综述,详细讨论了这些性质的机理、影响因素和实际应用。最后,展望了螺吡喃在设计和开发新型刺激响应材料和化学传感器领域的前景。
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鲍艳
韩旆
张文博
刘锋
高璐
马建中
关键词:  刺激响应聚合物  螺吡喃  光致变色  机械力致变色  化学传感器    
Abstract: Spiropyrane, a class of compounds, displays diverse properties in response to a range of external stimuli encompassing physical, chemical, and biological factors. These stimuli induce changes in the structure, shape, and properties of spiropyran compounds. Within the spiropyran category, two isomers exist, namely a closed-loop spiropyran structure (SP) and an open-loop paroxycyanine structure (MC). Due to their uncomplicated structure, facile modification, and responsiveness to different stimuli, spiropyran compounds find extensive utility in the fabrication of stimuli-responsive polymers and chemical sensors. These versatile polymers and sensors have applications in various domains including construction, color-changing textiles, optical security, and ion detection. This paper presents a comprehensive review of the synthesis pathways employed for spiropyran compounds. The traditional three-step synthesis, one-pot synthesis, as well as newer techniques such as ultrasonic and microwave synthesis, are discussed. Furthermore, the paper delves into an examination of the photochromic, mechanochromic, solvatochromic, acidochromic, pressure chromism, and thermochromism exhibited by spiropyran polymers. The mechanism underlying these phenomena, factors influencing their manifestation, and practical applications are thoroughly discussed. Finally, the paper provides an outlook on the potential of spiropyran in the design and development of novel stimuli-response materials and chemical sensors.
Key words:  stimuli-responsive polymers    spiropyran    photochromic    mechanochromism    chemical sensor
出版日期:  2024-09-10      发布日期:  2024-09-30
ZTFLH:  O62  
基金资助: 国家自然科学基金(22378253,22078188);咸阳市科技计划项目(2021ZDZX-GY-0007)
通讯作者:  *鲍艳,二级教授,博士研究生导师,享受国务院政府特殊津贴。长期从事有机/无机纳米复合功能化学品的研究。先后入选国家特殊人才支持计划青年人才、国家级百千万人才工程、教育部新世纪优秀人才支持计划、陕西省“特支计划”青年拔尖人才等人才项目,获国家有突出贡献的中青年专家、全国五一巾帼奖状等多项荣誉称号。作为负责人先后承担各类纵向科研项目21项,包括国家重点研发计划子课题、国家自然科学基金面上项目等;以第一/通信作者在Advanced Functional Materials、Advances in Colloid and Interface Science、Journal of Cleaner Production、ACS Applied Materials & Interfaces、《高等学校化学学报》等国内外重要刊物发表学术论文150余篇,授权国家发明专利58件,修制定国家标准2项;研究成果获国家技术发明奖、国家科技进步奖等省部级以上科研奖励25项。baoyan@sust.edu.cn;
张文博,副教授,硕士研究生导师,入选陕西高校“青年杰出人才支持计划”,陕西科技大学前沿科学与技术转移研究院协同中心办公室主任。主要研究方向为功能性复合涂层材料、石墨烯基光催化材料、胶原纤维柔性传感器等。主持国家自然科学基金、政府间科技交流项目、陕西省重点研发计划等项目10余项;以第一作者或通信作者发表学术论文30余篇;授权国家发明专利6件、德国发明专利1件;开发3种新型涂料印花粘合剂、油田堵剂等精细化学品并实现产业化生产。zhangwenbo@sust.edu.cn   
引用本文:    
鲍艳, 韩旆, 张文博, 刘锋, 高璐, 马建中. 螺吡喃类刺激响应变色聚合物的研究进展[J]. 材料导报, 2024, 38(17): 23060044-9.
BAO Yan, HAN Pei, ZHANG Wenbo, LIU Feng, GAO Lu, MA Jianzhong. Research Progress of Spiropyrans Stimuli-responsive Chromotropic Polymers. Materials Reports, 2024, 38(17): 23060044-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23060044  或          http://www.mater-rep.com/CN/Y2024/V38/I17/23060044
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