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材料导报  2022, Vol. 36 Issue (Z1): 22030070-5    
  高分子与聚合物基复合材料 |
基于RAFT调控的聚合诱导自组装研究进展
张壹霖, 腾凡, 高庆, 杨婷婷
湖北大学材料科学与工程学院,湖北省高分子材料重点实验室, 武汉 430062
Research and Development of RAFT-Mediated Polymerization Induced Self-Assembly
ZHANG Yilin, TENG Fan, GAO Qing, YANG Tingting
Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, China
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摘要 可逆加成-断裂链转移(Reversible addition-fragmentation chain transfer,RAFT)聚合被认为是最有效和最具工业化应用前景的可控自由基聚合方法之一。目前基于RAFT调控的聚合诱导自组装(Polymerization induced self-assembly, PISA)技术已成功制备出各种形貌(球形、蠕虫状、棒状、囊泡等)、尺寸(纳米、亚微米)和功能负载的嵌段共聚物纳米颗粒,本文总结了采用不同引发方式介导的RAFT调控PISA技术的应用研究进展,并展望了PISA的未来发展。
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张壹霖
腾凡
高庆
杨婷婷
关键词:  可逆加成-断裂链转移  聚合诱导自组装  引发方式  嵌段共聚物  纳米颗粒    
Abstract: Reversible addition-fragmentation chain transfer (RAFT) polymerization is considered as one of the most effective and promising methods for controllable radical polymerization. Recently, polymerization induced self-assembly has been used to prepare block copolymer nanoparticles of various morphologies (spheres, worms, rods, vesicles, etc.), sizes (nano, submicaron) and functional loadings via RAFT polymerization methods. The research and development of RAFT-mediated PISA under different initiation condition were reviewed, and the broad prospects were prospected.
Key words:  reversible addition-fragmentation chain transfer    polymerization induced self-assembly (PISA)    initiation method    block copolymer    nanoparticles
出版日期:  2022-06-05      发布日期:  2022-06-08
ZTFLH:  TQ316.2  
通讯作者:  tingting.yang@hubu.edu.cn   
作者简介:  张壹霖,2019年6月毕业于湖南人文科技学院,获得工学学士学位。现为湖北大学材料科学与工程学院研究生,在杨婷婷教授的指导下进行研究,目前主要研究领域为硅基复合纳米颗粒的可控制备。
杨婷婷,湖北大学材料科学与工程学院教授,硕士研究生导师。2007年湖北大学材料学博士毕业,留校任教至今,目前主要从事复杂结构高分子的可控制备和硅基纳米结构的基础研究。
引用本文:    
张壹霖, 腾凡, 高庆, 杨婷婷. 基于RAFT调控的聚合诱导自组装研究进展[J]. 材料导报, 2022, 36(Z1): 22030070-5.
ZHANG Yilin, TENG Fan, GAO Qing, YANG Tingting. Research and Development of RAFT-Mediated Polymerization Induced Self-Assembly. Materials Reports, 2022, 36(Z1): 22030070-5.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2022/V36/IZ1/22030070
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