材料导报 2022, Vol. 36 Issue (Z1): 21100088-6
高分子与聚合物基复合材料
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长碳链聚酰胺PA1012的改性研究进展
张子健1,2 , 姜锋1,2 , 于春晓2
1 东华大学材料科学与工程学院,上海 201620 2 中国纺织科学研究院有限公司生物源纤维制造技术国家重点实验室,北京 100025
Research Progress on Modification of Long Carbon Chain Polyamide 1012
ZHANG Zijian1,2 , JIANG Feng1,2 , YU Chunxiao2
1 College of Materials Science and Engineering, Donghua University, Shanghai 201620, China 2 State Key Laboratory of Biobased Fiber Manufacturing Technolegy, China Textile Academy, Beijing 100025, China
摘要 作为一种长碳链聚酰胺,PA1012具有较长的相邻亚甲基链段和相对较低的酰胺键及氢键的密度,因而在宏观性能上表现出韧性好、结晶度低、熔点低等特点。国外起步较早,阿克玛、德国赢创公司等是国外的主要生产企业,而国内生产厂商不多,且关于原料、聚合改性的方面所披露的研究较少。本文综述了国内外利用共混和共聚改性PA1012的相关研究,分析了共混成分、配比对改性PA1012的力学、结晶等性能的影响。最后,针对此领域亟待解决的问题进行了总结,并对未来的发展提出了一些思路和建议。
关键词:
长碳链聚酰胺
PA1012
改性
柔性链段
Abstract: As a long carbon chain polyamide, PA1012 has long adjacent methylene chain segments and relatively low density of amide bond and hydrogen bond, so it has the characteristics of good toughness, low crystallinity and low melting point. Akma and Evonik are major foreign manufacturers, while there are few domestic manufacturers, as well as few studies on raw materials and polymerization modification. In this paper, the related studies on the modification of PA1012 by blending and copolymerization at home and abroad are reviewed, and the effects of blending composition and ratio on the mechanical and crystallization properties of modified PA1012 are analyzed. Finally, the problems to be solved in this field have been summarized, and some ideas and suggestions for future development have been put forward.
Key words:
long-carbon chain polyamide
polyamide 1012
modification
flexibility chain segment
出版日期: 2022-06-05
发布日期: 2022-06-08
通讯作者:
joinfun2005@sina.com.cn
作者简介: 张子健,2020年毕业于东华大学,获得工学学士学位,现为东华大学和中国纺织科学研究院联合培养硕士研究生,在姜峰博士的指导下进行研究。目前主要研究方向为共聚酰胺6/1012和共聚酰胺MXD6/6的制备以及性能表征。 姜峰,从事高性能纤维结构性能表征及新一代聚己内酰胺材料工程技术领域的研究。主持和作为主要完成人完成国家、省部级、企业研究项目8项。发表论文21篇,其中SCI/EI收录5篇,中文核心8篇;获授权发明专利16项,制订2项企业标准。
1 Wang Y D, Zhao Q X, Liu M Y, et al. Journal of Applied Polymer Science, 2005, 98(4), 1643. 2 李馥梅. 化工新型材料, 2006(12), 6. 3 何曼君. 高分子物理, 复旦大学出版社, 2005, pp.114. 4 Bartmann M, Gude A, Droscher M, et al. EP patent, EP297245-A, 1989. 5 李勇进, 颜德岳, 朱新远, 等. 高等学校化学学报, 2000(6), 983. 6 王百木. 塑料科技, 2010, 38(3), 61. 7 李闻达, 张传辉, 肖中鹏, 等. 塑料工业, 2014, 42(11), 5. 8 万丽华, 翁志学, 黄志明, 等. 化工学报, 2004(1), 106. 9 王玉东, 刘民英, 赵清香, 等. 工程塑料应用, 2001(1), 1. 10 许冬峰, 冯新星, 张卫东, 等. 中国塑料, 2019, 33(3), 17. 11 罗玉航. 共聚酰胺6/66的制备及性能研究. 硕士学位论文, 湖南师范大学, 2017. 12 Li X H, He Y C, Dong X, et al. Polymer , 2020, 189(10), 122165. 13 苏成晓, 王道波, 张传辉, 等. 工程塑料应用, 2019, 47(11), 105. 14 李树新, 田国锋, 王朝进, 等. 中国专利, CN108003613A, 2020. 15 董侠, 朱平, 王笃金, 等. 中国专利, CN105566639A, 2016. 16 Zhu P, Dong X, Cao Y Y, et al. European Polymer Journal , 2017, 93, 334. 17 曹诣宇. 长碳链聚酰胺-聚醚多嵌段共聚物的结晶. 硕士学位论文, 中国科学院大学, 2018. 18 Wang Y, Zhu P, Lai Y, et al. Polymer, 2021, 225, 123802. 19 朱平. 长碳链聚酰胺-聚醚嵌段共聚物:合成与结构性能关系研究. 博士学位论文, 中国科学院大学, 2017. 20 Alvarez-Lainez M L, Palacio R J A, et al. Wear , 2017, 372-373, 76. 21 Wang B B,Hu G S, Zhao X. Materials Letters , 2006, 60(21-22), 2715. 22 Zierdt P, Mitzner E, Gomoll A, et al. Journal of Applied Polymer Science , 2016, 133(46), 44155. 23 Rwei S P, Tseng Y C, Chiu K C, et al. Thermochimica Acta , 2013, 55, 37. 24 Wang L L, Dong X, Wang X R, et al. Chinese Journal of Polymer Science , 2016, 38(8), 991. 25 Wu Z, Zhou C, Qi R, et al. Journal of Applied Polymer Science , 2010, 83(11), 2403. 26 Rui Y, Chen F, Iqbal M I, et al. Journal of Fiber Bioengineering and Informatics , 2018, 11(1), 41. 27 Song J, Liu J, Zhang Y, et al. Journal of Composite Materials , 2015, 49(4), 415. 28 戴军, 金惠明. 中国专利, CN100387654C, 2006. 29 许彦冰, 陈学进, 林俊澍, 等. 塑料工业, 2016, 44(11), 37. 30 陈学进, 吕广超, 许彦冰, 等. 塑料工业, 2016, 44(10), 26. 31 景新阳, 于元章. 塑料工业, 2016, 44(10), 14. 32 景新阳, 于元章. 塑料工业, 2016, 44(9), 112. 33 丁超, 梁惠强, 陈勇文, 等. 塑料工业, 2014, 42(5), 46. 34 周云霞. ACR-g-GMA增韧PA1012及其性能研究. 硕士学位论文, 长春工业大学, 2015. 35 汪永伟, 王玉东, 赵清香,等. 塑料工业, 2008, 4(1), 57. 36 胡三友. PA1212、PA1012增韧复合材料的制备及性能研究. 硕士学位论文, 郑州大学, 2014. 37 Zhou C Zhu P, Liu X, et al. Composites Part B Engineering , 2020, 206, 108539. 38 戴军, 金惠明, 任进科, 等. 中国专利, CN1502660A, 2004.
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