非贵金属催化剂催化硼氢化钠水解制氢的研究进展

材料导报

2021, Vol. 35

Issue (Z1): 21-28

无机非金属及其复合材料

非贵金属催化剂催化硼氢化钠水解制氢的研究进展

王小炼¹, 杨茂¹, 刘永辉¹, 张渝彬², 冯威¹

1 成都大学机械工程学院,成都 610106
2 成都工业学院自动化与电气工程学院,成都 611730

Research Progress of Hydrogen Production by Hydrolysis of Sodium Borohydride Catalyzed by Non-Noble Metal Catalysts

WANG Xiaolian¹, YANG Mao¹, LIU Yonghui¹, ZHANG Yubin², FENG Wei¹

1 School of Mechanical Engineering, Chengdu University, Chengdu 610106, China
2 School of Automation and Electrical Engineering, Chengdu Technological University, Chengdu 611730, China

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摘要硼氢化钠水解制氢具有安全方便、放氢温度适中、反应易于控制和制氢纯度高等优点,现已成为制氢技术中的研究热点。但纯硼氢化钠水解放氢速率缓慢、产氢率低,常需添加合适的催化剂以改善硼氢化钠水解的放氢速率。金属催化剂因其具有高的催化活性已被广泛研究。其中,贵金属由于价格昂贵限制了它们的使用,而非贵金属价格低且储量高。并且,近年来有研究发现某些非贵金属催化剂的催化活性有了显著提高。因此,从经济角度出发考虑,将非贵金属用于催化硼氢化钠水解制氢是非常可取的。本文结合近几年国内外非贵金属催化剂催化硼氢化钠水解的发展现状,介绍了非负载型催化剂和负载型催化剂的研究进展,并对其未来的发展趋势进行了展望。

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关键词: 催化剂非贵金属水解制氢硼氢化钠

Abstract: Hydrogen production by hydrolysis of sodium borohydride has the advantages of safety and convenience, moderate hydrogen release temperature, easy control of the reaction, and high purity of hydrogen production. It has become a research hotspot in hydrogen production technology. Hydrogen production speed of pure sodium borohydride hydrolysis is slow and the hydrogen production rate is low. Suitable catalysts are often added to improve the rate of hydrogen liberation from sodium borohydride hydrolysis. Metal catalysts have been widely studied because of their high catalytic activity. Among them, noble metals limit their use due to their high prices, while non-noble metals are low in price and high in reserves. Moreover, in recent years, studies have found that the catalytic activity of some non-noble metal catalysts has been significantly improved. Therefore, from an economic point of view, it is highly desirable to use non-noble metals to catalyze the hydrolysis of sodium borohydride to produce hydrogen. In this paper, the research progress of unsupported catalysts and supported catalysts was introduced based on the development status of non-noble metal catalysts for hydrolysis of sodium borohydride at home and abroad in recent years, and its future development trend was prospected.

Key words: catalyst non-noble metals hydrolysis hydrogen production sodium borohydride

发布日期: 2021-07-16

ZTFLH:	O643.36
	TQ116.2

基金资助: 四川省教育厅(18ZB0133);四川省粉末冶金工程技术研究中心(SC-FMYJ2018-05);四川省应用基础研究计划(2018JY0062);成都大学研究项目(2018XZB17)资助

通讯作者: wangxiaolian@cdu.edu.cn

作者简介: 王小炼,成都大学机械工程学院讲师。2016年6月在四川大学材料科学与工程学院取得材料学专业博士学位。目前主要从事氢能与燃料电池技术、粉末冶金材料和量子化学计算的研究工作。主持和参加国家级和省部级科研项目多项,在International Journal of Hydrogen Energy、Journal of Power Sources和Acta Physica Sinica等刊物发表论文10余篇。杨茂,2020年6月毕业于成都大学,获得工学学士学位。现为成都大学机械工程学院硕士研究生,在王小炼老师的指导下进行研究。目前主要研究领域为化学储氢材料。

引用本文:

王小炼, 杨茂, 刘永辉, 张渝彬, 冯威. 非贵金属催化剂催化硼氢化钠水解制氢的研究进展[J]. 材料导报, 2021, 35(Z1): 21-28.
WANG Xiaolian, YANG Mao, LIU Yonghui, ZHANG Yubin, FENG Wei. Research Progress of Hydrogen Production by Hydrolysis of Sodium Borohydride Catalyzed by Non-Noble Metal Catalysts. Materials Reports, 2021, 35(Z1): 21-28.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/IZ1/21

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