废弃高抗冲聚苯乙烯高值化再利用的研究进展

材料导报

2020, Vol. 34

Issue (Z1): 557-562

高分子与聚合物基复合材料

废弃高抗冲聚苯乙烯高值化再利用的研究进展

张通姗¹, 徐海萍¹, 徐世豪¹, 廖杨科¹, 熊维²

1 上海第二工业大学工学部环境与材料学院,上海 201209;
2 上海睿莫环保新材料有限公司,上海 201209

Research Progress on High Value Reuse of Waste High Impact Polystyrene

ZHANG Tongshan¹, XU Haiping¹, XU Shihao¹, LIAO Yangke¹, XIONG Wei²

1 School of Environment and Materials, Ministry of Engineering, University of Polytechnic Shanghai, Shanghai 201209, China;
2 Shanghai Re-mall Environmental New Material Co., Ltd., Shanghai 201209, China

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摘要高抗冲聚苯乙烯(HIPS)以其优异的力学性能在高分子塑料领域发挥着重要作用,短短数年内其生产量已直逼传统的丙烯腈-丁二烯-苯乙烯共聚物(ABS)聚合物树脂。作为一类优异的聚合物树脂材料,HIPS在工程(特别是电器和计算机)材料领域表现出巨大的优势:具有良好的尺寸稳定性;耐热性强,具有良好的冲击韧性强度;易加工,可以通过添加合适的填料来开发新型功能型材料等。
然而,基于科技创新化发展,电子产品的发展日新月异,塑料材料的大量废弃造成了高分子材料资源的流失和自然环境的破坏。因此,包含废弃HIPS在内的废塑料再生技术得到了迅速发展,而废弃HIPS的高值化再利用也推动了再生塑料产业的发展。
本文就国内外有关废弃HIPS高值化再利用的研究进展进行了综述,主要从废弃HIPS的物质再生和能量再生角度出发,论述了目前对其进行的熔融共混改性、工业回收利用以及焚烧热裂解回收。其中,熔融共混改性是我国实现废弃HIPS树脂再生循环利用的主要方式,根据共混改性工艺的不同可分为物理再生利用和物化再生利用两种。而根据共混材料种类的差异,现已初步明确橡胶类弹性体、有机材料及无机纳米材料对废弃HIPS树脂进行的单一或协同改性效果较好。总体来讲,废弃HIPS的高值化再利用为社会带来了巨大的经济和环境效益,在废塑料再生领域发挥着积极的推动作用。

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关键词: 废弃HIPS 熔融共混改性物理再生物化再生

Abstract: High impact polystyrene (HIPS) plays an important role in the field of polymer plastics due to its excellent mechanical properties. In a few years, its output has been directly equal to that of ABS (acrylonitrile-butadiene-styrene copolymer) polymer resin.As a kind of excellent polymer resin material, HIPS has shown great advantages in engineering(especially in electrical and computer) material field: good dimensional stability; strong heat resistance, good impact toughness; easy processing, and can be processed into various functional materials by adding appropriate fillers. However, the development of science and technology innovation ushered in the rapid development of electronic products. The waste of plastic materials caused the loss of polymer resources and the damage to the natural environment. Therefore, the recycling technology of waste plastics including waste hips has developed rapidly, and the high value reuse of waste hips has also promoted the development of recycled plastics industry. In this paper, the research progress of high-value reuse of waste HIPS at home and abroad is reviewed. The melt blending modification, industrial recycling and incineration pyrolysis recovery of waste HIPS are discussed from the point of view of material and energy regeneration. Among them, melt blending modification is the mainway to realize recycling of waste HIPS resin in China. According to the different blending modification process, it can be divided into physical recycling and physicochemical recycling. According to the different types of blends, it has been initially clear that rubber elastomers, organic materials and inorganic nanomaterials have better single or synergistic modification effect on waste HIPS resin. Generally speaking, the high value reuse of waste HIPS has brought enormous economic and environmental benefits, and plays an active role in promoting the recycling of waste plastics.

Key words: waste HIPS melt blending modification physical regeneration,physicochemical regeneration

发布日期: 2020-07-01

ZTFLH:

TB33

基金资助: 上海市自然科学基金(16ZR1412400;15ZR1417100);上海市高原学科-环境科学与工程(资源循环科学与工程);国家自然科学基金(51607109);上海第二工业大学重点学科(材料科学与工程,XXKYS1601)

作者简介: 张通姗,上海第二工业大学硕士研究生,于2017年12月参与上海睿莫环保新材料有限公司校企合作项目。2017年6月,在河南工程学院获得环境工程专业工学学士学位;2020年6月,在上海第二工业大学获得环境工程专业硕士学位;徐海萍,女,1966 年12月生,博士,教授。1988年本科毕业于天津大学无机非金属材料专业;2005年博士毕业于太原理工大学化学工程与技术专业;2007年北京化工大学材料科学与工程博士后出站。2012.7—2013.8期间在美国宾州州立大学材料研究所做高级访问学者。2008年至今任上海第二工业大学工学部环境与材料工程学院教师。研究方向为功能高分子及其复合材料在储能、电子线路过流过压保护等方面的应用开发,包括介电高分子储能材料与器件、聚合物基热敏电阻材料与器件等。主持并完成上海市科委基础研究重点项目1项;上海市教委基础研究重点项目1项;上海市科促会“联盟计划”2项。

引用本文:

张通姗, 徐海萍, 徐世豪, 廖杨科, 熊维. 废弃高抗冲聚苯乙烯高值化再利用的研究进展[J]. 材料导报, 2020, 34(Z1): 557-562.
ZHANG Tongshan, XU Haiping, XU Shihao, LIAO Yangke, XIONG Wei. Research Progress on High Value Reuse of Waste High Impact Polystyrene. Materials Reports, 2020, 34(Z1): 557-562.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/557

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