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材料导报  2020, Vol. 34 Issue (8): 8194-8199    https://doi.org/10.11896/cldb.18090253
  高分子与聚合物基复合材料 |
不同隔热填料对双层涂层柔性复合材料热防护性能的影响
刘国熠1,2,3,†, 赵晓明1,†, 刘元军1, 谌玉红4
1 天津工业大学纺织科学与工程学院,天津 300387;
2 天津市消防救援总队,天津 300090;
3 中国消防救援学院,北京 102202;
4 军事科学院军需装备研究所,北京 100010
Effect of Different Insulation Fillers on Thermal Protective Performance of Double-layer Coated Flexible Composites
LIU Guoyi1,2,3,†, ZHAO Xiaoming1,†, LIU Yuanjun1, SHEN Yuhong4
1 College of Textiles Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China;
2 Tianjin Fire and Rescue Bureau, Tianjin 300090, China;
3 China Fire and Rescue Institute, Beijing 102202, China;
4 The Quartermaster Research Institute of the General Logistic Department, Beijing 100010, China
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摘要 本研究制备了一系列以气凝胶、空心玻璃微珠以及100目、200目和400目空心陶瓷微珠为主要隔热功能填料的双层涂层柔性复合材料,并对比了不同复合材料的高温隔热性能、高温热稳定性和辐射热防护性能等。结果表明,隔热填料的化学组成和内部结构对所制备样品的高温热防护性能以及高温热稳定性能影响显著,以空心陶瓷微珠为填料的样品的起始分解温度分别比以空心玻璃微珠和二氧化硅气凝胶为填料的样品高87.2 ℃和80.58 ℃。其中,100目空心陶瓷微珠双层涂层复合材料的高温隔热性能测试平台温度为360.97 ℃,分别比200目和400目空心陶瓷微珠样品下降了32.41 ℃和57.69 ℃。空心玻璃微珠双层涂层柔性复合材料样品的二级烧伤时间最长,为43.13 s。为了达到理想的热防护效果,应选择在涂层体系内部更易形成稳定连续静止空气层、粒径在所设定涂层厚度下能形成较好分布状态、孔隙率或空心率较高的填料作为复合材料体系的主要隔热功能填料。
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刘国熠
赵晓明
刘元军
谌玉红
关键词:  隔热填料  双层涂层  柔性复合材料  热防护    
Abstract: In this study, a series of double-layer coated flexible composites with different insulation fillers, like aerogel, hollow glass microspheres and 100 mesh, 200 mesh and 400 mesh’s hollow ceramic microspheres were prepared, and their high temperature insulation performance, high temperature thermal stability and radiant heat protection performance were tested. The results indicated that the chemical composition and internal structures of thermal insulation functional filler had a great influence on the thermal protective performance and thermal stability under high tempe-rature. In the high-temperature thermal insulating performance test, stable temperature of 100 mesh hollow ceramic microballoon double-layer coatedk flexible composite was 360.97 ℃, which was 32.41 ℃ and 57.69 ℃, lower than that of 200 mesh and 400 mesh samples respectively. Among the four samples, TPP time of hollow glass microsphere double-layer coated flexible composite was the longest whose value was 43.13 s. To achieve an ideal effect of thermal protective performance, the thermal insulation functional filler which display greater propensity, more appropriate particle size and higher porosity or hollow ratio should be decided on.
Key words:  insulation fillers    double-layer coating    flexible composites    thermal protection
               出版日期:  2020-04-25      发布日期:  2020-04-25
ZTFLH:  TB33  
基金资助: 天津市高等学校基本科研业务资助项目(TJPU2K20170105);天津市教委科研计划项目(2017KJ070);天津市科委科技特派员项目(18JCTPJC62500);天津市自然科学基金重点项目(18JCZDJC99900);中国博士后科学基金资助项目(2019TQ0181)
通讯作者:  liuyuanjunsd@163.com   
作者简介:  †These authors contributed equally to this work.
刘国熠,博士,工程师,专业技术一级指挥员消防救援衔,国家二级心理咨询师,天津工业大学兼职硕士生导师。主要研究方向为高性能防火阻燃复合材料、消防防护及装备、传热模拟与仿真、应急管理与文化等,以第一作者身份发表中英文论文近20篇,其中SCI检索论文5篇,EI检索论文5篇,专利2项。为Textile Research JournalJournal of Industrial Textiles等多家权威SCI、EI期刊论文审稿人。近年荣获“纺织之光”中国纺织工业联合会科技进步一等奖、全国研究生数学建模竞赛二等奖、天津工业大学优秀博士学位论文奖等,荣立个人三等功一次。
赵晓明,特聘教授,博导,中国产业用纺织品协会特种纺织品分会秘书长,天津市千人计划专家,天津工业大学柔性防护中心主任。主要研究方向:1、热防护材料:纤维制品的隔热性能机理研究,热防护效果评估,燃烧烟气毒性检测,特种隔热纤维制品的设计等。2、生化核防护材料:防护系统的数字模型与仿真,物理法/化学法防护装备设计,防护效果的客观评估,生化毒气的实时检测等。3、电磁防护材料:电磁波在纤维集合体的传播,纤维制品吸波效果的客观评估等。近五年发表论文100余篇,申请专利20余项。
刘元军,博士,硕士研究生导师。2018年入选天津市131创新型人才培养工程第三层次。以第一作者发表论文100余篇,其中一篇被评为中国科学技术信息研究所领跑者5000—中国精品科技期刊顶尖学术论文。以第一发明人申请了发明专利7项。近两年,主持中国博士后科学基金特别资助项目1项,主持天津市科委项目1项,主持天津市教委项目1项,主持国家高新技术企业委托项目1项,主持天津工业大学科研项目1项。参与天津市科委自然科学基金重点项目1项,企业委托项目多项。近三年指导学生获奖二十余项。
引用本文:    
刘国熠, 赵晓明, 刘元军, 谌玉红. 不同隔热填料对双层涂层柔性复合材料热防护性能的影响[J]. 材料导报, 2020, 34(8): 8194-8199.
LIU Guoyi, ZHAO Xiaoming, LIU Yuanjun, SHEN Yuhong. Effect of Different Insulation Fillers on Thermal Protective Performance of Double-layer Coated Flexible Composites. Materials Reports, 2020, 34(8): 8194-8199.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.18090253  或          http://www.mater-rep.com/CN/Y2020/V34/I8/8194
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