磷酸活化鱼鳞活性生物炭的制备及表征

材料导报

2020, Vol. 34

Issue (Z1): 116-119

无机非金属及其复合材料

磷酸活化鱼鳞活性生物炭的制备及表征

张净净, 李海朝

青海民族大学,青藏高原资源化学与生态环境保护实验室,西宁 810007

Preparation and Characterization of Fish Scale Activated Carbon byPhosphoric Acid

ZHANG Jingjing, LI Haichao

Key Laboratory of Resource Chemistry and Eco-environment Protection of Qinghai-Tibet Plateau, Qinghai Nationalities University, Xining 810007, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 2895KB )
输出: BibTeX | EndNote (RIS)

摘要以鱼鳞为原料,通过磷酸活化法制备具有较高比表面积并含大量微孔的活性生物炭。利用傅里叶变换红外光谱(FT-IR)、扫描电镜(SEM)、X射线光电子能谱(XPS)、Boehm滴定法对制备的鱼鳞活性生物炭的结构特征和表面的组成及性质等进行了表征。结果表明:在85%的磷酸、浸渍比(磷酸与鱼鳞质量比)为2、550 ℃活化1.0 h条件下制备的鱼鳞活性生物炭的得率为26.74%,亚甲基蓝吸附值为213 mg/g,碘吸附值为936.46 mg/g,比表面积为498.162 cm²/g, 总孔容为0.266 cm³/g,平均孔径为2.138 nm。Boehm滴定法总酸度为1.678 mmol/g,总碱度为0.433 mmol/g,其表面含有两性官能团。其中酸性官能团为羟基、羧酸基、内酯基等多种含氧类官能团和含磷官能团,碱性官能团为酰胺、内酰胺、吡啶型和吡咯型等含氮官能团。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	张净净
	李海朝

关键词: 活性炭鱼鳞磷酸含氮官能团

Abstract: Using fish scales as raw materials, activated carbon with high specific surface area and a large number of micropores was prepared by phosphoric acid activation. Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and Boehm titration were used to characterize the structural characteristics and surface composition of fish scale carbon. The results showed that the yield of activated carbon was 26.74% when 85% phosphoric acid was used and impregnation ratio is 2 (phosphoric acid and raw material mass ratio of fish scale) was activated under 550 ℃ for 1.0 h. The adsorption value of methylene blue was 213 mg/g, the adsorption value of iodine was 936.46 mg/g, the specific surface area was 498.162 cm²/g, the total pore volume was 0.266 cm³/g and the average pore diameter was 2.138 nm. Boehm titration has a total acidity of 1.678 mmol/g and a total alkalinity of 0.433 mmol/g. Its surface contains amphoteric functional groups. Among them, acid functional groups are hydroxyl, carboxylic acid group, lactone group and other oxygen-containing functional groups and phosphorous functional groups, while alkaline functional groups are amide, lactam, pyridine type and pyrrole type nitrogen-containing functional groups.

Key words: activated carbon fish scale phosphoric acid nitrogen functional groups

发布日期: 2020-07-01

ZTFLH:

TQ424.1

基金资助: 青海省自然科学基金(2019-ZJ-928)

作者简介: 张净净,青海民族大学硕士研究生;李海朝,青海民族大学教授,硕士生导师。2003年获博士学位,2005年博士后出站。加拿大新布伦瑞克大学访问学者(合作教授为加拿大院士Dr. Y. H. Ni)。青海省化学会委员,青海省级高等学校青年骨干教师,省级自然科学化学工程学科带头人。现任青海民族大学化学化工学院副院长,负责学院科研、学科建设和研究生工作。主持国家自然科学基金,省部级科研项目等科研课题多项。

引用本文:

张净净, 李海朝. 磷酸活化鱼鳞活性生物炭的制备及表征[J]. 材料导报, 2020, 34(Z1): 116-119.
ZHANG Jingjing, LI Haichao. Preparation and Characterization of Fish Scale Activated Carbon byPhosphoric Acid. Materials Reports, 2020, 34(Z1): 116-119.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/116

1 李春阳,张利波,夏洪应,等.材料导报:研究篇,2016,30(7),49.
2 王玉新,刘聪敏,周亚平.功能材料,2008(3),420.
3 魏旋.淡水鱼鱼鳞制备羟基磷灰石的研究.硕士学位论文,湖北工业大学,2011.
4 刘文涛,李国英,缪煜清,等.水利渔业,2006(1),20.
5 罗红宇.食品研究与开发,2003(3),63.
6 Yang G, Chen H L, Qin H D, et al. Applied Surface Science,2014,293,299.
7 陈继锡,左宋林,王永芳,等.林产化学与工业,2016,36(2),37.
8 Ozawa M K, Suzuki S. Communication of the American Ceramic Society,2002,85(5),1315.
9 汪昆平,徐乾前.环境工程学报,2012,6(2),373.
10 张文斌,左宋林,王宜望.林产化学与工业,2017,37(2),1075.
11 Zhang B H, Ren J W, Liu X, et al. Journal of Porous Materials,2011,18(6),743.
12 牛耀岚,马承愚,李登新,等.高等学校化学学报,2010,31(10),1929.
13 陈灵智,吴瑞红,王燕,等.炭素技术,2015,34(6),32.

[1]	刘竹, 杨守禄, 姬宁, 罗扬, 许杰, 吴义强. 油茶果壳高值化利用研究进展[J]. 材料导报, 2020, 34(Z1): 120-127.
[2]	魏俊富, 张天烨, 辛卓含, 王智航, 张丽. 水体中芳香类有机化合物吸附材料的研究进展[J]. 材料导报, 2020, 34(Z1): 527-530.
[3]	赵智煌, 何梦雅, 钱建华, 马良, 冯伯文. 柱状活性炭与酸改性球形活性炭对甲苯的吸附研究[J]. 材料导报, 2020, 34(Z1): 531-534.
[4]	刘树和, 刘彬, 赵焱, 张兰, 于晓华, 李如燕, 姚耀春, 董鹏. 香蒲活性炭用于锂硫电池正极材料[J]. 材料导报, 2020, 34(8): 8014-8019.
[5]	戴俊, 钱春香, 陈竞, 庞忠华. 无水乙酸钠对磷酸钾镁水泥水化性能和微观形貌的影响[J]. 材料导报, 2020, 34(6): 6066-6074.
[6]	王磊. 量子化学研究L-精氨酸磷酸盐的前线分子轨道与理论振动光谱[J]. 材料导报, 2020, 34(4): 4174-4178.
[7]	董金美, 肖学英, 李颖, 文静, 郑卫新, 常成功, 余红发. 原料质量配比对盐湖磷酸钾镁水泥性能和微观结构的影响[J]. 材料导报, 2020, 34(10): 10041-10045.
[8]	欧先国, 周玉山, 毛文峰, 顾晓瑜, 长世勇, 裴锋. 多孔碳添加量对溶胶凝胶-碳热还原法制备磷酸钒锂正极材料的电化学影响[J]. 材料导报, 2019, 33(Z2): 38-42.
[9]	徐颖, 邓利蓉, 杨进超, 左联, 杜广报, 芦玉峰, 李莎莎. 磷酸镁水泥的制备及其快速修补应用研究进展[J]. 材料导报, 2019, 33(Z2): 278-282.
[10]	陈明军. 涂料用分散剂研究进展[J]. 材料导报, 2019, 33(Z2): 643-645.
[11]	陈坤, 李君, 曲大为, 卢强. 基于LCA评价模型的动力电池回收阶段环境性研究[J]. 材料导报, 2019, 33(z1): 53-56.
[12]	邓恺, 黎红兵, 李响, 吴凯. 不同养护条件下钢渣与粉煤灰改性磷酸镁水泥的性能研究[J]. 材料导报, 2019, 33(z1): 264-268.
[13]	李芮, 施宇震, 宁平, 谷俊杰, 关清卿, 耿瑞文, 孟凡凡. 改性活性炭吸附甲苯废气的研究进展[J]. 材料导报, 2019, 33(7): 1133-1140.
[14]	莫松平, 郑麟, 袁潇, 林潇晖, 潘婷, 贾莉斯, 陈颖, 成正东. 具有高分散稳定性的磷酸锆悬浮液的液固相变循环性能[J]. 材料导报, 2019, 33(6): 919-922.
[15]	王岚, 崔世超, 任敏达. 多聚磷酸复配SBS改性沥青微观结构特性评价[J]. 材料导报, 2019, 33(24): 4105-4110.

[1]	Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells[J]. Materials Reports, 2018, 32(3): 337 -356 .
[2]	Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO₂/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[3]	Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[4]	Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[5]	Huanchun WU, Fei XUE, Chengtao LI, Kewei FANG, Bin YANG, Xiping SONG. Fatigue Crack Initiation Behaviors of Nuclear Power Plant Main Pipe Stainless Steel in Water with High Temperature and High Pressure[J]. Materials Reports, 2018, 32(3): 373 -377 .
[6]	Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378 -383 .
[7]	Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[8]	Yunzi LIU,Wei ZHANG,Zhanyong SONG. Technological Advances in Preparation and Posterior Treatment of Metal Nanoparticles-based Conductive Inks[J]. Materials Reports, 2018, 32(3): 391 -397 .
[9]	Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[10]	Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .

Viewed

Full text

Abstract

Cited

Shared

Discussed