Abstract: In order to improve the microstructure of the Al-Zn alloy, the dissolution rate of the alloy canbe effectively controlled. The influence of different Sn content on microstructure and electrochemical properties of as-cast Al-Zn alloy was studied by means of optical microscope (OM), X-ray diffractometer (XRD), scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and electrochemical workstation. The results show that the alloy is mainly composed of Al matrix phase, Al0.71Zn0.29 phase and Sn phase, with the increase of Sn element content, the content of the precipitated phase at the grain boundary is increased obviously, the size is gradually increased, and the grain is gradually changed into a strip shape. When the Sn content increased from 0.1wt% to 2wt%, the average grain size of the alloy decreased from 194.54 μm to 65.33 μm, and the dissolution rate and the electrochemical activity of the alloy were continuously improved. As Sn content continued to increase, the average grain size of the alloy gradually increased, while dissolution rate and electrochemical activity decreased.
1 Wen J, He J, Lu X. Corrosion Science,2011,53(11),1. 2 Wang H Z, Leung D Y C, Leung M K H, et al. Renewable and Sustai-nable Energy Reviews,2009,13(4),845. 3 杨朝晖,刘斌,李向阳,等.中国材料进展,2014(9),618. 4 Norris J C, Scantlebury J D, Alexander M R, et al. Surface & Interface Analysis,2015,30(1),170. 5 Wang F Q, Wang H H, Wang J, et al. Transactions of Nonferrous Metals Society of China,2016,26(1),152. 6 孙明先,马力,张海兵,等.装备环境工程,2018,15(3),9. 7 Yuan B, Tan S, Jing L. International Journal of Hydrogen Energy,2016,41(3),1453. 8 张杰,刘奉令,李伟华,等.材料工程,2011(4),47. 9 Khireche S, Boughrara D, Kadri A, et al. Corrosion Science,2014,87(5),504. 10 Al-Sultani K F, Nabat J N. Advanced Materials Research,2012,468-471,1585. 11 朱建锋,呼丹,任国富,等.陕西科技大学学报(自然科学版),2017(1),62. 12 贺俊光.Al-Zn-Sn系阳极材料的组织与性能研究.博士学位论文,兰州理工大学,2011. 13 王国伟,文九巴,马景灵,等.腐蚀与防护,2010,31(8),611. 14 Duan H, Du K, Yan C, et al. Electrochimica Acta,2006,51(14),2898. 15 曹楚南.腐蚀电化学原理,化学工业出版社,北京,2008. 16 纪志康,于思荣,刘丽,等.复合材料学报,2018,35(5),185.