Study on Flexible Transparent IPMC Material Based on PEDOT:PSS Electrodes
CHANG Longfei1,2, YANG Hailin1, JIN Ke1, SHEN Jinjie1, ZHU Zicai3, HU Ying1,2,*
1 Anhui Province Key Lab of Aerospace Structural Parts Forming Technology and Equipment, Institute of Industry and Equipment Technology, Hefei University of Technology, Hefei 230009, China 2 Anhui Key Laboratory of Advanced Functional Materials and Devices, Hefei University of Technology, Hefei 230009, China 3 School of Mechanical Engineering, Xi'an Jiaotong University, Xi'an 710049, China
Abstract: Transparent and flexible functional materials are crucial to the development of modern electro-mechanical devices. In this work, the preparation process of the transparent ionic polymer-metal composite (IPMC) with Nafion/IL substrate and PEDOT:PSS electrodes was explored by combining solution casting method and roll coating method. Furthermore, the electro-mechanical characteristics and electro-active properties of so-made IPMCs were investigated. Orthogonal optimization was carried out to evaluate the influence level of key parameters, including substrate thickness, electrode roll coating content on each side, hot pressing time immersed in IL and the degree of roughness. The transparent IPMC prepared according to the orthogonal optimization parameters showed nice optical transparency, electrochemical and mechanical properties. The maximum peak-to-peak tip displacement of our transparent IPMC can reach 11.824 mm; in addition, the samples can activate under voltage with frequency up to 100 Hz. The research is of great significance to expand the fabrication method of IPMC and promote the application of this mate-rial in the field of transparent flexible electronic devices.
作者简介: 常龙飞,合肥工业大学副研究员,爱沙尼亚塔尔图大学客座教授。2008年本科毕业于长安大学,2011年硕士毕业于西安交通大学,2015年博士毕业于西安交通大学,2013—2014年赴日本产业与技术综合研究所访问。主要研究方向包括智能材料与结构、凝聚态物理、软机械等。在Advanced Functional Materials、Smart Materials and Structures、Applied Phy-sics Letters、《机械工程学报》等国内外学术期刊上发表论文40余篇,申请发明专利20余项。主持国家自然科学基金面上项目和青年项目、中国博士后科学基金面上项目、安徽省自然科学基金青年项目、中央高校基本科研业务费等项目。
引用本文:
常龙飞, 杨海林, 金珂, 沈锦杰, 朱子才, 胡颖. 基于PEDOT:PSS电极的柔性透明IPMC材料研究[J]. 材料导报, 2023, 37(6): 21060011-8.
CHANG Longfei, YANG Hailin, JIN Ke, SHEN Jinjie, ZHU Zicai, HU Ying. Study on Flexible Transparent IPMC Material Based on PEDOT:PSS Electrodes. Materials Reports, 2023, 37(6): 21060011-8.
1 Ja H, Dong C, Hyung J, et al. Advanced Function Materials, 2018, 28(35), 1801834. 2 Coskun S, Selen A, Emrah U. Nanotechnology, 2013, 24(12), 125202. 3 Rak-Hwan K, Myung-Ho B, Dae G, et al. Nano Letters, 2011, 11(9), 3881. 4 Lee H, Lee J, Huynh C, et al. Liquid Crystals, 2015, 42, 322. 5 Liu Y, Jung E, Wang Y, et al. Small, 2014, 10(5), 944. 6 Liu Y, Feng J, Zhang Y, et al. Organic Electronics, 2014, 15, 478. 7 Li L, Yu Z, Hu W, et al. Advanced Materials, 2011, 23(46), 5563. 8 Cai M, Tiong V, Hreid T, et al. Journal of Materials Chemistry A, 2015, 3, 2784. 9 Li Z, Liang Y, Zhong Z, et al. Synthetic Metals, 2015, 210, 363. 10 Morteza A, Aekachan P, Sangjun L, et al. ACS Nano, 2014, 8(5), 5154. 11 Chen B, Lu J, Yang C, et al. ACS Applied Materials & Interfaces, 2014, 6(10), 7840. 12 Liu Q, Liu Z, Li C, et al. Advanced Science, 2020, 7(10), 2000348. 13 My D, Ling Y, Lim W, et al. Advanced Function Materials, 2017, 27(25), 1700845. 14 Kaushik P, Vipin K, Wang J, et al. Advanced Materials, 2017, 29(37), 1702181. 15 Anuj R, Akshay K, Zhou C. Nanotechnology, 2011, 22, 245201. 16 Bu-Jong K, Jong-Seol P, Young-Jin H, et al. Thin Solid Films, 2015, 596, 68. 17 Mukai K, Asaka K, Kiyohara K, et al. Electrochimica Acta, 2008, 53(17), 5555. 18 Dang Z, Wang L, Wang H. Journal of Functional Materials, 2005, 36(7), 981(in Chinese). 党智敏, 王岚, 王海燕. 功能材料, 2005, 36(7), 981. 19 Ye Rim L, Hyungho K, Do Hoon L, et al. Soft Matter, 2017, 13, 6390. 20 Weng M, Chen L, Huang F, et al. Nanotechnology, 2020, 31(6), 065501. 21 Uikyum K, Junmo K, Choonghan L, et al. Nanotechnology, 2013, 24(14), 145501. 22 Samatham R, Kim K, Dogruer D, et al. Electroactive polymers for robotic applications. Springer London, London, 2007, pp.1. 23 Chen H, Zhu Z, Chang L, et al. Deformation mechanism and basic pro-perties of ionic polymer metal composites, Science Press, China, 2016 (in Chinese). 陈花玲, 朱子才, 常龙飞, 等. 离子聚合物-金属复合材料变形机理及其基本特性, 科学出版社, 2016. 24 Naohiro T. Sensors and Actuators B: Chemical, 2018, 257, 815. 25 Naohiro T. Langmuir, 2020, 36(22), 6154. 26 Jun K, Kim J, Oh I K. Small, 2018, 14(35), 1801603. 27 Kim B J, Park J S, Hwang Y J, et al. Thin Solid Films, 2015, 596, 68. 28 Kim R H, Bae M H, Kim D G, et al. Nano Letters, 2011, 11(9), 3881. 29 Li Z, Ying L, Zhong Z, et al. Synthetic Metals, 2015, 210, 363. 30 Zhu Z, Chang L, Takagi K, et al. Applied Physics Letters, 2014, 105(5), 054103. 31 Zhu Z. Study on the preparation and performance of ionic polymer-metal composite (IPMC). Master's Thesis, Xi'an Jiaotong University, China, 2008 (in Chinese). 朱子才. 离子聚合物-金属复合材料(IPMC)制备和性能研究. 硕士学位论文, 西安交通大学, 2008. 32 Yang Q. Effect of a new base film roughening process on the interface and properties of IPMC. Master's Thesis, Hefei University of Technology, China, 2019 (in Chinese). 杨倩. 一种新型基膜糙化工艺对IPMC界面及性能的影响. 硕士学位论文, 合肥工业大学, 2019. 33 Lang U, Dual J. Key Engineering Materials, 2007, 345-346, 1189.
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2023, Vol. 37 
