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材料导报  2024, Vol. 38 Issue (22): 23040274-11    https://doi.org/10.11896/cldb.23040274
  高分子与聚合物基复合材料 |
动态热机械分析技术在高分子形状记忆效应表征中的应用进展
李兴建1,*, 吕佳宁1, 姚新宽2, 周孟2, 李因文1, 徐守芳1
1 临沂大学材料科学与工程学院,山东 临沂 276000
2 淄博市特种设备检验研究院,山东 淄博 255000
Progress in Application of Dynamic Thermomechanical Analysis Technique in Characterization of Polymeric Shape Memory Effects
LI Xingjian1,*, LYU Jianing1, YAO Xinkuan2, ZHOU Meng2, LI Yinwen1, XU Shoufang1
1 School of Materials Science and Engineering, Linyi University, Linyi 276000, Shandong, China
2 Zibo Institute of Special Equipment Inspection, Zibo 255000, Shandong, China
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摘要 形状记忆高分子(SMP)是指能够感知外界环境变化的刺激并响应这种变化,对其自身状态参数进行调整,从而回复到预先设定状态的一类高分子材料。目前SMP除能够实现研究最为广泛的不可逆双重形状记忆效应外,也能够展现复杂的三重形状记忆效应、多重形状记忆效应、恒定外力下的可逆双向形状记忆效应、无外力的可逆双向形状记忆效应及其形状可重构效应。通常聚合物的形状记忆效应能够使用动态热机械分析技术进行表征,通过控制SMP的应力、应变和温度能够实现变形、暂时形状的固定和形状的回复,从而得到应力-应变-温度循环热机械曲线,实现定量形状记忆性能,包括形状固定率(Rf)、形状回复率(Rr)、形状回复速率(Vr)和形状回复力等。本文综述了动态热机械分析仪(TA-Q800)的拉伸模式在各种形状记忆效应表征中的应用,包括测试程序的选择、程序设置及其相对应的热机械循环曲线、参数计算和测试条件对形状记忆效应的影响,最后分析了研究中存在的问题并展望了未来发展方向。
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李兴建
吕佳宁
姚新宽
周孟
李因文
徐守芳
关键词:  形状记忆高分子  动态热机械分析  形状记忆效应  表征    
Abstract: The shape memory polymers refer to a class of intelligent materials that sense changes in the external environment, respond to such changes, adjust to its own state parameters and return to a preset state. At present, SMP can not only realize the most widely studied irreversible double shape memory effect, but also exhibit complex triple shape memory effect, multiple shape memory effect, reversible two-way shape me-mory effect under constant external force, and reversible two-way shape memory effect without external force and shape reconfigurable effects. Generally, the shape memory effect of polymers can be characterized using dynamic thermomechanical analysis techniques. By controlling the stress, strain and temperature of the SMP, deformation, temporary shape fixation and shape recovery can be achieved, thereby obtaining a stress-strain-temperature cycle thermomechanical curves to achieve quantitative shape memory performance, including shape fixation ratio (Rf), shape recovery ratio (Rr), shape recovery speed and shape recovery force, etc. This paper reviews the application of the tensile mode of the dynamic thermomechanical analyzer (TA-Q800) in the characterization of various shape memory effects, including the selection of test programs, program settings and their corresponding thermomechanical cycle curves, parameter calculations, and influences of test conditions on shape memory effects. It ends with a critical and prospective discussion on problems existing in the current research and future development trends of this field.
Key words:  shape memory polymer    dynamic thermomechanical analysis    shape memory effect    characterization
出版日期:  2024-11-25      发布日期:  2024-11-22
ZTFLH:  O631.2  
基金资助: 国家自然科学基金面上项目(22275076;22172070);山东省自然科学青年基金项目(ZR2020QE092);山东省自然科学基金重点项目(ZR2020KE002);2023国家级大学生创新创业训练计划项目(202310452143)
通讯作者:  *李兴建,临沂大学材料科学与工程学院副教授、硕士研究生导师。2016年博士毕业于中国科学院成都有机化学研究所,同年进入浙江大学从事博士后研究工作。于2018年任教于临沂大学材料科学与工程学院,主要从事形状记忆高分子材料的研究。在Advanced Functional Materials、Polymer Chemistry、Macromolecular Rapid Communications等期刊发表论文50余篇。lixingjian1314@163.com   
引用本文:    
李兴建, 吕佳宁, 姚新宽, 周孟, 李因文, 徐守芳. 动态热机械分析技术在高分子形状记忆效应表征中的应用进展[J]. 材料导报, 2024, 38(22): 23040274-11.
LI Xingjian, LYU Jianing, YAO Xinkuan, ZHOU Meng, LI Yinwen, XU Shoufang. Progress in Application of Dynamic Thermomechanical Analysis Technique in Characterization of Polymeric Shape Memory Effects. Materials Reports, 2024, 38(22): 23040274-11.
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http://www.mater-rep.com/CN/10.11896/cldb.23040274  或          http://www.mater-rep.com/CN/Y2024/V38/I22/23040274
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