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材料导报  2024, Vol. 38 Issue (21): 23020231-11    https://doi.org/10.11896/cldb.23020231
  无机非金属及其复合材料 |
球型Si基碳包覆锂离子电池负极材料研究进展
李东霖, 杨万亮, 曹锐, 杨雪, 徐梅松*
贵州大学化学与化工学院,贵阳 550025
Research Progress of Spherical Si-based Carbon-coated Anode Materials for Lithium-ion Batteries
LI Donglin, YANG Wanliang, CAO Rui, YANG Xue, XU Meisong*
School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China
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摘要 硅基材料包括单质硅及其氧化物SiOx(0≤x≤2),具有理论容量高、工作电位低、对环境友好、储量丰富等特点,有望取代石墨成为新一代锂离子电池负极材料。然而,硅基材料在充放电过程中的体积膨胀效应始终不能避免,硅氧化物的低电导率也限制了硅基材料的发展。为解决上述问题,研究人员提出了各种各样的解决方法,其中,在硅基材料表面进行碳包覆的方法具有很广阔的应用前景并被广泛研究。本文先简要介绍了各硅基材料的储锂机理和失效问题,再从最典型的球型结构设计的角度切入,详细介绍了不同的球型碳包覆结构,如核壳结构、蛋黄壳结构、多孔结构等,并讨论了Si基碳包覆负极材料未来商业化的发展趋势和要面对的挑战。
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李东霖
杨万亮
曹锐
杨雪
徐梅松
关键词:  锂离子电池  球型  硅基材料  碳包覆    
Abstract: Silicon-based materials, including elemental silicon and its oxide SiOx(0≤x≤2), are expected to replace graphite as a new generation of anode material for lithium-ion batteries because of their high theoretical capacity, low working potential, environment-friendly and abundant reserves. However, the volume expansion effect of silica-based materials in the process of charge and discharge is inevitable. In addition, the low conductivity of silica-based materials also limits the development of silica-based materials. In order to solve the above problems, researchers have proposed a variety of solutions, among which the carbon coating method on the surface of silicon-based materials has a great application prospect and has been widely studied. This paper first outlines the lithium storage mechanism and failure problems of each silicon-based material, and then summarizes different spherical carbon coating structures in detail from the perspective of the most typical spherical structure design, such as core-shell structure, yolk-shell structure, porous structure, etc. The future development trend of carbon-coated anode materials based on Si and the challenges to be faced are discussed.
Key words:  lithium-ion battery    spherical    silicon-based material    carbon coating
出版日期:  2024-11-10      发布日期:  2024-11-11
ZTFLH:  O469  
基金资助: 国家自然科学基金(22162008);贵州省科学技术厅基础研究计划项目([2020]1Y055)
通讯作者:  *徐梅松,贵州大学化学与化工学院副教授、硕士研究生导师。1997年贵州工业大学(现合并为贵州大学)化学工程与工艺专业本科毕业后留校工作至今。目前主要从事化工及材料等方面的研究工作。msxu1974@126.com   
作者简介:  李东霖,2022年7月于合肥工业大学获得工学学士学位。现为贵州大学化学与化工学院硕士研究生,在徐梅松副教授的指导下进行研究。目前主要研究领域为锂离子电池负极材料。
引用本文:    
李东霖, 杨万亮, 曹锐, 杨雪, 徐梅松. 球型Si基碳包覆锂离子电池负极材料研究进展[J]. 材料导报, 2024, 38(21): 23020231-11.
LI Donglin, YANG Wanliang, CAO Rui, YANG Xue, XU Meisong. Research Progress of Spherical Si-based Carbon-coated Anode Materials for Lithium-ion Batteries. Materials Reports, 2024, 38(21): 23020231-11.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23020231  或          http://www.mater-rep.com/CN/Y2024/V38/I21/23020231
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