质子交换膜电解水用非贵金属基析氧反应催化剂的研究进展

doi:10.11896/cldb.23020032

材料导报

2024, Vol. 38

Issue (13): 23020032-16 https://doi.org/10.11896/cldb.23020032

无机非金属及其复合材料

质子交换膜电解水用非贵金属基析氧反应催化剂的研究进展

狄大程, 李明哲, 李羿龙, 凌子昱, 吕玉珍^*, 陈克丕

华北电力大学能源动力与机械工程学院,北京 102206

Research Progress of Non-noble Metal-based Oxygen Evolution Catalyst for Proton Exchange Membrane Water Electrolysis

DI Dacheng, LI Mingzhe, LI Yilong, LING Ziyu, LYU Yuzhen^*, CHEN Kepi

School of Energy, Power and Mechanical Engineering , North China Electric Power University, Beijing 102206, China

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摘要质子交换膜(PEM)电解水制氢技术是可再生能源存储与转化的重要技术手段。目前,国内外研究者在非贵金属析氧反应(OER)催化剂方面开展了大量的工作。但是,在PEM电解水阳极的强酸性条件下,催化剂仍难以兼顾催化活性和稳定性。为此,本文对PEM电解水用非贵金属酸性介质OER催化剂的研究进行了系统总结和分析。首先,基于PEM装置的工作特点提出了PEM电解水用OER催化剂的性能指标;第二,阐述了OER催化过程的基本原理;第三,系统介绍了碳基材料、过渡金属氧化物、过渡金属硫化物、过渡金属磷化物和多金属氧酸盐等非贵金属OER催化剂的研究进展,重点分析了其催化活性和稳定性的改进策略;最后,从PEM电解水需求和材料改性两方面对OER催化剂的设计进行了展望。

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关键词: PEM电解水析氧反应酸性介质非贵金属

Abstract: Proton exchange membrane (PEM) water electrolysis for hydrogen production is an important technology for renewable energy storage and conversion. At present, extensive studies have been focused on the non-noble metal-based oxygen evolution reaction (OER) catalyst. A variety of catalysts have been explored, but it is still a challenge to remain catalytic activity and stability under the strong acidic condition of PEM water anode. Progress on OER catalyst of non-noble metal under acid medium is summarized in this work for PEM water electrolysis. Firstly, the performance index of OER catalyst for water electrolysis is proposed based on the working characteristics of PEM device. Secondly, the basic principle of OER catalysis is described. Thirdly, the research progress of non-noble metal OER catalysts, including carbon-based materials, transition metal oxides, transition metal sulfides, transition metal phosphates and polyoxometalates is systematically reviewed, and the improvement strategies for catalytic activity and stability are emphatically analyzed. Finally, the design of OER catalyst is prospected from two aspects of actual demand and material modification for PEM.

Key words: PEM water electrolysis OER acid medium non-precious metal

出版日期: 2024-07-10 发布日期: 2024-08-01

ZTFLH:

O643.36

基金资助: 国家重点研究计划项目子课题(2018YFB0604302-04)

通讯作者: ^*吕玉珍,华北电力大学能源动力与机械工程学院教授,主要从事纳米功能材料与涂层的设计合成、性能调控及电解水制氢领域的应用研究,已发表SCI收录论文60多篇。yzlv@ncepu.edu.cn

作者简介: 狄大程,2018年6月毕业于华北电力大学,获得工学学士学位,现为华北电力大学材料科学与工程专业硕士研究生,主要研究领域为非贵金属催化剂的制备与性能调控。

引用本文:

狄大程, 李明哲, 李羿龙, 凌子昱, 吕玉珍, 陈克丕. 质子交换膜电解水用非贵金属基析氧反应催化剂的研究进展[J]. 材料导报, 2024, 38(13): 23020032-16.
DI Dacheng, LI Mingzhe, LI Yilong, LING Ziyu, LYU Yuzhen, CHEN Kepi. Research Progress of Non-noble Metal-based Oxygen Evolution Catalyst for Proton Exchange Membrane Water Electrolysis. Materials Reports, 2024, 38(13): 23020032-16.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23020032 或 http://www.mater-rep.com/CN/Y2024/V38/I13/23020032

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