Xe离子辐照后Zr-4和Zr-1Nb合金的力学和耐腐蚀性能研究

doi:10.11896/cldb.23020010

材料导报

2024, Vol. 38

Issue (18): 23020010-5 https://doi.org/10.11896/cldb.23020010

金属与金属基复合材料

Xe离子辐照后Zr-4和Zr-1Nb合金的力学和耐腐蚀性能研究

全琪炜¹, 刘向兵^1,*, 赵文增², 吴奕初², 徐超亮¹, 张晏玮¹, 李远飞¹, 钱王洁¹, 贾文清¹, 尹建¹

1 苏州热工研究院有限公司,江苏苏州 215000
2 武汉大学物理科学与技术学院,武汉430000

Study on Mechanical and Corrosion Properties of Zr-4 and Zr-1Nb Alloy After Xe Ions Irradiation

QUAN Qiwei¹, LIU Xiangbing^1,*, ZHAO Wenzeng², WU Yichu², XU Chaoliang¹, ZHANG Yanwei¹, LI Yuanfei¹, QIAN Wangjie¹, JIA Wenqing¹, YIN Jian¹

1 Suzhou Nuclear Power Research Institute Co., Ltd., Suzhou 215000, Jiangsu, China
2 School of Physics and Technology, Wuhan University, Wuhan 430000, China

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摘要为探究两种典型燃料包壳锆合金Zr-4和Zr-1Nb辐照后的性能变化规律,本研究使用5.0 MeV的Xe离子室温辐照锆合金最高至4.0 dpa,并在360 ℃/18.6 MPa、0.01 mol/L LiOH溶液中开展最高28 d的腐蚀实验,结合纳米压痕、SEM和TEM,研究辐照硬化规律、腐蚀后的氧化膜形态及锆合金第二相的变化规律,讨论辐照对腐蚀的影响。结果表明,Xe离子辐照后两种锆合金产生了辐照硬化,Zr-1Nb比Zr-4辐照硬化率更高。在模拟环境腐蚀28 d内,Zr-4的耐腐蚀性优于Zr-1Nb,离子辐照增加了锆合金的腐蚀增重,且Zr-1Nb的辐照增强腐蚀效应更显著,辐照使锆合金第二相产生了不同程度的非晶化。研究结果有助于理解相关锆合金的辐照效应,为新型包壳锆合金材料开发及性能评估提供参考。

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	全琪炜
	刘向兵
	赵文增
	吴奕初
	徐超亮
	张晏玮
	李远飞
	钱王洁
	贾文清
	尹建

关键词: 锆合金离子辐照辐照硬化耐腐蚀性能

Abstract: In order to study the performance of two typical fuel cladding zirconium alloys Zr-4 and Zr-1Nb after irradiation, this study used 5.0 MeV Xe ions to irradiate the zirconium alloys up to 4.0 dpa at room temperature, and carried out the corrosion experiment at 360 ℃/18.6 MPa, 0.01 mol/L LiOH solution for 28 d. Combined with nano-indentation, SEM and TEM, the irradiation hardening effect, the morphology of oxidation film and the change of second phase were characterized, discussing the effect of irradiation on corrosion. The result showed that both zirconium alloys produced irradiation hardening after Xe ion irradiation, with Zr-1Nb being more significant than Zr-4. The corrosion resistance of Zr-4 was better than Zr-1Nb in 28 d of simulated environmental corrosion. Ions irradiation increased the corrosion weight gain and caused the second phase amorphous, and the irradiation enhancing corrosion effect was more pronounced for Zr-1Nb. The research could help understand the irradiation effects of zirconium alloys and provide a reference for the development of new cladding zirconium alloy materials.

Key words: zirconium alloy ions irradiation irradiation harden corrosion resistance

发布日期: 2024-10-12

ZTFLH:

TL341

基金资助: 国家自然科学基金(11975171)

通讯作者: *刘向兵,通信作者,中广核苏州热工研究院有限公司材料工程技术中心副总工,研究员级高级工程师、博士研究生导师。2010年1月毕业于北京科技大学,获材料学博士学位,兼任江苏省仪器仪表学会无损检测仪器专业委员会会员、北京粉末冶金研究会副理事长、电力行业电力锅炉压力容器安全监督管理委员会专家等。目前主要从事核结构材料辐照效应研究与核电老化管理的研究工作,主编/参编专著2本,发表学术论文90余篇。liuxbing@cgnpc.com.cn

作者简介: 全琪炜,服役安全评价工程师,2020年6月毕业于东南大学,获得材料科学与工程专业工学硕士学位。2020年7月加入中广核苏州热工研究院有限公司,目前主要从事核燃料包壳锆合金的离子辐照效应、辐照缺陷缓解技术、增材制造核电材料的离子辐照效应的研究。

引用本文:

全琪炜, 刘向兵, 赵文增, 吴奕初, 徐超亮, 张晏玮, 李远飞, 钱王洁, 贾文清, 尹建. Xe离子辐照后Zr-4和Zr-1Nb合金的力学和耐腐蚀性能研究[J]. 材料导报, 2024, 38(18): 23020010-5.
QUAN Qiwei, LIU Xiangbing, ZHAO Wenzeng, WU Yichu, XU Chaoliang, ZHANG Yanwei, LI Yuanfei, QIAN Wangjie, JIA Wenqing, YIN Jian. Study on Mechanical and Corrosion Properties of Zr-4 and Zr-1Nb Alloy After Xe Ions Irradiation. Materials Reports, 2024, 38(18): 23020010-5.

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http://www.mater-rep.com/CN/10.11896/cldb.23020010 或 http://www.mater-rep.com/CN/Y2024/V38/I18/23020010

1 Sagiroun M, Cao X R, Helal W, et al. International Journal of Engineering Research in Africa, 2020, 46, 7.
2 Hu J, Li G, Zhang T G, et al. Metal World, 2020(3), 23 (in Chinese).
胡娟, 李刚, 张天广, 等. 金属世界, 2020(3), 23.
3 Pan R J, Tang A T, Wu L, et al. Material Sciences, 2019(9), 861 (in Chinese).
潘荣剑, 汤爱涛, 吴璐, 等. 材料科学, 2019(9), 861.
4 Yang Z F, Shi P, Ao B Y. Materials Reports, 2020, 34(5), 102 (in Chinese).
杨振飞, 史鹏, 敖冰云. 材料导报, 2020, 34(5), 102.
5 Tewari R, Krishna K, Neogy S, et al. Comprehensive Nuclear Materials, 2020, 7, 284.
6 Lemaignan C, Moan G D, Rudling P, et al. In:Zirconium in the Nuclear Industry:Thirteenth International Symposium. Annecy, 2002, pp.20.
7 Dykhuis A F, Short M P. Corrosion Science, 2019, 146, 179.
8 Romain V, Marc T, Gerard B, et al. Corrosion Science, 2015, 98, 327.
9 Markelov V, Novikov V, Shevyakov A, et al. In:Zirconium in the Nuclear Industry:18th International Symposium. Hilton Head, 2016, pp.857.
10 Was G S, Busby J T. Journal of Nuclear Materials, 2002, 300(2-3), 198.
11 Bererd N, Moncoffre N, Chevarier A, et al. Nuclear Instruments and Methods in Physics Research, 2006, 249B, 513.
12 Yang Z B, Cheng Z Q, Qiu J, et al. Nuclear Power Engineering, 2017, 38(5), 123 (in Chinese).
杨忠波, 程竹青, 邱军, 等. 核动力工程, 2017, 38(5), 123.
13 Yan C G. Research on microstructure and performance of zirconium alloys under ion irradiation. Ph.D. Thesis, University of Science and Technology Beijing, China, 2016 (in Chinese).
燕春光. 锆合金在离子辐照下的微观结构及性能的研究. 博士学位论文, 北京科技大学, 2016.
14 Bai R Y, Fan P, Xia H H, et al. Nuclear Physics Review, 2017, 34(3), 630 (in Chinese).
白若玉, 范平, 夏海鸿, 等. 原子核物理评论, 2017, 34(3), 630.
15 Bai R Y, Wang K, Bai Y K, et al. Atomic Energy Science and Technology, 2018, 52(11), 2020 (in Chinese).
白若玉, 王珂, 白亚奎, 等. 原子能科学技术, 2018, 52(11), 2020.
16 Pharr G M, Herbert E G, Gao Y F. Annual Review of Materials Research, 2010, 40, 271.
17 Nix W D, Gao H. Journal of the Mechanics and Physics of Solids, 1998, 46(3), 411.
18 Zhao W Z, Quan Q W, Zhang S M, et al. Radiation Physics and Chemistry, 2023, 209, 110986.
19 Zhou B X, Li Q, Huang Q, et al. Nuclear Power Engineering, 2000, 21(5), 439 (in Chinese).
周邦新, 李强, 黄强, 等. 核动力工程, 2000, 21(5), 439.
20 Nikulina A V, Markelov V A, Peregud M M, et al. In:Zirconium in the Nuclear Industry:Eleventh International Symposium. West Conshohocken, 1996, pp.785.
21 Chai L J, Luan B F, Zhou Y, et al. The Chinese Journal of Nonferrous Metals, 2012, 22(6), 1594 (in Chinese).
柴林江, 栾佰峰, 周宇, 等. 中国有色金属学报, 2012, 22(6), 1594.
22 Zu X T, Sun K, Atzmon M, et al. Philosophical Magazine, 2005, 85(4-7), 649.
23 Griffiths M, Gilbert R W, Fidleris V, et al. Journal of Nuclear Materials, 1987, 150, 159.
24 Qiu R S, Luan B F, Chai L J, et al. The Chinese Journal of Nonferrous Metals, 2012, 22(6), 1605 (in Chinese).
邱日盛, 栾佰峰, 柴林江, 等. 中国有色金属学报, 2012, 22(6), 1605.
25 Quan Q W, Liu X B, Xu C L, et al. Materials Reports, 2022, 36(S1), 375 (in Chinese).
全琪炜, 刘向兵, 徐超亮, 等. 材料导报, 2022, 36(S1), 375.
26 Yao M Y, Zhou B X. Journal of Shanghai University (Natural Science), 2020, 26(5), 681 (in Chinese).
姚美意, 周邦新. 上海大学学报:自然科学版, 2020, 26(5), 681.
27 Liao J J, Qiu S Y, Zhang J S, et al. Nuclear Power Engineering, 2020, 41(S1), 164 (in Chinese).
廖京京, 邱绍宇, 张君松, 等. 核动力工程, 2020, 41(S1), 164.

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