钯催化环加成反应构建中环化合物的研究进展

doi:10.11896/cldb.22110292

材料导报

2024, Vol. 38

Issue (12): 22110292-12 https://doi.org/10.11896/cldb.22110292

高分子与聚合物基复合材料

钯催化环加成反应构建中环化合物的研究进展

皮晓琳, 李鸿鹏, 田乙然, 童应成, 倪文若, 袁藤瑞, 唐振艳^*

贵研铂业股份有限公司, 稀贵金属综合利用新技术国家重点实验室, 云南贵金属实验室有限公司, 昆明 650106

Advances in Palladium-Catalyzed Cycloaddition Reactions for the Construction of Medium-ring Compounds

PI Xiaolin, LI Hongpeng, TIAN Yiran, TONG Yingcheng, NI Wenruo, YUAN Tengrui, TANG Zhenyan^*

State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Yunnan Precious Metals Lab Co., Ltd., Sino-Platinum Metals Co.,Ltd., Kunming 650106, China

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摘要中环化合物(7—11元环)广泛存在于许多天然产物及药物等功能分子之中,这些分子因具有优异的生物活性及特殊的骨架结构等优点,展现出极其重要的药用价值,如常见的抗癌药物紫杉醇、抗菌药物Spiroxin A等。同时,这类化合物也对化学、医药以及材料等诸多领域产生了深远的影响。但受动力学和热力学因素影响,中环化合物的高效构建依然是一个严峻的挑战。在科研工作者们的不懈努力下,近年来发展出多个新型环加成反应催化体系,其中钯催化环加成反应凭借高效、高选择性和原子经济性等优点在该领域得到了迅猛发展。本文详细介绍了近五年国内外有关钯催化环加成反应构建中环化合物研究的最新进展,旨在为该领域的发展提供一定的帮助。

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	袁藤瑞
	唐振艳

关键词: 中环化合物钯催化环加成反应环化反应反应机理

Abstract: The medium-ring compounds (7 to 11-membered rings) are widely found in functional molecules, such as many natural products and drugs. These molecules show great medicinal value due to their excellent biological activity and special backbone structure, exemplified by the common anti-cancer drug paclitaxel and the anti-bacterial drug Spiroxin A, and have also exerted a profound impact on many fields including chemistry, medicine and materials. However, the efficient construction of medium-ring compounds has long been a serious challenge, owing to the unfavorable kinetic and thermodynamic factors. Fortunately, thanks to the unremitting efforts of researchers, there have emerged and been proved effective several new catalytic systems for cycloaddition reactions in recent years, among which the palladium-catalyzed cycloaddition reactions have found rapid development in this field by virtue of high efficiency, high selectivity and atomic economy. This article details global research progress in the past five years on the use of palladium-catalyzed cycloaddition reactions to construct medium-ring compounds, expecting to provide helpful information and insight for the research community.

Key words: medium-ring compounds palladium-catalyzed cycloaddition reactions cyclization reactions reaction mechanisms

出版日期: 2024-06-25 发布日期: 2024-07-17

ZTFLH:

O621

基金资助: 国家重点研发计划(2022YFE0105100);云南省基础研究专项-重点项目(202101AS070049);云南贵金属实验室科技计划项目(YPML-2022050210;YPML-2022050232)

通讯作者: *唐振艳,副研究员,硕士研究生导师,云南省万人计划 “青年拔尖人才”专项人才。2006年河北科技大学环境工程专业本科毕业,2009年昆明贵金属研究所工业催化专业硕士毕业,2013年厦门大学物理化学专业博士毕业。主要从事贵金属均相催化剂制备工艺及关键技术的研发工作。迄今为止,在ACS Catalysis、Physical Chemistry Chemical Physics、Surface Science、Langmuir、Catalysis Today等期刊上发表论文10余篇;授权中国发明专利4篇。tzy@ipm.com.cn

作者简介: 皮晓琳,2019年6月、2022年6月分别于西华大学和云南大学获得理学学士学位和硕士学位。现为稀贵金属综合利用新技术国家重点实验室,云南贵金属实验室有限公司助理工程师,在唐振艳副研究员的指导下进行研究。目前主要从事贵金属新型功能材料的设计与制备。

引用本文:

皮晓琳, 李鸿鹏, 田乙然, 童应成, 倪文若, 袁藤瑞, 唐振艳. 钯催化环加成反应构建中环化合物的研究进展[J]. 材料导报, 2024, 38(12): 22110292-12.
PI Xiaolin, LI Hongpeng, TIAN Yiran, TONG Yingcheng, NI Wenruo, YUAN Tengrui, TANG Zhenyan. Advances in Palladium-Catalyzed Cycloaddition Reactions for the Construction of Medium-ring Compounds. Materials Reports, 2024, 38(12): 22110292-12.

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http://www.mater-rep.com/CN/10.11896/cldb.22110292 或 http://www.mater-rep.com/CN/Y2024/V38/I12/22110292

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