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材料导报  2024, Vol. 38 Issue (11): 22100182-8    https://doi.org/10.11896/cldb.22100182
  高分子与聚合物基复合材料 |
木质素熔融沉积式3D打印的分子结构-流变学响应关系研究进展
姜波1,2,*, 焦欢1, 郭新宇1, 金永灿1,*
1 南京林业大学江苏省林业资源高效加工利用协同创新中心,南京 210037
2 植物纤维功能材料国家林业和草原局重点实验室,福州 350108
Research Progress on Lignin Structure-Melt Rheology Relationship in Fused Deposition Modeling
JIANG Bo1,2,*, JIAO Huan1, GUO Xinyu1, JIN Yongcan1,*
1 Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China
2 National Forestry and Grassland Administration Key Laboratory of Plant Fiber Functional Materials, Fuzhou 350108, China
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摘要 木质素作为自然界储量最大的可再生芳香族生物质资源,开发其高值化加工利用技术是林业生物质产业转型升级的重要途径。近年来,基于3D打印技术制备高性能木质素基复合材料的研究发展迅速。木质素的3D打印可快速、高效构建具有特定功能特性的复合材料,且可灵活调控木质素基复合材料的宏观、微观结构,以使其满足能量传输、药物递送和个性化医疗等需求。然而,由于木质素分子结构复杂多变、分子量分布宽、脆性大等特点,木质素的分子结构-流变学响应关系仍缺乏系统研究,限制了木质素基复合材料的进一步开发和应用。本文基于近年来木质素熔融沉积式3D打印的发展现状,系统总结了木质素分子结构与其熔融流变学的响应关系。首先介绍了木质素的分子结构特性和熔融沉积式3D打印技术,然后重点对比分析了不同木质素分子结构、木质素与热塑性高聚物的共混对其熔融流变学特性和打印性的影响,最后总结了木质素熔融沉积式3D打印面临的挑战,并对木质素熔融沉积式3D打印的发展方向进行了展望,通过更好地理解木质素熔融流变学的构-效关系,促进木质素的高值化利用。
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姜波
焦欢
郭新宇
金永灿
关键词:  木质素  熔融沉积打印  分子结构  熔融流变学  构-效关系    
Abstract: The development of high-value processing and utilization technology for lignin, the most abundant renewable aromatic biomass in nature, is an important way to facilitate the industrial upgrade of forest chemicals and materials. In recent years, 3D printing of lignin has flourished to construct advanced lignin-based materials. The use of 3D printing technologies enables to print lignin into composite materials with desired functional properties and the macro- and microstructures of 3D printed lignin composites can be flexible tuned to meet the requirements of energy, drug delivery, and personalized medicine. However, the unclear structure-rheological relationship caused by the diverse chemical structure, high polydispersity in molecular weight, and rigid structure of lignin greatly limits its performance and applications. Based on the development of fused deposition modeling 3D printing for lignin in last decades, this paper summarizes the structure-melt rheology relationship of lignin and its compo-sites. The lignin structure and the fused deposition modeling technology are firstly discussed and then the effects of different lignin structures and lignin/polymer blends on their melt rheological behavior and printability are vertically reviewed. Finally, the challenges and future directions of lignin fused deposition modeling 3D printing is also highlighted to better understand the structure-melt rheology relationship and to promote the high-value utilization of lignin.
Key words:  lignin    fused deposition modeling    structure    melt rheology    structure-rheology relationship
发布日期:  2024-06-25
ZTFLH:  O636.2  
基金资助: 国家自然科学基金(32201500);江苏省自然科学基金(BK20220431);江苏省高等学校自然科学研究基金(21KJB220001);国家林业和草原局植物纤维功能材料重点实验室开放基金(2022KFJJ05)
通讯作者:  *姜波,南京林业大学轻工与食品学院副教授、硕士研究生导师。2015年获南京林业大学轻化工程专业工学学士学位,2020年获南京林业大学制浆造纸工程博士学位,2022年入选中国科协第八届青年人才托举工程。目前主要从事生物质资源高效转化利用、木质素3D打印等领域的基础研究、材料创制和技术开发工作。发表论文40余篇,包括Nature Sustainability、Advanced Functional Materials、Advanced Science、Small、Bioresource Techno-logy、ACS Sustainable Chemistry & Engineering等。bjiang@njfu.edu.cn;
金永灿,南京林业大学轻工与食品学院教授、博士研究生导师,国际木材科学院院士。1989年毕业于南京林业大学制浆造纸工程专业,1998年获南京林业大学林产化学加工工程博士学位。先后前往东京农工大学、美国北卡罗莱纳州立大学、东京大学等学习进修或合作研究。主要从事生物质资源高效转化及制浆造纸工程等领域的基础研究和技术开发工作。发表论文300余篇,包括Chemical Reviews、Chemical Engineering Journal、Advanced Functional Materials、Bioresource Technology、Carbohydrate Polymers、Food Chemistry等。jinyongcan@njfu.edu.cn   
引用本文:    
姜波, 焦欢, 郭新宇, 金永灿. 木质素熔融沉积式3D打印的分子结构-流变学响应关系研究进展[J]. 材料导报, 2024, 38(11): 22100182-8.
JIANG Bo, JIAO Huan, GUO Xinyu, JIN Yongcan. Research Progress on Lignin Structure-Melt Rheology Relationship in Fused Deposition Modeling. Materials Reports, 2024, 38(11): 22100182-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22100182  或          http://www.mater-rep.com/CN/Y2024/V38/I11/22100182
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