NiFe-P/石墨烯双功能催化剂的有效构建及全解水性能研究

doi:10.11896/cldb.21120112

材料导报

2023, Vol. 37

Issue (13): 21120112-9 https://doi.org/10.11896/cldb.21120112

无机非金属及其复合材料

NiFe-P/石墨烯双功能催化剂的有效构建及全解水性能研究

杨芷奇¹, 孙立^1,2,*, 宋伟明¹, 赵冰^1,2, 叶军¹, 陈朝晖¹, 赵桦萍¹, 王福洋¹

1 齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔 161006
2 黑龙江省表面活性剂与工业助剂重点实验室,黑龙江齐齐哈尔 161006

Effective Construction of the NiFe-P/Graphene Bifunctional Electrocatalyst for Overall Water Splitting

YANG Zhiqi¹, SUN Li^1,2,*, SONG Weiming¹, ZHAO Bing^1,2, YE Jun¹, CHEN Zhaohui¹, ZHAO Huaping¹, WANG Fuyang¹

1 School of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang, China
2 Heilongjiang Provincial Key Laboratory of Surface Active Agent and Auxiliary, Qiqihar 161006, Heilongjiang, China

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摘要为构建低成本、高效的析氢(HER)和析氧(OER)双功能电催化剂,基于基团配位原理,以氧化石墨烯为载体,硝酸镍、铁氰化钾、柠檬酸三钠为原料,通过水热-磷化热解法制备磷化镍铁/石墨烯复合电催化剂(NiFe-P/RGO)。采用SEM、TEM、XRD、XPS和BET多种物理手段对NiFe-P/RGO电催化剂的化学结构和物理形貌进行了表征,并对NiFe-P/RGO电催化剂的碱性全解水性能进行了测试。研究结果表明,高活性NiFe-P与高导电性石墨烯有效复合,极大地增加了传质传荷能力,从本质上提高了催化剂的电催化性能。在HER和OER反应中,NiFe-P/RGO在10 mA/cm²电流密度下的产氢和产氧过电位分别为125 mV和218 mV。将NiFe-P/RGO分别作为阴极和阳极组装成全解水装置,在10 mA/cm²下,其施加电压为1.52 V,并且具有优异的稳定性。

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	杨芷奇
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	叶军
	陈朝晖
	赵桦萍
	王福洋

关键词: NiFe-P 石墨烯双功能催化剂全解水

Abstract: To gain bifunctional electrocatalyst with low cost and high catalytic activity for HER and OER, we used the principle of group coordination, and then the NiFe-P/RGO bifunctional catalyst was successfully prepared by a hydrothermal-phosphatizing pyrolysis method, in which graphite oxide was selected as the host carrier, nickel nitrate, potassium ferricyanide and trisodium citrate were acted as the raw materials. The chemical structure and morphological characterization of as-prepared catalysts were carried out by SEM, TEM, XRD, XPS and BET, respectively. Moreover, the alkaline hydrolysis performance of NiFe-P/RGO electrocatalyst was tested. The results exhibited that the effective recombination between highly active NiFe-P and good conductive RGO can vastly accelerate ion/electron charge transport to increase electrocatalytic performance. For HER and OER, NiFe-P/RGO manifests excellent bifunctional activity with low overpotentials was 125 mV and 218 mV at a current density of 10 mA/cm², respectively. The electrolyzer equipped with the NiFe-P/RGO as both cathode and anode requires only 1.52 V at a current density of 10 mA/cm² with superior catalytic durability.

Key words: NiFe-P graphene bifunctional electrocatalyst overall water splitting

发布日期: 2023-07-10

ZTFLH:

X511

基金资助: 国家自然科学基金(21978140;21501104);黑龙江省博士后资助经费(LBH-Z18231);黑龙江省省属高校基本科研业务费(YSTSXK135409211;YSTSXK201845);黑龙江省表面活性剂与工业助剂重点实验室开放课题基金资助项目(BMHXJKF 007);齐齐哈尔大学研究生创新科研项目(YJSCX2020004)

通讯作者: *孙立,齐齐哈尔大学化学与化学工程学院副教授,硕士研究生导师。2007年7月毕业于哈尔滨学院,获学士学位。2010年7月毕业于黑龙江大学,获硕士学位。2014年7月毕业于黑龙江大学,获博士学位。主要研究领域为过渡金属基纳米材料的制备及能量转换特性研究。目前,已经发表SCI论文10余篇,并且超过1 000次引用。sunli8481@163.com

作者简介: 杨芷奇,2019年7月毕业于哈尔滨学院,获得理学学士学位,现为齐齐哈尔大学化学与化学工程学院应用化学专业硕士研究生,主要研究领域为纳米材料的制备与设计。

引用本文:

杨芷奇, 孙立, 宋伟明, 赵冰, 叶军, 陈朝晖, 赵桦萍, 王福洋. NiFe-P/石墨烯双功能催化剂的有效构建及全解水性能研究[J]. 材料导报, 2023, 37(13): 21120112-9.
YANG Zhiqi, SUN Li, SONG Weiming, ZHAO Bing, YE Jun, CHEN Zhaohui, ZHAO Huaping, WANG Fuyang. Effective Construction of the NiFe-P/Graphene Bifunctional Electrocatalyst for Overall Water Splitting. Materials Reports, 2023, 37(13): 21120112-9.

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http://www.mater-rep.com/CN/10.11896/cldb.21120112 或 http://www.mater-rep.com/CN/Y2023/V37/I13/21120112

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