聚苯乙烯/α-磷酸锆多孔材料制备及油水乳液分离研究

doi:10.11896/cldb.21110076

材料导报

2023, Vol. 37

Issue (16): 21110076-9 https://doi.org/10.11896/cldb.21110076

高分子与聚合物基复合材料

聚苯乙烯/α-磷酸锆多孔材料制备及油水乳液分离研究

黄世杰¹, 赵春霞^1,*, 王硕¹, 黄浩然¹, 李嘉鑫¹, 李辉¹, 向东¹, 李云涛^1,2,*

1 西南石油大学新能源与材料学院,成都 610500
2 西南石油大学油气藏地质开发国家重点实验室,成都 610500

Preparation of Polystyrene/α-Zirconium Phosphate Porous Materials and Separation of Oil-Water Emulsion

HUANG Shijie¹, ZHAO Chunxia^1,*, WANG Shuo¹, HUANG Haoran¹, LI Jiaxin¹, LI Hui¹, XIANG Dong¹, LI Yuntao^1,2,*

1 School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China
2 State Key Lab of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, China

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摘要疏水亲油性多孔材料具有处理和净化含油废水的能力。本工作通过高内相乳液模板法制备得到聚苯乙烯基多孔三维材料(P(St-E)/α-ZrP)。通过扫描电子显微镜(SEM)、全自动压汞仪等对材料的微观结构进行表征,并对其油水分离性能进行测试分析。结果表明,层状纳米粒子α-ZrP能够稳定存在于油包水乳液的分散相中,单体聚合完成后α-ZrP均匀镶嵌在多孔材料骨架上构成粗糙界面。α-ZrP用量为单体质量的5%时,制得的多孔材料具有最佳力学性能和疏水性能,该材料对三氯甲烷的吸附倍率高达54.2。P(St-E)/α-ZrP多孔材料在尺寸筛分效应和α-ZrP电负性协同作用下能够高效分离非离子型和阳离子型油水乳液。实验制备的多孔材料有望用于含乳化油污水的净化处理,在含油废水处理中有潜在的发展前景。

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	黄世杰
	赵春霞
	王硕
	黄浩然
	李嘉鑫
	李辉
	向东
	李云涛

关键词: 油水乳液 α-磷酸锆聚苯乙烯超浓乳液模板多孔材料

Abstract: Hydrophobic andlipophilic porous materials have the ability to treat and purify oil-bearing wastewater. In this work, polystyrene (PSt) based three-dimensional porous materials (P(St-E)/α-ZrP) were prepared by high internal emulsion template method. Microstructure of the prepared materials were characterized by scanning electron microscope (SEM) and automatic mercury injection instrument. Meanwhile, their oil-water separation performance was tested and analyzed. The results showed that layered nanoparticles α-ZrP was stabilized in the dispersed phase of water in oil emulsion. After polymerization of monomers, α-ZrP inlayed on the skeleton of porous material to form a rough interface. The porous material had the best mechanical and hydrophobic properties with 5% α-ZrP incorporation. The adsorption rate of trichlormethane for P(St-E)/α-ZrP5 was as high as 54.2. P(St-E)/α-ZrP porous materials can efficiently separate non-ionic and cationic stabled oil-water emulsion because of the synergistic effects of size selecting effect and electronegativity of α-ZrP. The porous materials prepared in this work are expected to be used in the purification of wastewater containing emulsified oil, and have broad development prospects in the treatment of oil-bearing wastewater.

Key words: oil-water emulsion α-ZrP polystyrene concentrated emulsion template porous material

出版日期: 2023-08-25 发布日期: 2023-08-14

ZTFLH:

TB34

基金资助: 四川省科技计划项目(2022NSFSC0301)

通讯作者: ^*赵春霞,西南石油大学新能源与材料学院副教授,第十三批四川省学术和技术带头人后备人选。2005年6月毕业于河北大学,获得学士学位;2008年6月毕业于四川大学,获得硕士学位;2011年6月毕业于中国科学院成都有机化学研究所,获得博士学位;2011年7月到西南石油大学从事教学和科研工作至今。主要从事高性能高分子纳米复合材料、多功能热固性树脂、能源用新型高分子材料的研究。已在国内外重要刊物上发表论文60多篇(SCI收录40余篇);获准授权专利20余项。polychem@swpu.edu.cn
李云涛,西南石油大学新能源与材料学院教授、博士研究生导师,四川省“百人计划”特聘专家。1994年6月毕业于兰州大学,获得学士学位;1997年6月,毕业于兰州大学,获得硕士学位;2000年6月,毕业于四川大学,获得博士学位;2004年12月毕业于美国德州农工大学,获得博士学位;2004年12月至2006年6月于美国德州农工大学从事博士后研究工作,2006年10月—2010年10月,在美国亨斯曼公司任高级科学家。2010年11月到西南石油大学从事教学和科研工作至今。主要从事高性能高分子材料和新能源用新型高分子材料的研究等。已在国内外重要刊物上发表论文70余篇,获准授权专利近30项。yuntaoli@swpu.edu.cn

作者简介: 黄世杰,2019年6月毕业于西南石油大学,获得学士学位。现为西南石油大学新能源与材料学院材料工程专业研究生。目前主要研究领域为油水分离材料和乳液分离材料。

引用本文:

黄世杰, 赵春霞, 王硕, 黄浩然, 李嘉鑫, 李辉, 向东, 李云涛. 聚苯乙烯/α-磷酸锆多孔材料制备及油水乳液分离研究[J]. 材料导报, 2023, 37(16): 21110076-9.
HUANG Shijie, ZHAO Chunxia, WANG Shuo, HUANG Haoran, LI Jiaxin, LI Hui, XIANG Dong, LI Yuntao. Preparation of Polystyrene/α-Zirconium Phosphate Porous Materials and Separation of Oil-Water Emulsion. Materials Reports, 2023, 37(16): 21110076-9.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.21110076 或 http://www.mater-rep.com/CN/Y2023/V37/I16/21110076

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