Abstract: Metal-organic frameworks (MOFs) are highly-ordered porous network frameworks constructed from metallic nodes and organic ligands linked together with coordination bonds. MOFs have significant potential applications in gas adsorption, storage, catalysis, sensing, magnetism, optics, electrochemistry, drug delivery, etc. because of their large surface area, designable and tunable structures and nature and strength of host-guest interactions. They have become one of the highest-growing types of functional nanostructured porous solids in the past two decades. MOFs as thin films are much more desirable than MOFs as bulk crystals in the development of MOFs-based components and devices. But the synthesis of defect-free MOF films is still a challenge. The methods for MOF film preparation mainly include hydrothermal synthesis, microwave synthesis, ultrasonic synthesis, mechanical ball milling and electrochemical synthesis. Electrochemical synthesis, usually fast, under environmental temperature and pressure, and with less chemical reagents, has obvious advantages over other methods, which are generally considered as time-consuming and under strict conditions. This paper reviews the relative progress in MOF film electrochemical synthesis techniques, anodic synthesis, cathode deposition, indirect bipolar electrodeposition (IBED), galvanic displacement, and electrophoretic deposition (EDP) and their applications over the last decade and highlight advantages and disadvantages of electrochemical synthesis methods above as well as the differences in their techniques and mechanisms.
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2020, Vol. 34 
