加压碳酸化法制备片状纳米碳酸钙及其表征

doi:10.11896/cldb.21110049

材料导报

2023, Vol. 37

Issue (17): 21110049-7 https://doi.org/10.11896/cldb.21110049

无机非金属及其复合材料

加压碳酸化法制备片状纳米碳酸钙及其表征

汤勇¹, 唐名德², 焦妍惠¹, 郭亚宁¹, 韦德恩², 童张法¹, 李立硕^1,*

1 广西大学化学化工学院,南宁 530004
2 崇左南方水泥有限公司广西钙基材料协同创新中心,广西崇左 532200

Preparation and Characterization of Flake-like Nano Calcium Carbonate by Pressurized Carbonation

TANG Yong¹, TANG Mingde², JIAO Yanhui¹, GUO Yaning¹, WEI Deen², TONG Zhangfa¹, LI Lishuo^1,*

1 School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
2 Guangxi Calcium-based Materials Collaborative Innovation Center, Chongzuo South Cement Co., Ltd., Chongzuo 532200, Guangxi, China

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摘要以氢氧化钙和二氧化碳为反应原料,二水合柠檬酸三钠(Na₃C₆H₅O₇·2H₂O)为晶型控制剂,乙醇为助表面活性剂,采用加压碳酸化法成功制备了片状碳酸钙。通过场发射扫描电镜(FESEM)、X射线衍射(XRD)、红外光谱(FTIR)、原子力显微镜(AFM)等手段对样品的形貌和结构进行了表征,并考察了柠檬酸钠添加量、反应温度、乙醇添加量、CO₂压力等对产品的影响。结果表明,在反应温度为100 ℃、柠檬酸钠添加量为8%、乙醇添加量为10 mL和CO₂压力为1.5 MPa的条件下,成功制备了厚度为7~8 nm、宽约为3.5 μm、长约为25 μm、长宽比约为7∶1的片状纳米碳酸钙,产品大小均一,形貌较为规整。片状碳酸钙的晶型为方解石型,比表面积约为27.11 m²·g^-1。加压碳酸化增加了CO₂在溶液中的溶解度,在柠檬酸三钠的作用下定向生成片状纳米碳酸钙。

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	李立硕

关键词: 加压碳酸化片状碳酸钙二水合柠檬酸三钠鼓泡

Abstract: With calcium hydroxide and carbon dioxide as raw materials, trisodium citrate dihydrate as crystal control agents and ethanol as co-surfactant, flake-like calcium carbonate were successful prepared by pressurized carbonation. The morphology and structure of the samples were characterized by FESEM, XRD, FTIR, AFM, etc. And the influences of calcium carbonate morphology are investigated by changing the amount of adding trisodium citrate dehydrate and ethanol, the reaction temperature, the pressure of the CO₂, etc. The results showed that under the conditions of reaction temperature of 100 ℃, sodium citrate content of 8%, ethanol content of 10 mL and CO₂ pressure of 1.5 MPa, flake-like nano calcium carbonate with thickness of about 7—8 nm, width of about 3.5 μm, length of about 25 μm and length to width ratio of about 7∶1 was successfully prepared, and the products were of uniform sizes and relatively regular morphologies. The crystalline form of flake-like calcium carbonate was calcite, and the specific surface area was about 27.11 m²·g^-1. Pressurized carbonation increased the solubility of CO₂ in solution, and under the action of trisodium citrate, flake-like nano calcium carbonate was directionally formed.

Key words: words pressurize carbonation flake-like calcium carbonate trisodium citrate dihydrate bubbling

出版日期: 2023-09-10 发布日期: 2023-09-05

ZTFLH:

TQ13

基金资助: 广西钙基材料协同创新中心项目(CZNF-JSZX20-03);广西碳酸钙产业化工程院公司级科研项目(TSGGCY-201907001)

通讯作者: *李立硕,广西大学化学化工学院副教授、研究生导师。2005年广西大学化学化工学院硕士毕业后留校工作至今,2013年获广西大学化学工艺专业博士学位。目前主要从事纳米材料、高反应性生物半焦制备、碳酸钙反应-结晶过程等方面的研究工作。已在国内外学术期刊发表论文20余篇,获授权专利10项。li_lishuo@163.com

作者简介: 汤勇,2019年6月毕业于河南城建学院,获得工学学士学位。现为广西大学化学化工学院化学工程专业硕士研究生,目前主要从事无机材料的制备和应用方向的研究。

引用本文:

汤勇, 唐名德, 焦妍惠, 郭亚宁, 韦德恩, 童张法, 李立硕. 加压碳酸化法制备片状纳米碳酸钙及其表征[J]. 材料导报, 2023, 37(17): 21110049-7.
TANG Yong, TANG Mingde, JIAO Yanhui, GUO Yaning, WEI Deen, TONG Zhangfa, LI Lishuo. Preparation and Characterization of Flake-like Nano Calcium Carbonate by Pressurized Carbonation. Materials Reports, 2023, 37(17): 21110049-7.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.21110049 或 http://www.mater-rep.com/CN/Y2023/V37/I17/21110049

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