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《材料导报》期刊社  2018, Vol. 32 Issue (8): 1218-1223    https://doi.org/10.11896/j.issn.1005-023X.2018.08.003
  材料研究 |
静电纺羽毛角蛋白/聚乙烯醇/聚氧化乙烯纳米纤维膜的交联改性及表征
陈曼, 何明, 郭妍婷, 尹国强
仲恺农业工程学院化学化工学院,广州 510225
Crosslinking Modification and Characterization of the Electrospun Feather Keratin/Poly(vinyl alcohol)/Poly(ethylene oxide) Nanofibrous Membrane
CHEN Man, HE Ming, GUO Yanting, YIN Guoqiang
College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510225
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摘要 采用氧化法从鸡毛中提取角蛋白(FK),将其与聚乙烯醇(PVA)和聚氧化乙烯(PEO)共混,利用静电纺丝技术成功制备出FK/PVA/PEO三元共混膜。为了增强共混膜的综合性能,加入乙二醛对其进行交联改性,并利用扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)、X射线衍射光谱(XRD)、热重分析(TG)、接触角实验及电子万能试验机对交联前后共混膜的形貌、结构、热稳定性、耐水性以及力学性能进行测试和表征。结果表明:当乙二醛/FK质量比从0%增加至8%时,纤维平均直径由(249.76±38.02) nm增至(399.67±53.44) nm,接触角由(42.1±5.1)°增至(84.9±7.1)°。当乙二醛/FK质量比为6%时,抗拉强度和杨氏模量达到最大,分别为4.57 MPa和6.64 MPa。
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陈曼
何明
郭妍婷
尹国强
关键词:  静电纺丝  羽毛角蛋白  纳米纤维膜  交联改性    
Abstract: The present work focuses on the fabrication and crosslinking modification of a feather keratin/poly(vinyl alcohol)/poly(ethylene oxide) ternary hybrid nanofibrous membrane. We mixed chicken feathers keratin (FK) (pre-extracted from chicken feathers by oxidation method), poly(vinyl alcohol) (PVA) and poly(ethylene oxide) (PEO) to prepare the spinning solution, and then fabricated the FK/PVA/PEO nanofibrous membrane through a electrospinning process. The glyoxal which acted as a crosslin-king agent was also added into the spinning solution in order to improve product’s performance. The fabricated (crosslinking-modified and unmodified) membranes were characterized by using a scanning electron microscope (SEM), a Fourier transform infrared (FT-IR) spectroscope, an X-ray diffractometer (XRD), a thermogravimetric analyzer (TGA), a water contact angle tester and a universal testing machine. The results indicated an increase of average fiber diameter from (249.76±38.02) nm to (399.67±53.44) nm and a contact angle rise from (42.1±5.1) ° to (84.9±7.1) °, whilst the glyoxal/FK mass ratio was raised from 0% to 8%. The hybrid membranes with 6% glyoxal/FK mass ratio showed pleasurable mechanical properties, as the tensile strength and Young’s modulus reached 4.57 MPa and 6.64 MPa, respectively.
Key words:  electrospinning technique    feather keratin    nanofibrous membrane    crosslinking modification
               出版日期:  2018-04-25      发布日期:  2018-05-11
ZTFLH:  O636.9  
  TB324  
基金资助: 广东省科技计划项目(2013B010403029);广东省自然科学基金(2016A030313371)
通讯作者:  尹国强:通信作者,男,博士,教授,主要研究方向为功能高分子材料 E-mail:yingq007@163.com   
作者简介:  陈曼:女,1992年生,硕士研究生,主要研究方向为功能高分子材料 E-mail:1601616084@qq.com
引用本文:    
陈曼, 何明, 郭妍婷, 尹国强. 静电纺羽毛角蛋白/聚乙烯醇/聚氧化乙烯纳米纤维膜的交联改性及表征[J]. 《材料导报》期刊社, 2018, 32(8): 1218-1223.
CHEN Man, HE Ming, GUO Yanting, YIN Guoqiang. Crosslinking Modification and Characterization of the Electrospun Feather Keratin/Poly(vinyl alcohol)/Poly(ethylene oxide) Nanofibrous Membrane. Materials Reports, 2018, 32(8): 1218-1223.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.08.003  或          http://www.mater-rep.com/CN/Y2018/V32/I8/1218
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