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材料导报  2023, Vol. 37 Issue (18): 22050272-6    https://doi.org/10.11896/cldb.22050272
  高分子与聚合物基复合材料 |
SiO2纳米颗粒对环保型泡沫灭火剂稳定性的影响
盛友杰*, 彭云川, 张含灵, 阎灿彬, 李杨, 马文智
西安科技大学安全科学与工程学院,西安 710054
Effect of SiO2 Nanoparticles on Foam Stability of Environmental-friendly Firefighting Foam
SHENG Youjie*, PENG Yunchuan, ZHANG Hanling, YAN Canbin, LI Yang, MA Wenzhi
College of Safety Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
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摘要 本工作以碳氢表面活性剂(APG0810)和短链氟碳表面活性剂(FS-50)为核心组分制备了环保型泡沫灭火剂,系统地研究了SiO2纳米颗粒对泡沫灭火剂溶液性质、起泡性能及泡沫稳定性的影响,分析了SiO2纳米颗粒对泡沫灭火剂稳定性的增强机理。结果表明,SiO2纳米颗粒对泡沫灭火剂的溶液性质与泡沫性能均有较大影响。随纳米颗粒浓度的增加,泡沫灭火剂溶液的表面活性先降低后增加,动态粘度逐渐增加,电导率逐渐降低,而起泡性略微下降。泡沫稳定性随着纳米颗粒浓度的增加而显著增加,达到7%后,泡沫稳定性急剧增加。SiO2纳米颗粒与泡沫灭火剂活性组分在泡沫液膜和Plateau边界中相互作用,形成网状结构聚集体,有效地延缓泡沫析液和粗化,从而增强泡沫的稳定性。本工作的研究结果能够为SiO2纳米颗粒在环保型泡沫灭火剂的研发和应用方面提供理论指导。
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盛友杰
彭云川
张含灵
阎灿彬
李杨
马文智
关键词:  纳米颗粒  氟碳表面活性剂  碳氢表面活性剂  泡沫灭火剂  泡沫稳定性    
Abstract: In the work, a kind of environmentally friendly firefighting foams were prepared based on hydrocarbon surfactant (APG0810) and short chain fluorocarbon surfactant (FS-50). The effect of SiO2 nanoparticles on solution properties, foaming ability and foam stability of the firefighting foams were systematically studied. The enhancement mechanism of SiO2 nanoparticles on foam stability was analyzed. The results show that the SiO2 nanoparticles have a great influence on the solution properties and foam properties of the firefighting foams. The surface activity of the mixed dispersions decreased and then increased with increasing nanoparticle concentration. The dynamic viscosity increases with increasing nanoparticle concentration. The conductivity decreases with increasing nanoparticle concentration. The addition of nanoparticles results in decrease in foaming ability of the mixed dispersions. The foam stability increased significantly with the increase of nanoparticle concentration,and the foam stability increased sharply after reaching 7wt%. The added nanoparticles accumulate in foam bubble films and Plateau borders, effectively delaying foam drainage and coarsening and enhancing foam stability. This study can provide theoretical guidance for the application of nanoparticles in the development of environmentally friendly firefighting foams.
Key words:  nanoparticle    fluorocarbon surfactant    hydrocarbon surfactant    firefighting foam    foam stability
出版日期:  2023-09-25      发布日期:  2023-09-18
ZTFLH:  TQ569  
基金资助: 国家自然科学基金(51904230);陕西省教育厅青年创新团队项目(21JP074)
通讯作者:  *盛友杰,西安科技大学安全科学与工程学院副教授、硕士研究生导师,中国科学技术大学博士,美国宾夕法尼亚大学访问学者。主要从事火灾防治关键技术、环保型多功能水系灭火新材料等方面的研究。近年主持国家自然科学基金青年项目、中国博士后基金面上项目、中国科学技术大学火灾科学国家重点实验室开放课题及陕西省自然科学基础研究计划项目等,参与国家和省部级科研项目8项,发表学术论文50余篇,其中SCI检索41篇,获中国煤炭工业协会科技进步一等奖1项,获美国消防协会和消防工程师协会会刊《Fire technology》2021年度最佳论文奖。youjies@xust.edu.cn   
引用本文:    
盛友杰, 彭云川, 张含灵, 阎灿彬, 李杨, 马文智. SiO2纳米颗粒对环保型泡沫灭火剂稳定性的影响[J]. 材料导报, 2023, 37(18): 22050272-6.
SHENG Youjie, PENG Yunchuan, ZHANG Hanling, YAN Canbin, LI Yang, MA Wenzhi. Effect of SiO2 Nanoparticles on Foam Stability of Environmental-friendly Firefighting Foam. Materials Reports, 2023, 37(18): 22050272-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22050272  或          http://www.mater-rep.com/CN/Y2023/V37/I18/22050272
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