Research Status of Environmental Foam Extinguishing Agent for Liquid Fire
QI Lei1, JIAO Jinqing2, XIONG Jing1, LAI Kezhen1, WEI Yuechang1,*
1 State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, China 2 SINOPEC Research Institute of Safety Engineering Co., Ltd., Qingdao 266071, Shandong, China
Abstract: Traditional aqueous film-forming foam (AFFF) has good extinguishing performance and is the best extinguishing agent for liquid fire extinguishing at present. However, its components involve perfluorooctane sulfonic acid (PFOS) and other substances that are difficult to decompose, which seriously harm the environment. With the improvement of environmental protection policies and regulations in various countries, it is the general trend that PFOS will be replaced comprehensively in the future. In recent years, many researchers at home and abroad are also actively developing environment-friendly foam extinguishing agents. The current research and development mainly include two directions. One is to research and develop environment-friendly foam extinguishing agent containing fluorine, which uses short-chains fluorocarbon surfactant to replace long-chains fluorocarbon surfactant, meeting the demand of fire extinguishing while reducing the harm to the environment. Although the environmental concerns have been solved for the time being, it has a short service life, and there is a lack of direct evidence of being environmentally friendly in the long run. Another is the development of fluorine-free environment-friendly foam extinguishing agent, mainly using hydrocarbon surfactants and other surfactants for compounding, among which silicone surfactants is the most widely used. In this paper, the research progress of environment-friendly foam extinguishing agents used in liquid fire in recent years is summarized, and the fluorine containing and fluorine-free foam extinguishing agents are introduced, respectively. The research status and problems of various environment-friendly foam extinguishing agents are summarized, and their development prospects are analyzed and discussed reasonably. It is expected to provide reference for prepa-ring foam extinguishing agents with better effect, better performance and no harm to the environment.
作者简介: 亓磊,2020年6月于齐鲁工业大学(山东省科学院)获得工学学士学位。现为中国石油大学(北京)理学院博士研究生,在韦岳长教授的指导下进行研究。目前主要研究领域为改性有机硅表面活性剂的环保泡沫灭火剂。 韦岳长,中国石油大学(北京)理学院教授、博士研究生导师。2005年和2008年在济南大学分别获得学士学位和硕士学位,2012年7月在中国石油大学(北京)化学工程与技术专业取得博士学位,2015年在美国堪萨斯大学进行博士后研究工作。主要从事石油加工与利用过程中的环境催化研究,在新型高效致霾机动车尾气PM氧化消除催化剂和光催化还原CO2催化剂的设计、制备及其催化机理等方面取得突出的研究成果。近年来,在有环境催化领域发表论文140余篇,包括Energy & Environmental Science、ACS Catalysis、Applied Catalysis B:Environmental、Angewandte Chemie International Edition、Journal of the American Chemical Society和Journal of Catalysis等。
引用本文:
亓磊, 焦金庆, 熊靖, 赖可溱, 韦岳长. 用于液体火灾的环保泡沫灭火剂研究现状[J]. 材料导报, 2022, 36(20): 22040233-7.
QI Lei, JIAO Jinqing, XIONG Jing, LAI Kezhen, WEI Yuechang. Research Status of Environmental Foam Extinguishing Agent for Liquid Fire. Materials Reports, 2022, 36(20): 22040233-7.
1 Rogula-Kozłowska W, Rakowska J, Walczak A, et al. MATEC Web of Conferences, 2018, 247, 00014. 2 Xu Z S, Guo X, Yan L, et al. Case Studies in Thermal Engineering, 2020, 17, 100578. 3 Hinnant K M, Giles S L, Smith E P, et al. Fire Technology, 2019, 56(4), 1413. 4 Place B J, Field J A. Environmental Science & Technology, 2012, 46(13), 7120. 5 Barzen-Hanson K A, Roberts S C, Choyke S, et al. Environmental Science & Technology, 2017, 51(4), 2047. 6 Rotander A, Toms L M, Aylward L, et al. Environment International, 2015, 82, 28. 7 Ross I. Training, 2021, 9, 06. 8 Sunderland E M, Hu X C, Dassuncao C, et al. Journal of Exposure Science & Environmental Epidemiology, 2019, 29(2), 131. 9 Wang Z Y, Cousins I T, Scheringer M, et al. Environment International, 2015, 75, 172. 10 Jiao J Q, Ying W B, Tan L M, et al. Journal of Natural Science of Heilongjiang University, 2020, 37(6), 706(in Chinese). 焦金庆, 应伟波, 谈龙妹, 等. 黑龙江大学自然科学学报, 2020, 37(6), 706. 11 Dubocq F, Wang T, Yeung L W Y, et al. Environmental Science & Technology, 2020, 54(1), 245. 12 Banerjee A, Liu Y. Langmuir, 2021, 37(30), 8937. 13 Back G G, Farley J P. Fire protection research foundation,Quincy, MA, 2020. 14 Jiao J Q. Safety Health & Environment, 2021, 21(4), 1(in Chinese). 焦金庆. 安全、健康和环境, 2021, 21(4), 1. 15 Jiang N. Investigation on seawater-resistant aqueous film-forming foam based on short-chain fluorocarbon and hydrocarbon surfactants. Ph.D. Thesis, University of Science and Technology of China, China, 2021(in Chinese). 姜宁. 基于短链碳氟-碳氢复配体系的耐海水型水成膜泡沫灭火剂研究. 博士学位论文, 中国科学技术大学, 2021. 16 Sheng Y J. lnvestigation on fire-fighting foam based on mixture of hydrocarbon and silicone surfactants. Ph.D. Thesis, University of Science and Technology of China, China, 2018(in Chinese). 盛友杰. 碳氢和有机硅表面活性剂复配体系为基剂的泡沫灭火剂研究. 博士学位论文, 中国科学技术大学, 2018. 17 Wu N, Cao Q, Zhang L C.Fire Science and Technology, 2020, 39(7), 997(in Chinese). 吴楠, 曹青, 张连超.消防科学与技术, 2020, 39(7), 997 18 Wang P.Fire Technology, 2014, 51(3), 503. 19 Sheng Y J, Wang Q H, Zhao Y L, et al. Fire Technology, 2020, 56(3), 1059. 20 Yu X Y, Jiang N, Miao X Y, et al. Process Safety and Environmental Protection, 2020, 133, 201. 21 Hinnant K M, Ananth R, Farley J P, et al. Naval Research Laboratory, Washingtion,DC, 2020, 20, 10031. 22 Hu B, Liu F Y, Zhang R. Environmental Protection of Chemical Industry, 2020, 40(6), 573(in Chinese). 胡彪, 刘付永, 张荣, 等. 化工环保, 2020, 40(6), 573. 23 Wang S.IOP Conference Series: Earth and Environmental Science, IOP Publishing, 2017, 61(1), 012135. 24 Hao T Z.Guangdong Chemical Industry, 2021, 48(24), 73(in Chinese). 郝廷柱. 广东化工, 2021, 48(24), 73. 25 Dhangar K, Kumar M. Contaminants in Drinking and Wastewater Sources, 2021, 18,405. 26 Wei C L, Wang Q, Song X, et al. Ecotoxicology and Environmental Safety, 2018, 152, 141. 27 Wang Q, Zhao Z, Ruan Y, et al. Science of the Total Environment, 2018, 645, 596. 28 Krafft M P, Riess J G. Current Opinion in Colloid & Interface Science, 2015, 20(3), 192. 29 Peshoria S, Nandini D, Tanwar R K, et al. Environmental Chemistry Letters, 2020, 18(4), 1277. 30 Sha M,Xing P, Jiang B.Chinese Chemical Letters, 2015, 26(5), 491. 31 Jiang N, Sheng Y J, Li C H, et al. Journal of Molecular Liquids, 2018, 268, 249. 32 Jia X H, Bo H D, He Y H. Chemical Papers, 2019, 73(7), 1777. 33 Chen Y G, Bo H D, Jia X H, et al. Fire Science and Technology, 2019, 38(4), 538(in Chinese). 陈勇刚, 薄海东, 贾旭宏, 等. 消防科学与技术, 2019, 38(4), 538. 34 Yang Y W, Peng M Y, Sha M, et al. Journal of Surfactants and Detergents, 2021, 25(2), 205. 35 Yang Y W, Fang J Q, Sha M, et al. Chemical Papers, 2021, 75(12), 6241. 36 Yu X Y, Jiang N, Miao X Y, et al. Colloids and Surfaces A-Physicoche-mical and Engineering Aspects, 2020, 591, 124545. 37 Sheng Y J, Yan C B, Li Y, et al. Gels, 2021, 7(4), 179. 38 Jiang N, Yu X Y, Sheng Y J, et al. Chemical Engineering Science, 2020, 216, 115474. 39 Dlugogorski B Z, Schaefer T H. Fire Safety Journal, 2021,120,103288. 40 Liu H, Zhang T W, Zhang C W, et al. E3S Web of Conferences, 2021, 237, 01009. 41 Sheng Y J, Xue M H, Ma L, et al. Fire Technology, 2021, 57(5), 2079. 42 Sheng Y J, Jiang N, Lu S X, et al. Journal of Molecular Liquids, 2019, 296, 111836. 43 Jia X H, Luo Y Z, Huang R, et al. Scientific Reports, 2021, 11(1), 1148 44 Yu X Y, Li F, Fang H S, et al. Journal of Molecular Liquids, 2021, 327, 114811. 45 Hinnant K M,Conroy M W, Ananth R.Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2017, 522, 1. 46 Giles S L, Snow A W, Hinnant K M, et al. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 2019, 579, 123660. 47 Petkova B, Tcholakova S, Chenkova M, et al. Advances in Colloid and Interface Science, 2020, 276, 102084. 48 Zhang L, Tian L L, Du H L, et al. Langmuir, 2017, 33(29), 7305. 49 Hinnant K M, Giles S L, Snow A W, et al. Journal of Surfactants and Detergents, 2018, 21(5), 711. 50 Hetzer R H, Kümmerlen F, Wirz K, et al. Fire Safety Science, 2014, 11, 1261. 51 Pukale D D, Bansode A S, Jadhav N L, et al. Tenside Surfactants Detergents, 2019, 56(4), 268. 52 Xiao G, Lei L, Chen C, et al. Journal of Nanoelectronics and Optoelectronics, 2020, 15(7), 884. 53 Wang S. Earth and Environmental Science, 2019, 295(3), 032072. 54 Tan J L,Xiao M H, Hu Q. The Journal of Physical Chemistry B, 2019, 123(16), 3543. 55 Sheng Y J, Jiang N, Lu S X, et al. Colloids and Surfaces A-Physicoche-mical and Engineering Aspects, 2018, 552, 1. 56 Ananth R, Snow A W, Hinnant K M, et al. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 2019, 579, 123686. 57 Rafati R,Haddad A S, Hamidi H. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 2016, 509, 19. 58 Sobolciak P, Popelka A, Tanvir A, et al. Water, 2021, 13(5), 652. 59 Li Y, Xiao G, Chen C, et al. Physicochemical and Engineering Aspects, 2021, 627, 127147. 60 Yu X Y, Lin Y R, Li F, et al. Chemical Engineering Science, 2022, 250, 117378.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2022, Vol. 36 
