304不锈钢在熔融多硫化钠中的高温腐蚀行为研究

doi:10.11896/cldb.22010026

材料导报

2023, Vol. 37

Issue (14): 22010026-5 https://doi.org/10.11896/cldb.22010026

金属与金属基复合材料

304不锈钢在熔融多硫化钠中的高温腐蚀行为研究

姚艺, 任延杰^*, 彭玉宬, 陈荐, 邱玮, 周立波

长沙理工大学能源与动力工程学院,长沙 410114

Study on High-temperature Corrosion Behavior of 304 Stainless Steel in Molten Sodium Polysulfide

YAO Yi, REN Yanjie^*, PENG Yucheng, CHEN Jian, QIU Wei, ZHOU Libo

Department of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410114, China

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摘要钠硫电池不锈钢集流体材料在熔融多硫化钠中易发生高温腐蚀,影响电池的性能并引发安全问题。本工作采用电化学阻抗谱技术研究了304不锈钢在350 ℃熔融多硫化钠熔盐中的高温腐蚀行为,结合微观组织分析,探索其高温腐蚀机理。结果表明,304不锈钢的电化学阻抗谱由高频段的容抗弧和低频段的直线组成,呈典型的扩散反应控制。电荷转移电阻较小,介于0.918~2.014 Ω·cm²之间,表明不锈钢的腐蚀速率较快。腐蚀产物层主要由外层的FeS₂、FeNiS₂和内层的Cr₂S₃组成。在腐蚀过程中,合金表面的产物膜经历生长、溶解与脱落的过程。

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	周立波

关键词: 钠硫电池集流体 304不锈钢电化学阻抗谱高温腐蚀

Abstract: The stainless steel current collector of sodium-sulfur batteries is prone to suffer high-temperature corrosion in molten sodium polysulfide, which affects the performance of the battery. In this work, the high-temperature corrosion behavior of 304 stainless steel molten sodium polysulfide molten salt at 350 ℃ was studied by electrochemical impedance spectroscopy (EIS). Combined with microstructure analysis, the high-temperature corrosion mechanism was investigated. Electrochemical impedance spectroscopy of 304 stainless steel corroded in the molten sodium polysulfide is composed of the capacitive arc in the high frequency zone and the straight line in the low frequency zone, which shows a typical diffusion controlled reaction. The charge transfer resistance is between 0.918 Ω·cm² and 2.014 Ω·cm², indicating that 304 stainless steel is apt to corrode in the molten sodium polysulfide. The corrosion scale is mainly composed of FeS₂, FeNiS₂ outer layer, and inner layer Cr₂S₃. During the corrosion process, the product film on the surface of the alloy undergoes growth, dissolution and shedding.

Key words: sodium-sulfur battery current collector 304 stainless steel electrochemical impedance spectroscopy high temperature corrosion

出版日期: 2023-07-25 发布日期: 2023-07-24

ZTFLH:

TG178

基金资助: 国家自然科学基金(51771034);湖南省自然科学基金(2020JJ4610)

通讯作者: *任延杰,长沙理工大学教授,2001年6月毕业于长春工业大学获得工学学士学位,2004年6月毕业于长春工业大学获材料学硕士学位,2008年毕业于中国科学院金属研究所获材料学博士学位。主要从事动力设备的腐蚀与防护、金属的表面改性领域的研究。近年来在Corrosion Science、Journal of Power Sources、International Journal of Hydrogen Energy等国内外刊物上发表论文40余篇。参与完成国家“973”项目子课题1项。目前主持国家自然科学基金、湖南省自然科学基金项目等10余项;主编及参编专著各1部,申请并获批发明专利8项。yjren@csust.edu.cn

作者简介: 姚艺,2019年6月本科毕业于长沙理工大学城南学院,获得工学学士学位,2019年9月进入长沙理工大学能源与动力工程学院攻读硕士,在任延杰教授的指导下主要从事金属的腐蚀与防护研究。

引用本文:

姚艺, 任延杰, 彭玉宬, 陈荐, 邱玮, 周立波. 304不锈钢在熔融多硫化钠中的高温腐蚀行为研究[J]. 材料导报, 2023, 37(14): 22010026-5.
YAO Yi, REN Yanjie, PENG Yucheng, CHEN Jian, QIU Wei, ZHOU Libo. Study on High-temperature Corrosion Behavior of 304 Stainless Steel in Molten Sodium Polysulfide. Materials Reports, 2023, 37(14): 22010026-5.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22010026 或 http://www.mater-rep.com/CN/Y2023/V37/I14/22010026

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