(Fe81.5Co1.5Ga17)100-xTbx合金结构及其磁性能

doi:10.11896/cldb.20120138

材料导报

2022, Vol. 36

Issue (5): 20120138-5 https://doi.org/10.11896/cldb.20120138

金属与金属基复合材料

(Fe_81.5Co_1.5Ga₁₇)_100-xTb_x合金结构及其磁性能

张光睿¹, 姚特^1,2, 龚沛², 乔禹¹, 王婷婷¹, 梁雨萍¹, 郝宏波¹

1 包头稀土研究院,白云鄂博稀土资源研究与综合利用国家重点实验室,内蒙古包头 014030
2 内蒙古工业大学材料科学与工程学院,呼和浩特 010051

The Structure and Magnetic Properties of (Fe_81.5Co_1.5Ga₁₇)_100-xTb_x Alloys

ZHANG Guangrui¹, YAO Te^1,2, GONG Pei², QIAO Yu¹, WANG Tingting¹, LIANG Yuping¹, HAO Hongbo¹

1 State Key Laboratory for Research and Comprehensive Utilization of Rare Earth Resources in Bayan Obo District, Baotou Research Institute of Rare Earths, Baotou 014030,Inner Mongolia, China
2 School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

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摘要制备(Fe_81.5Co_1.5Ga₁₇)_100-xTb_x(x=0,0.05,0.10,0.15,0.20)系列合金铸锭,探究了Tb元素添加对Fe_81.5Co_1.5Ga₁₇合金结构及其磁性能的影响。结果表明,该系列合金均以无序α-Fe体心立方结构为主,加入Tb元素后合金晶格常数增加,I₂₀₀/I₁₁₀相对峰强度变化与晶格常数变化趋势一致,合金在[100]晶向择优取向。Tb元素的添加使合金析出富Tb相,并使合金晶粒细化。随着Tb元素含量的增加,合金中分布的富Tb相由分散状态逐渐变为连续的网状结构,并产生枝状晶。(Fe_81.5Co_1.5Ga₁₇)_100-xTb_x合金的饱和磁致伸缩系数随x值的增大呈先增大后减小的趋势,x=0.10时合金的饱和磁致伸缩系数达到217×10^-6,相比x=0的合金提升11%。该系列合金中,当磁场小于40 kA/m时,x=0的合金的磁致伸缩率最大;当磁场为40~80 kA/m时,x=0.10的合金的磁致伸缩率最大;当磁场为80~120 kA/m时,x=0.20的合金的磁致伸缩率最大;磁场大于120 kA/m后,合金的磁致伸缩基本达到饱和,x=0.10,0.15的合金具有高饱和磁致伸缩系数。该系列合金饱和磁化强度值随Tb元素的增加先增后降,x=0.05时合金的饱和磁化强度达到最大,为210.06 emu/g。

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关键词: Fe-Co-Ga合金 Tb元素添加富Tb相磁致伸缩磁性能

Abstract: The ingots of (Fe_81.5Co_1.5Ga₁₇)_100-xTb_x(x=0,0.05,0.10,0.15,0.20) series alloys were prepared, and the effects of Tb element addition on the structure and magnetic properties of Fe_81.5Co_1.5Ga₁₇ alloy were investigated. The results show that the disordered α-Fe body centered cubic structure is the main structure in this series of alloys, the lattice constant of the alloys increase with the addition of Tb element, the change of relative peak strength is consistent with the change trend of lattice constant, alloy preferred orientation in[100]crystal direction. The addition of Tb element precipitates Tb-rich phase and makes the alloy grain refined. With the increase of Tb element content, the Tb-rich phase distribution in the alloy gradually changes from a dispersed state to a continuous network structure and produces dendritic crystals. The saturated magnetostrictive coefficient of the alloys increase first and then decreases with the increase of x value. When x=0.10, the saturated magnetostrictive coefficient of the alloy reached 217×10^-6, compared with x=0 alloy, the saturated magnetostrictive coefficient increased by 11%. In this series of alloys, when the magnetic field is less than 40 kA/m, the magnetostrictive rate of x=0 alloy is the highest. When the magnetic field is 40—80 kA/m, x=0.10 alloy magnetostriction rate is the highest. When the magnetic field range is 80—120 kA/m, the magnetostrictive rate of the alloy x=0.20 is the highest. When the magnetic field is greater than 120 kA/m, the alloy magnetostrictive basically reaches saturation, x=0.10, 0.15 alloy has high saturation magnetostrictive coefficient. The saturated magnetization value of this series of alloys increases first and then decreases with the increase of Tb elements. When x=0.05, the saturated magnetization value of the alloys reaches the maximum value of 210.06 emu/g.

Key words: Fe-Co-Ga alloy Tb element addition Tb-rich phase magnetostriction magnetic property

出版日期: 2022-03-10 发布日期: 2022-03-08

ZTFLH:

TB34

基金资助: 内蒙古自治区自然科学基金重大项目(2018ZD10)

通讯作者: hhbo1981@126.com

作者简介: 张光睿,包头稀土研究院,高级工程师。2005年毕业于兰州大学,2011年获河北工业大学工程硕士学位。主要从事稀土磁致伸缩材料的研发、制备及应用研究工作。
郝宏波,包头稀土研究院,高级工程师,2004年毕业于内蒙古大学,同年进入包头稀土研究院稀土功能材料所工作至今,主要从事磁致伸缩材料研发,重点研究方向为材料的磁致伸缩性能、机理;稀土元素添加对合金性能的影响规律及其机理;合金的制备工艺及产业化技术;磁致伸缩材料的应用。工作以来主持及参加了国家、省市级项目30余项,发表及参与发表科技论文40余篇,授权专利14项,受理专利20项。

引用本文:

张光睿, 姚特, 龚沛, 乔禹, 王婷婷, 梁雨萍, 郝宏波. (Fe_81.5Co_1.5Ga₁₇)_100-xTb_x合金结构及其磁性能[J]. 材料导报, 2022, 36(5): 20120138-5.
ZHANG Guangrui, YAO Te, GONG Pei, QIAO Yu, WANG Tingting, LIANG Yuping, HAO Hongbo. The Structure and Magnetic Properties of (Fe_81.5Co_1.5Ga₁₇)_100-xTb_x Alloys. Materials Reports, 2022, 36(5): 20120138-5.

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http://www.mater-rep.com/CN/10.11896/cldb.20120138 或 http://www.mater-rep.com/CN/Y2022/V36/I5/20120138

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