Please wait a minute...
材料导报  2022, Vol. 36 Issue (1): 20100129-5    https://doi.org/10.11896/cldb.20100129
  高分子与聚合物基复合材料 |
Ptn-CsxWO3/PNIPAM热致调光材料的制备及其隔热性能研究
张浩源, 刘敬肖, 史非, 刘素花, 宋昕
大连工业大学纺织与材料工程学院,新材料与材料表面改性重点实验室,辽宁 大连 116034
Preparation of Ptn-CsxWO3/PNIPAM Thermally Light-adjusting Material and Its Heat-insulation Performance
ZHANG Haoyuan, LIU Jingxiao, SHI Fei, LIU Suhua, SONG Xin
Key Laboratory of New materials and Material Surface Modification, School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, Liaoning, China
下载:  全 文 ( PDF ) ( 4760KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 为获得具有优异热致调光性能的Ptn-CsxWO3/PNIPAM(聚N-异丙基丙烯酰胺)复合材料,以二水合钨酸钠、硫酸铯和氯铂酸为原料,以低温溶剂热法制备了Ptn-CsxWO3粉体;将制得的Ptn-CsxWO3粉体与PNIPAM水凝胶前驱液混合,在一定条件下制备了Ptn-CsxWO3/PNIPAM复合水凝胶,且对复合水凝胶的形貌、透过率和隔热性能进行了研究。结果表明,n(Pt)/n(W)=0.006时所制备的Pt0.006-Cs0.3WO3薄膜具有最好的近红外遮蔽性能;所制备的Ptn-CsxWO3/PNIPAM复合凝胶具有良好的热致调光功能,且其近红外遮蔽率比纯Ptn-CsxWO3薄膜高。隔热性能测试表明,Ptn-CsxWO3/PNIPAM复合凝胶夹层玻璃最大隔热温差可达普通玻璃的三倍,且Ptn-CsxWO3粒子掺入量越多,其保温隔热性能越强。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
张浩源
刘敬肖
史非
刘素花
宋昕
关键词:  Ptn-CsxWO3  PNIPAM  热致调光  近红外遮蔽  隔热    
Abstract: In order to obtain Ptn-CsxWO3/PNIPAM hydrogel composite materials with excellent thermally light-adjusting performance, Ptn-CsxWO3 powders were prepared by low temperature solvothermal method using sodium tungstate dihydrate, cesium sulfate and chloroplatinic acid as raw materials, and then the Ptn-CsxWO3/PNIPAM composite hydrogels were prepared under certain conditions from the mixture of Ptn-CsxWO3 powders with the precursor of PNIPAM hydrogel. The morphology, transmittance and heat insulation performance of the composite hydrogel were investigated. The results indicate that the Pt0.006-Cs0.3WO3 film prepared at n(Pt)/n(W)=0.006 exhibits the best near-infrared shielding perfor-mance, and the as-prepared Ptn-CsxWO3/PNIPAM composite hydrogel has excellent light-adjusting function, and its near-infrared shielding rate is higher than that of pure Ptn-CsxWO3 film. The thermal insulation measurement results indicate that the maximum heat insulation temperature difference of Ptn-CsxWO3/PNIPAM composite film is 3 times that of ordinary glass, and the higher the concentration of Ptn-CsxWO3 particles, the stronger the thermal insulation performance.
Key words:  Ptn-CsxWO3    PNIPAM    thermally light-adjusting    near infrared shielding    heat insulation
出版日期:  2022-01-13      发布日期:  2022-01-13
ZTFLH:  TU55  
基金资助: 国家自然科学基金项目(51778098);大连市科技发展补助资金项目([2016]415);住房城乡建设部科学技术项目(2015-K1-042);大连市科技创新基金计划(2018J12SN066)
通讯作者:  drliu-shi@dlpu.edu.cn   
作者简介:  张浩源,2019年毕业于大连工业大学,获得工学学士学位。现为大连工业大学纺织与材料工程学院硕士研究生,在刘敬肖教授的指导下进行研究,目前主要研究方向为具有近红外遮蔽性能的无机纳米粒子及其复合隔热材料的制备。
刘敬肖,2001年毕业于大连理工大学材料学专业,获工学博士学位,现为大连工业大学教授、硕士研究生导师。2004年入选辽宁省百千万人才千人层次,2006年获评为辽宁省优秀青年骨干教师,2008—2009年曾在日本东北大学作为高级访问学者进行科研工作,现为国际材料领域多个核心期刊杂志的稿件评审专家。主要研究方向包括生态环境友好材料、特种玻璃与陶瓷及功能复合材料(含生物医用材料)。近几年,主持及参与完成国家自然科学基金、住房城乡建设部科技项目、教育部留学归国人员科研启动基金等多项研发项目。已对环境水污染及空气净化、特种玻璃与陶瓷、介孔气凝胶材料、红外线遮蔽和隔热节能等领域相关材料进行了基础理论及应用研究,在生物医用材料、环境光催化材料、功能玻璃陶瓷、气凝胶和纳米粒子合成方面已积累丰富的研究经验与研究成果。目前,已与多家企业建立了科技开发合作关系,拥有授权发明专利16项。
引用本文:    
张浩源, 刘敬肖, 史非, 刘素花, 宋昕. Ptn-CsxWO3/PNIPAM热致调光材料的制备及其隔热性能研究[J]. 材料导报, 2022, 36(1): 20100129-5.
ZHANG Haoyuan, LIU Jingxiao, SHI Fei, LIU Suhua, SONG Xin. Preparation of Ptn-CsxWO3/PNIPAM Thermally Light-adjusting Material and Its Heat-insulation Performance. Materials Reports, 2022, 36(1): 20100129-5.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20100129  或          http://www.mater-rep.com/CN/Y2022/V36/I1/20100129
[1] Li Z R, Xu W P, Ju J L, et al.Heating Ventilating & Air Conditioning,2015, 45(5),74(in Chinese).
李峥嵘, 徐伟鹏, 句俊玲, 等.暖通空调,2015, 45(5),74.
[2] He Y F, Xu G, Zhu J, et al.Micronanoelectronic Technology,2008(7),387(in Chinese).
何云富, 徐刚, 朱俊, 等.微纳电子技术,2008(7),387.
[3] Liu C, Cao X, Kamyshny A, et al.Journal of Colloid and Interface Science, 2014, 427, 49.
[4] Long H, He X, Tian L, et al.China Building Materials Science & Technology, 2015, 24(2),78(in Chinese).
龙辉,何孝,田路.中国建材科技,2015,24(2),78.
[5] Gao H, Jiang G Y, Zhang D, et al.Journal of Functional Materials, 2010, 41(S3),511(in Chinese).
高虹, 蒋国瑜, 张东, 等.功能材料, 2010, 41(S3),511
[6] Xu Q, Liu J X, Shi F, et al.Journal of Dalian Dalian Polytechnic University, 2015, 34(1),55(in Chinese).
徐强, 刘敬肖, 史非, 等.大连工业大学学报, 2015, 34(1),55.
[7] Ning W W, Zhang X, Chang H H, et al.Modern Chemical Industry, 2019, 39(4),137(in Chinese).
宁雯雯, 张笑, 常宏宏, 等.现代化工, 2019, 39(4),137.
[8] Peng Z J, Liu J X, Shi F, et al.Journal of the Chinese Ceramic Society, 2012, 40(6),806(in Chinese).
彭战军, 刘敬肖, 史非, 等.硅酸盐学报, 2012, 40(6),806.
[9] Lv W Z, Zheng W M, Qiu Q, et al.Fine Chemicals,2018,35(8),1278(in Chinese).
吕维忠, 郑威猛, 邱琦, 等.精细化工,2018,35(8),1278.
[10] Liu J X, Ran S, Fan C Y, et al.Solar Energy,2019,178,17.
[11] Chen L, Lam S, Zeng Q, et al. The Journal of Physical Chemistry C, 2012, 116(21),11722.
[12] Zhu Y T. Preparation of cesium tungsten bronze-paraffin composite material and research on its solar energy capture and storage performance.Master's Thesis, Taiyuan University of Technology,China,2019(in Chinese).
朱玉婷. 铯钨青铜—石蜡复合材料的制备及其太阳能捕获与存储性能研究. 硕士学位论文, 太原理工大学,2019.
[13] Shi F, Liu J, Dong X, et al.Journal of Materials Science & Technology, 2014, 30(4), 342.
[14] Zhang B, Hou C Y, Wang H P, et al.Journal of Inorganic Materials,2018,33(11),1232(in Chinese).
张斌, 侯成义, 汪浩鹏, 等.无机材料学报,2018, 33(11),1232.
[15] Islam M R, Ahiabu A, Li X, et al.Sensors, 2014, 14(5),8984.
[16] Xue C, Yonet-Tanyeri N, Brouette N, et al. Langmuir, 2011, 27(14),8810.
[17] You Y, Tang C, Zhang G, et al.Journal of Biomedical Materials Research Part B Applied Biomaterials, 2019, 107(7),1786.
[18] Wu M C, ShiY S, Li R Y, et al.ACS Applied Materials & Interfaces,2018, 10(46),39818.
[19] Ke Y, Zhou C, Zhou Y, et al.Advanced Functional Materials, 2018, 28(22), 1800113.
[20] Lee H Y,Cai Y,Bi S,et al. ACS Applied Materials & Interfaces, 2017, 9(7),6054.
[21] Wang K, Kang L T, Chen S, et al.Journal of Inorganic Materials,2014,29(5), 550(in Chinese).
王琨, 康利涛, 陈石, 等.无机材料学报,2014, 29(5), 550.
[1] 董桂伟, 赵国群, 丁汪洋, 王桂龙, 张磊. 基于多阶压力控制的双峰泡孔聚合物发泡行为及性能[J]. 材料导报, 2022, 36(2): 20050168-5.
[2] 路畅, 陈洪运, 傅梁杰, 田光燕, 张红, 梁金生, 杨华明. 铁尾矿制备新型建筑材料的国内外进展[J]. 材料导报, 2021, 35(5): 5011-5026.
[3] 苏力军, 赵佳明, 王瑞杰, 郭慧, 宋寒, 李文静, 杨洁颖. 夹层结构气凝胶外防热材料的制备及应用技术研究[J]. 材料导报, 2020, 34(Z2): 157-159.
[4] 刘国熠, 赵晓明, 刘元军, 谌玉红. 不同隔热填料对双层涂层柔性复合材料热防护性能的影响[J]. 材料导报, 2020, 34(8): 8194-8199.
[5] 瑚佩, 姜勇刚, 张忠明, 冯军宗, 李良军, 冯坚. 耐高温、高强度隔热复合材料研究进展[J]. 材料导报, 2020, 34(7): 7082-7090.
[6] 郭建业, 赵英民, 吴朝军, 李文静, 杨洁颖, 张丽娟, 苏力军. 温度对石英纤维毡隔热性能的影响[J]. 材料导报, 2020, 34(24): 24019-24022.
[7] 张倩, 郑振荣, 赵晓明, 毛科铸, 罗丽娟. 高温下涂层织物传热过程的数值模拟[J]. 材料导报, 2020, 34(16): 16167-16171.
[8] 张凤云, 姜勇刚, 冯军宗, 李良军, 冯坚. 快速制备纳米SiO2粉末基隔热复合材料的研究进展及展望[J]. 材料导报, 2020, 34(11): 11043-11048.
[9] 郭建业, 赵英民, 张丽娟, 苏力军, 李文静, 杨洁颖. 高温可重复使用二氧化硅气凝胶复合材料性能研究[J]. 材料导报, 2019, 33(z1): 202-205.
[10] 张文华, 吕毓静, 刘鹏宇. EPS混凝土研究进展综述[J]. 材料导报, 2019, 33(13): 2214-2228.
[11] 舒心, 刘朝辉, 丁逸栋, 杨宏波, 罗平. 纳米SiO2气凝胶的制备及保温隔热性应用研究进展[J]. 《材料导报》期刊社, 2018, 32(5): 788-795.
[12] 胡耀强, 陈法锦, 刘海宁, 张慧芳, 吴志坚, 叶秀深. 聚N-异丙基丙烯酰胺水凝胶的制备及热致聚集行为[J]. 《材料导报》期刊社, 2018, 32(14): 2491-2496.
[1] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[2] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[3] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[4] ZHANG Le, ZHOU Tianyuan, CHEN Hao, YANG Hao, ZHANG Qitu, SONG Bo, WONG Chingping. Advances in Transparent Nd∶YAG Laser Ceramics[J]. Materials Reports, 2017, 31(13): 41 -50 .
[5] CHEN Bida, GAN Guisheng, WU Yiping, OU Yanjie. Advances in Persistence Phosphors Activated by Blue-light[J]. Materials Reports, 2017, 31(21): 37 -45 .
[6] ZHANG Yong, WANG Xiongyu, YU Jing, CAO Weicheng,FENG Pengfa, JIAO Shengjie. Advances in Surface Modification of Molybdenum and Molybdenum Alloys at Elevated Temperature[J]. Materials Reports, 2017, 31(7): 83 -87 .
[7] FANG Sheng, HUANG Xuefeng, ZHANG Pengcheng, ZHOU Junpeng, GUO Nan. A Mechanism Study of Loess Reinforcing by Electricity-modified Sodium Silicate[J]. Materials Reports, 2017, 31(22): 135 -141 .
[8] ZHOU Dianwu, HE Rong, LIU Jinshui, PENG Ping. Effects of Ge, Si Addition on Energy and Electronic Structure of ZrO2 and Zr(Fe,Cr)2[J]. Materials Reports, 2017, 31(22): 146 -152 .
[9] HUANG Wenxin, LI Jun, XU Yunhe. Research Progress on Manganese Dioxide Based Supercapacitors[J]. Materials Reports, 2018, 32(15): 2555 -2564 .
[10] SU Li, NIU Ditao, LUO Daming. Research of Coral Aggregate Concrete on Mechanical Property and Durability[J]. Materials Reports, 2018, 32(19): 3387 -3393 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed