Research Progress in Preparation and Purification of Fullerene
WANG Hao1,2, ZONG Nan1,3, CHENG Zhongzheng1, BO Yong1, PENG Qinjun1,3
1 Key Laboratory of Solid state laser, Chinese Academy of Sciences, Institute of Physical and Chemical Technology, Chinese Academy of Sciences, Beijing 100190, China 2 School of Materials Science and Optoelectronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China 3 Key Laboratory of Functional Crystal and Laser Technology, Chinese Academy of Sciences, Institute of Physical and Chemical Technology, Chinese Academy of Sciences, Beijing 100190, China
Abstract: Fullerene are hollow molecules arranged by carbon five-membered ring and six-membered ring, which are the third allotrope of carbon discovered after graphite and diamond. Due to their unique cage structure and special physical and chemical properties, fullerenes are of high application research value. In this paper, we review the preparation and separation methods of fullerenes, analyze the factors affecting the efficiency of different methods, and analyze the advantages and disadvantages of various methods. Finally, we propose the prospect of the preparation and purification technology of fullerenes.
1 Zhang Y, Yin Q Z.Proceedings of the National Academy of Sciences of the United States of America, 2012, 109(48), 19579. 2 Pace N R.Proceedings of the National Academy of Sciences, 2001, 98(3), 805. 3 Kroto H W, Heath J R, Obrien S C, et al.Nature, 1985, 318(14), 162. 4 Nasir S, Hussein M Z, Zainal Z, et al. Materials, 2018, 11 (2), 295. 5 Green M A, Dunlop E D, Dean H L, et al. Progress in Photovoltaics: Research and Applications, 2019, 27(7), 565. 6 Mousavi S Z, Nafisi S, Maibach H I. Nanomedicine: Nanotechnology, Biology, and Medicine, 2017, 13(3), 1071. 7 Kanbur Y, Tayfun U. Journal of Elastomers and Plastics, 2019, 51(3), 262. 8 Pan Y, Liu X J, Zhang W, et al.Applied Catalysis B: Environmental, 2020, 265, 118579. 9 Capone M, Fabrizio M, Castellani C, et al. Reviews of Modern Physics, 2009, 81(2), 943. 10 Zhao Y F, Kim Y H, Dillon AC, Heben M J,Zhang S B. Physical review letters, 2005, 94(15), 155504. 11 Haufler R E, Chai Y, Chibante L P F, et al.MRS Proceedings, 1990, 206, 627. 12 Wakabayashi T,Kasuya D, Shiromaru H, et al. In: Conference Record of the 8th International Symposium on Small Particles and Inorganic Clusters (ISSPIC 8). Copenhagen, 1997, pp. 414. 13 Oyama T, Ishii T, Takeuchi K.Fullerene Science and Technology, Nanotubes, 1997, 5(5), 919. 14 Afanas'ev D V, Baranov G A ,Belyaev A A , et al.Technical Physics Letters, 2001, 27(5), 408. 15 Krätschmer W, Lamb l D, Fostiropoulos K, et al.Nature, 1990, 347(27), 354. 16 Dudnik A I, Osipova I V, Nikolaev N S, et al.Fullerenes Nanotubes and Carbon Nanostructures, 2020, 28(9), 697. 17 Churilov G N, Krätschmer W, Osipova I V, et al.Carbon, 2013, 62, 389. 18 Churilov G, Popov A, Vnukova N, et al.Fullerenes Nanotubes and Carbon Nanostructures, 2016, 24(11), 675. 19 Kareev I E, Nekrasov V M, Bubnov V P.Technical Physics, 2015, 60(1), 102. 20 Kareev I E, Dutlov E A, Bubnov V P. Technical Physics, 2020, 65(1), 102. 21 魏贤凤, 龙新平, 韩勇.含能材料, 2011,19(5), 597. 22 Yoshie K, Kasuya S, et al. Applied Physics Letters, 1992, 61(23), 2782. 23 Szépvölgyi J, Marković Z, Todorović-marković B,et al. Plasma Chemistry and PlasmaProcessing, 2006, 26(6), 597. 24 Fulcheri L, Fabry F, Rohani V.Carbon, 2012, 50(12), 4524. 25 Anctil A, Babbitt C W, Raffaelle R P, et al.Environmental Science and Technology, 2011, 45(6), 2353. 26 Kim K S, Kim T H. Journal of Applied Physics, 2019, 125(7), 070901. 27 Howard J B, Mckinnon J T, Makarovsky Y, et al.Nature, 1991, 352(11), 139. 28 Lee S M, Yoon S S, Chung S H, et al.Combustion and Flame, 2004, 136(4), 493. 29 王金刚, 彭汝芳, 朱根华, 等. 材料工程, 2008(10), 306. 30 Gerhardt P, Löffler S, Homann K H. Chemical Physics Letters, 1987, 137(4), 306. 31 付超勇. 低压苯/乙炔-氧气扩散火焰燃烧法合成富勒烯的放大实验研究.硕士学位论文. 厦门大学, 2018. 32 Qian H J, Adri C T, Morokuma K, et al.Journal of Chemical Theory and Computation, 2011, 7(7), 2040. 33 Takehara H, Fujiwara M, Arikawa M, et al.Carbon, 2005, 43(2), 311. 34 Grieco W J, Lafleur A L, Swallow K C, et al.Symposium (International) on Combustion, 1998, 27(2), 1669. 35 Alford J M, Bernal C, Cates M, et al.Carbon, 2008, 46(12), 1623. 36 Scott L T.Science, 2002, 295(22), 1500. 37 Otero G, Biddau G, Sanchez-Sanchez C, et al.Nature, 2008, 454(14), 865. 38 Scott L T.Angewandte Chemie-International Edition, 2004, 43(38), 4994. 39 Bezmel'nitsyn V N, Eletskii A V, Okun M V.Uspekhi Fizicheskih Nauk, 1998, 168(11),1195. 40 Churilov G N, Еlesina V I, Dudnik A I, et al.Fullerenes Nanotubes and Carbon Nanostructures, 2018, 27(3), 225. 41 Elesina V I, Churilov G N, Vnukova N G, et al. Fullerene Science and Technology, 2019, 27(10), 803. 42 Perez R A, Albero B, Miguel E, et al.Analytical Sciences, 2013, 29(5), 533. 43 Capp C, Wood T D, Marshall A G, et al.Journal of the American Chemical Society, 1994,116(11), 4987. 44 Place B J, Kleber M, Field J A, et al.Journal of Separation Science, 2013, 36(5), 953. 45 Kwok K S, Chan Y C, Ng K M, et al. Aiche Journal, 2010, 56(7), 1801. 46 Smalley R E,Haufler R E. U.S. Patent, US5227038A, 1993. 47 Yeretzian C, Wiley J B, Holczer K, et al.The Journal of Physical Chemistry, 1993, 97(39), 10097. 48 Moscalev G N, Grushko Y S, Sedov v P. RU.patent application, 2124473, 1999. 49 杨文宁, 彭汝芳, 王凯, 等.化工新型材料, 2010, 38(1), 5. 50 Hare J P, Kroto H W.Chemical Physics Letters, 1991, 177, 394. 51 Scrivens W A, Bedworth P V, Pour J M, et al.Journal of the American Chemical Society, 1992, 144(20), 7917. 52 Yi H , Zeng G, Lai C, et al.The Chemical Engineering Journal, 2017, 330, 134. 53 Komatsu N, Ohe T, Matsushige K,Carbon, 2004, 42(1), 163. 54 Komatsu N, Kadota N, Kimura T, et al.Fullerenes Nanotubes and Carbon Nanostructures, 2007, 15(4), 217. 55 Zhou X H, Liu J B, Jin Z X, et al. Fullerene Science and Technology, 2012, 5(1), 285. 56 Zhou X H, Gu Z N, Wu Y Q, et al.Carbon, 1994, 32(5), 935. 57 Doome R J, Fonseca A, Richter H, et al.Journal of Physics and Chemistry of Solids, 1997, 58(11), 1839. 58 Kishi N, Akita M, Yoshizawa M. Angewandte Chemie, 2014, 126(14), 3678. 59 García-simón C, Garcia-borràs M, Gómez, L, et al. Nature Communications, 2014, 5, 5557. 60 李培娟. 2018年中国富勒烯行业发展现状和市场前景分析:富勒烯纳米碳材料应用前景广阔. 2019-02-19. 61 郭静原. 我国首条吨级富勒烯生产线投产. 经济日报,2018-7-12.