非金属超疏水纳米涂层技术的研究进展

材料导报

2020, Vol. 34

Issue (Z1): 66-71

无机非金属及其复合材料

非金属超疏水纳米涂层技术的研究进展

王永红^1,2, 杨倩倩², 刘辰², 刘会斌², 林晨³, 肖鹏飞³, 巩凌峰³

1 国网内蒙古东部电力有限公司,呼和浩特 010010;
2 国网内蒙古东部电力有限公司电力科学研究院,呼和浩特 010020;
3 北京易净星科技有限公司,北京 100000

A Review on Recent Researches of Nonmetal Superhydrophobic Nano-coatings

WANG Yonghong^1,2, YANG Qianqian², LIU Chen², LIU Huibin², LIN Chen³, XIAO Pengfei³, GONG Lingfeng³

1 East Inner Mongolia Electric Power Co., Ltd., Hohhot 010010, China;
2 Electric Power Research Institute of East Inner Mongolia Electric Power Co., Ltd., Hohhot 010010, China;
3 Beijing Neatrition Technology Co., Ltd., Beijing 100000, China

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摘要设备表面防水、防冰、防雾的需求在工业生产中随处可见,在其表面喷覆超疏水涂层是针对此类需求的有效解决方法。超疏水涂层的疏水性由材料表面的表面能和微纳粗糙结构两个因素决定,构筑超疏水涂层主要包括降低材料的表面能和改变微观结构两个方面。本文综述了国内外主要的非金属纳米材料,如石墨烯、二氧化硅、二氧化钛等制备超疏水涂层的方法,评价了不同纳米材料的适用范围。这类材料自身尺度是纳米级,易于构筑微纳粗糙结构和通过化学改性引入非极性共价官能团,降低材料的表面能。通过氧化还原、表面改性等方法引入疏水基团,通过自组装法、凝胶法、模板法、刻蚀法等进行结构组装,可制备接触角大于150°、滚动角小于5°的超疏水表面。分析了能够与纳米材料通过共价或非共价结合组成复合超疏水涂层的聚合物,增强涂层在力学、热学等方面的性能,扩展其应用范围。总结了近些年来在非金属超疏水纳米涂层领域的最新技术和进展,介绍了不同种类的纳米材料构筑超疏水表面的方法及其应用,为超疏水涂层的规模化生产提供可行的思路。

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	王永红
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	林晨
	肖鹏飞
	巩凌峰

关键词: 超疏水纳米材料低表面能微纳结构石墨烯二氧化硅

Abstract: The worldwide coating industries and scientific communities have paid much attention on superhydrophobic coatings for the requirements of anti-water, anti-ice and anti-fog. Superhydrophobicity is mainly due to the low surface energy and the micro-nano structure of the coating materials. These two features can be achieved on many nanomaterials by chemical modification and physical assembly. Nonmetal nanomaterials, such as graphene, silicon dioxide and titanium dioxide, are potential candidates for fabricating superhydrophobic coatings with high contact angle (>150°) and low sliding angle (<5°). These materials can be easily chemically modified and physically assembled. This review attempts to highlight the technical development and breakthrough in superhydrophobic coatings made of nonmetal nanomaterials in different fields. Recent developments in superhydrophobic coatings through nanotechnology are provided. Both preparation strategies and their distinctive properties are revealed. To prepare superhydrophobic coatings, polymers are usually used with nanomaterials, for their various structures and applications. Several important methods and examples in designing stable and self-cleanable superhydrophobic surface by nonmetal nanomaterials with frequently used polymers are discussed. This review provides various approaches to prepare superhydrophobic nonmetal nanomaterials, which could be promising solutions for the large scale production of superhydrophobic coatings.

Key words: superhydrophobicity nanomaterial low surface energy micro-nano structure graphene SiO₂

发布日期: 2020-07-01

ZTFLH:

O6-1

作者简介: 林晨,2017年1月毕业于清华大学化工系,获得工程博士学位。于2017年9月加入北京易净星科技有限公司,担任研发总监一职,主要从事纳米超疏水材料、超亲水材料、超硬材料领域的研究。

引用本文:

王永红, 杨倩倩, 刘辰, 刘会斌, 林晨, 肖鹏飞, 巩凌峰. 非金属超疏水纳米涂层技术的研究进展[J]. 材料导报, 2020, 34(Z1): 66-71.
WANG Yonghong, YANG Qianqian, LIU Chen, LIU Huibin, LIN Chen, XIAO Pengfei, GONG Lingfeng. A Review on Recent Researches of Nonmetal Superhydrophobic Nano-coatings. Materials Reports, 2020, 34(Z1): 66-71.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/66

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