Abstract: Graphene has become an ideal reinforcement because of its unique two-dimensional structure, high mechanical properties, excellent electrical and thermal conductivity. When graphene is introduced into copper matrix, high performance copper composites are expected to be prepared by fully exerting the synergistic effect of graphene and copper. At present, the comprehensive properties of graphene reinforced copper matrix composites have been significantly improved compared with those of pure copper, however, preparation technology and stability problems still restrain its enhancement of overall performance and practical application. This review offers a retrospection of the research efforts with respect to the preparation technology, microstructure and properties of graphene reinforced copper matrix composites, and especially discusses the effective dispersion of graphene, the modification of graphene-copper interface, and the design of graphene configuration. Meanwhile, the current challenges and future directions of graphene reinforced copper matrix composites are proposed.
1 赵亚茹, 李勇, 李焕. 表面技术,2016,45(5),33. 2 辛丽莎, 孙瑞雪. 材料导报:综述篇,2013,27(5),51. 3 Li Y P, Xiao Z, et al. Journal of Alloys & Compounds,2017,723,1162. 4 Arnaud C, Lecouturier F, Mesguich D, et al. Materials Science & Engineering A,2016,649,209. 5 Zeng W, Xie J W, Zhou D S, et al. Journal of Alloys & Compounds,2018,745,55. 6 李岩, 宋美慧, 张煜, 等. 化学工程师,2017,10,13. 7 Liu L Q, Weng W, Lin W H. C.N. patent, WO2016090755 A1,2016. 8 Toshihiro K, Akira S, Isamu A, et al. U.S. patent, US5205878,1993. 9 Novoselov K S, Geim A K, Morozov S V, et al. Science,2004,306(5696),666. 10 Lee C G, Wei X D, Kysar J W, et al. Science,2008,321(5887),385. 11 Choi W, Lahiri I, Seelaboyina R, et al. Critical Reviews in Solid State & Materials Sciences,2010,35(1),71. 12 Balandin A A, Ghosh S, Bao W, et al. Nano Letters,2008,8(1),907. 13 匡达, 胡文彬. 无机材料学报,2013,28(3),235. 14 Walker L S, Marotto V R, Rafiee M A, et al. ACS Nano,2011,5(4),3182. 15 Xu Z, Gao C. Macromolecules,2010,43(16),6716. 16 Stankovich S, Dikin D A, Dommett G H B, et al. Nature,2006,442,282. 17 Li Z, Fan G L, Tan Z Q, et al. Nano-Micro Letters,2016,8(1),54. 18 王勇, 周吉学, 程开明, 等. 材料导报,2017,31(S1),451. 19 Yue H Y, Yao L H, Gao X, et al. Journal of Alloys & Compounds,2017,691,755. 20 Kim W J, Lee T J, Han S H. Carbon,2014,69(4),55. 21 Hwang J, Yoon T, Jin S H, et al. Advanced Materials,2013,25(46),6724. 22 Gao X, Yue H Y, Guo E, et al. Powder Technology,2016,301,601. 23 Xiong D B, Cao M, Guo Q, et al. ACS Nano,2015,9(7),6934. 24 Chen Y K, Zhang X, Liu E Z, et al. Journal of Alloys & Compounds,2016,688,69. 25 Xiao Q, Yi X O, Jiang B, et al. Advanced Materials Science,2017,2(2),1 26 凌自成. 石墨烯/铜基复合材料制备及其力电性能研究. 硕士学位论文, 昆明理工大学,2016. 27 Kim Y B, Lee J S, Yeom M S, et al. Nature Communications,2013,4,3114. 28 Xu Z P, Buehler M J. Journal of Physics: Condensed Matter,2010,22(48),485301. 29 Tang Y X, Yang X M, Wang R R, et al. Materials Science & Enginee-ring A,2014,599,247. 30 Meyer J C, Geim A K, Novoselov K S, et al. Nature,2007,446(7131),60. 31 Li D, Müller M B, Gilje S, et al. Nature Nanotechnology,2008,3(2),101. 32 Reina A, Jia X T, Ho J, et al. Nano Letters,2009,9(1),30. 33 Berger C, Song Z M, Li X B, et al. Science,2006,312(5777),1191. 34 Jiang R R, Zhou X F, Fang Q L, et al. Materials Science & Engineering A,2016,654,124. 35 Zhang D D, Zhan Z J. Journal of Alloys & Compounds,2016,654,226. 36 Cao M, Xiong D B, Tan Z Q, et al. Carbon,2017,117,65. 37 Yang M, Weng L, Zhu H X, et al. Carbon,2017,118,250. 38 Yang M, Weng L, Zhu H X, et al. Scripta Materialia,2017,138,17. 39 Chu K, Wang X H, Wang F, et al. Carbon,2018,127,102. 40 Chu K, Wang F, Wang X H, et al. Materials & Design,2018,144,290. 41 Yu A P, Ramesh P, Itkis M E, et al. Journal of Physical Chemistry C,2007,111(21),7565. 42 Chu K, Jia C C. Physica Status Solidi,2014,211(1),184. 43 张丹丹. 石墨烯/铜复合材料的制备、组织及力学性能研究. 博士学位论文, 燕山大学,2016. 44 张丹丹, 战再吉. 材料工程,2016,44(5),112. 45 郭俊贤, 王波, 杨振宇. 复合材料学报,2014,31(1),152. 46 Zhao X, Zhang Q H, et al. Macromolecules,2010,43(5),2357. 47 Liu L Q, Barber A H, Nuriel S, et al. Advanced Functional Materials,2005,15(6),975. 48 Li W P, Li D L, Fu Q, et al. RSC Advances,2015,5(98),80428. 49 Chen Y K, Zhang X, Liu E Z, et al. Scientific Reports,2016,6,19363. 50 Chu K, Wang F, Li Y B, et al. Composites Part A,2018,109,267. 51 Goli P, Ning H, Li X S, et al. Nano Letters,2014,14(3),1497. 52 Jagannadham K. Metallurgical & Materials Transactions Part A,2013,44(1),552. 53 Boden A, Boerner B J, Kusch P, et al. Nano Letters,2014,14(6),3644. 54 Firkowska I, Boden A, Boerner B, et al. Nano Letters,2015,15(7),4745.