改性剂对TiN/PS纳米复合材料流变行为的影响

doi:10.11896/cldb.18060011

材料导报

2019, Vol. 33

Issue (14): 2444-2449 https://doi.org/10.11896/cldb.18060011

高分子与聚合基复合材料

改性剂对TiN/PS纳米复合材料流变行为的影响

程国君¹, 产爽爽¹, 陈晨¹, 钱家盛², 丁国新¹, 王周锋¹

1 安徽理工大学材料科学与工程学院,淮南 232001;
2 安徽大学化学化工学院,合肥 230601

Effect of Modifiers on the Rheological Behavior of TiN/PS Nanocomposites

CHENG Guojun¹, CHAN Shuangshuang¹, CHEN Chen¹, QIAN Jiasheng², DING Guoxin¹, WANG Zhoufeng¹

1 School of Materials Science and Engineering, Anhui University of Science & Technology, Huainan 232001;
2 School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601

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摘要分别以γ-甲基丙烯酰氧基丙基三甲氧基硅烷(MAPTMS)和大分子St/AN/MAPTMS无规共聚物为改性剂对纳米TiN进行表面预处理,再将其与聚苯乙烯(PS)复合,通过熔融挤出法制备TiN/PS纳米复合材料。研究了改性剂种类对纳米TiN增强复合材料熔融流变性能、热性能和纳米粒子分散性能的影响。实验结果发现大分子改性剂处理TiN增强PS复合材料的玻璃化转变温度、热分解温度和粒子均匀分散稳定性均高于MAPTMS,大分子处理TiN增强PS复合材料的界面黏结作用更强;受纳米TiN与PS基体界面黏结效果的影响,大分子改性剂修饰TiN增强PS体系的储能模量和复数黏度增大更为明显。

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	程国君
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	丁国新
	王周锋

关键词: 纳米TiN 大分子改性剂表面改性流变性能界面黏结

Abstract: TiN reinforced PS nanocomposites were prepared by melt extrusion method, in which the nano TiN was pretreated by γ-methacryloxypropyl trimethoxy silane (MAPTMS) and macromolecular random copolymer St/AN/MAPTMS, and then blended with polystyrene (PS). The effects of modifiers type on the melt rheological properties, thermal performance and dispersion of nanoparticles of nano TiN reinforced compo-sites were studied. The experimental results discovered that the glass transition temperature, thermal decomposition temperature and uniform dispersion stability of particles of nano TiN reinforced PS composites treated with macromolecular modifier were higher than those of MAPTMS. It indicated that the macromolecular modifier had strongest interfacial bonding effect for TiN reinforced PS nanocomposites. Affected by the interfacial bonding effect between nano TiN and PS, the increase of storage modulus and complex viscosity of the TiN reinforced PS system modified with macromolecular modifier were more obvious.

Key words: nano TiN macromolecular modifier surface modification rheological property interfacial bonding

发布日期: 2019-06-19

ZTFLH:

TQ327.8

基金资助: 高校优秀青年人才支持计划(gxyq2017006);安徽省博士后基金(2016B122)

通讯作者: chengguojun0436@126.com

作者简介: 程国君,安徽理工大学副教授,硕士生导师,2002年获得长春工业大学高分子材料与工程专业学士学位并同年就职于安徽理工大学至今,其中2010年10月至2013年12月,在安徽大学获得高分子化学与物理专业理学博士学位,研究主要围绕高分子材料改性及复合材料界面结构调控,以第一作者在国内外学术期刊上发表论文20余篇,申请国家授权发明专利1项,已培养硕士3名,本科生60余名。

引用本文:

程国君, 产爽爽, 陈晨, 钱家盛, 丁国新, 王周锋. 改性剂对TiN/PS纳米复合材料流变行为的影响[J]. 材料导报, 2019, 33(14): 2444-2449.
CHENG Guojun, CHAN Shuangshuang, CHEN Chen, QIAN Jiasheng, DING Guoxin, WANG Zhoufeng. Effect of Modifiers on the Rheological Behavior of TiN/PS Nanocomposites. Materials Reports, 2019, 33(14): 2444-2449.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.18060011 或 http://www.mater-rep.com/CN/Y2019/V33/I14/2444

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