Abstract: Oxidation is an important surface modification technique for NiTi shape memory alloys, and the commonly used oxidation methods include thermal oxidation, micro-arc oxidation, anodic oxidation and chemical oxidation. Although the four met-hods all utilize the element Ti in the alloy to generate an in-situ oxide coating that mainly consists of crystalline or amorphous TiO2 on the alloy surface, they have diverse principles, coating morphology and coating structures. This paper reviews the advantages and disadvantages of these four methods and sketches out the development trend of the surface modification technique of NiTi shape memory alloy.
邵明增, 崔春娟, 杨洪波. 医用NiTi形状记忆合金表面氧化改性研究进展[J]. 《材料导报》期刊社, 2018, 32(7): 1181-1186.
SHAO Mingzeng, CUI Chunjuan, YANG Hongbo. Surface Oxidation as the Modification Technique of NiTi Shape Memory Alloys for Medical Application: a Technological Review. Materials Reports, 2018, 32(7): 1181-1186.
1 Zhang Hejia,Zhang Yang,Sun Xiaoju,et al.Evaluation of cytotoxicity of three types of orthodontic nickel-titanium shape memory alloy wire[J].Chinese Journal of Practical Stomatology,2010,3(8):477(in Chinese).
张贺佳,张扬,孙晓菊,等.3种正畸用镍钛形状记忆合金弓丝细胞毒性评价[J].中国实用口腔科杂志,2010,3(8):477.
2 Wang Chengjian,Meng Zengdong,Zhang Yuqin,et al.The biocompatibility of NiTi shape memory alloy:A review[J].Orthopaedic Biomechanics Materials and Clinical Study,2016,13(1):65(in Chinese).
王成健,孟增东,张玉勤,等.镍钛形状记忆合金的生物相容性研究进展[J].生物骨科材料与临床研究, 2016,13(1):65.
3 Vojtěch D,Novák P,Novák M,et al.Cyclic and isothermal oxidations of nitinol wire at moderate temperatures[J].Intermetallics, 2008,16(3):424.
4 Dagdelen F,Ercan E.The surface oxidation behavior of Ni-45.16%Ti shape memory alloys at different temperatures[J].Journal of Thermal Analysis and Calorimetry, 2014,115(1):561.
5 Xu C H,Ma X Q,Shi S Q,et al.Oxidation behavior of TiNi shape memory alloy at 450—750 ℃[J].Materials Science and Engineering A, 2004,371(1-2):45.
6 Gu Y W,Tay B Y,Lim C S,et al.Biomimetic deposition of apatite coating on surface-modified NiTi alloy[J].Biomaterials, 2005,26(34):6916.
7 Gu Y W,Tay B Y,Lim C S,et al.Characterization of bioactive surface oxidation layer on NiTi alloy[J].Applied Surface Science, 2005,252(5):2038.
8 Tao Binwu,Liu Jianhua,Li Songmei.Oxidation behaviors of Ti44Ni47-Nb9 shape memory alloy at high temperature[J].Acta Metallurgica Sinica,2005,41(6):633(in Chinese).
陶斌武,刘建华,李松梅.形状记忆合金Ti44Ni47Nb9的抗高温氧化性能[J].金属学报,2005,41(6):633.
9 Xu J,Zhao X,Gong S.Effect of Nb on oxidation behavior of NiTiNb alloys[J].Transactions of Nonferrous Metals Society of China,2006,16(Z2):31.
10Xu J W,Liu A L,Wang S H,et al.Effect of Y addition on isothermal oxidation behavior of Ti50Ni50 shape memory alloy at 700 ℃[J].Rare Metal Materials and Engineering,2016,45(9):2246.
11Wang S,Li Y,Zhao T.Effect of thermal oxidation on the surface characteristics and corrosion behavior of a Ta-implanted Ti-50.6Ni shape memory alloy[J].International Journal of Minerals,Metallurgy and Materials,2012,19(12):1134.
12Li Minggao,Sun Daqian,Qiu Xiaoming,et al.Effects of temperature on microstructure and mechanical behaviour of biomedical TiNi shape memory alloy wire[J].Rare Metal Materials and Engineering,2007,36(6):998(in Chinese).
李明高,孙大千,邱小明,等.温度对医用TiNi形状记忆合金丝微观组织和力学行为的影响[J].稀有金属材料与工程,2007,36(6):998.
13 Gao Jing,Yang Guanjun,Yang Hongjin,et al.Effect of heat treatment on microstructure and shape memory effect of biomedical TiNi alloy fine wire[J].Rare Metal Materials and Engineering,2005,34(2):299(in Chinese).
高静,杨冠军,杨宏进,等.热处理对医用TiNi细丝显微组织及形状记忆效应的影响[J].稀有金属材料与工程,2005,34(2):299.
14 Michiardi A,Aparicio C,Planell J A,et al.New oxidation treatment of NiTi shape memory alloys to obtain Ni-free surfaces and to improve biocompatibility[J].Journal of Biomedical Materials Research Part B:Applied Biomaterials,2006,77(2):249.
15 Heßing C,Gabert S,Pohl M,et al.High-temperature corrosion of NiTi-shape-memory alloys[J].Materials Science and Engineering Technology,2004,35(5):332.
16 Sinebryukhov S,Gnedenkov A,Khrisanfova O,et al.Influence of plasma electrolytic oxidation on mechanical characteristics of NiTi alloy[J].Surface Engineering,2013,25(8):565.
17 Wang H,Liu F,Xiong X,et al.Structure,corrosion resistance and in vitro bioactivity of Ca and P containing TiO2 coating fabricated on NiTi alloy by plasma electrolytic oxidation[J].Applied Surface Science,2015,356:1234.
18 Wang H,Liu F,Zhang Y,et al.Structure,corrosion resistance and apatite-forming ability of NiTi alloy treated by micro-arc oxidation in concentrated H2SO4[J].Surface & Coatings Technology,2012,206(19-20):4054.
19 Xu J L,Liu F,Wang F P,et al.Microstructure and corrosion resis-tance behavior of ceramic coatings on biomedical NiTi alloy prepared by micro-arc oxidation[J].Applied Surface Science,2008,254(20):6642.
20Xu J L,Fu L,Wang F P,et al.The corrosion resistance behavior of Al2O3 coating prepared on NiTi alloy by micro-arc oxidation[J].Journal of Alloys and Compounds,2009,472(1-2):276.
21Xu J L,Liu F,Luo J,et al.Effects of anodic voltages on microstructure and properties of plasma electrolytic oxidation coatings on biomedical NiTi alloy[J].Journal of Materials Science & Technology, 2013,29(1):22.
22Jiang Guirong,Lu Lihong,Shen Dejiu,et al.Fabrication and manufacturability of ceramic coatings obtained by micro arc oxidation on NiTi shape memory alloy substrate[J].Surface Technology,2011,40(6):1(in Chinese).
姜桂荣,卢立红,沈德久,等.NiTi形状记忆合金微弧氧化陶瓷层的制备及其工艺性研究[J].表面技术, 2011,40(6):1.
23 Wang H R,Liu F,Zhang Y P,et al.Preparation and properties of titanium oxide film on NiTi alloy by micro-arc oxidation[J].Applied Surface Science,2011,257(13):5576.
24 Feng D W,Jiang X Y.Structure changes of coating on NiTi alloy prepared by micro-arc oxidation in Na2SiO3 electrolyte[J].Materials Science Forum,2015,815:440.
25 Ge Zhendong,Zhao Hong, Guan Shaoxuan,et al.The storage life study of modified polyphenylene sulfide by hot air ageing test[J].Journal of Functional Materials,2009,40(6):1036(in Chinese).
葛振东,赵红,关少轩,等.表面预氧化镍钛丝微弧氧化涂层的研究[J].功能材料, 2009,40(6):1036.
26 Zhao H,Tian C C,Lin G Q,et al.Formation of porous (Ca,P)-doped TiO2/Dense Ti double coatings on NiTi alloy[J].Materials Science Forum,2011,675-677(42):333.
27 Xu Jilin,Li Fu,Luo Junming,et al.Formation mechanism of the micro-arc oxidation ceramic coating on NiTi alloy[J].Rare Metal Materials and Engineering,2012,41(10):1770(in Chinese).
徐吉林,福刘,罗军明,等.NiTi 合金表面微弧氧化陶瓷膜层的形成机制探讨[J].稀有金属材料与工程.2012,41(10):1770.
28 Wang Hairui.Preparation and bioactivity of titania coatings on medical NiTi alloy[D].Harbin:Harbin Institute of Technology,2013(in Chinese).
王海瑞.医用NiTi合金表面TiO2膜层的制备及生物活性研究[D].哈尔滨:哈尔滨工业大学,2013.
29 Hsieh S F,Ou S F,Chou C K.The influence of the substrate on the adhesive strength of the micro-arc oxidation coating developed on TiNi shape memory alloy[J].Applied Surface Science,2017,392(15):581.
30Zhu L H,Xu X J,Niu X Y,et al.Surface properties of TiNi alloy treated by micro-arc oxidation under different voltages[J].Advanced Materials Research,2014,1053:21.
31Siu H T,Man H C.Fabrication of bioactive titania coating on nitinol by plasma electrolytic oxidation[J].Applied Surface Science,2013,274:181.
32Liu F,Shimizu T.Effects of NaAlO2 concentrations on structure and characterization of micro-arc oxidation coatings formed on biomedical NiTi alloy[J].Journal of the Ceramic Society of Japan,2010,118(2):113.
33 Zhang P,Zhang Z,Li W,et al.Effect of Ti-OH groups on microstructure and bioactivity of TiO2 coating prepared by micro-arc oxidation[J].Applied Surface Science,2013,268(1):381.
34 Zhu Lihua,Xu Xiaojing,Liu Min,et al.Effects of micro-arc oxidation on surface properties of conventional and ultrafine-grained TiNi alloy[J].The Chinese Journal of Nonferrous Metals,2014,24(4):1014(in Chinese).
朱利华,许晓静,刘敏,等.微弧氧化对常规和超细TiNi合金表面性能的影响[J].中国有色金属学报,2014,24(4):1014.
35 Huan Z,Fratila-Apachitei L E,Apachitei I,et al.Effect of aging treatment on the in vitro nickel release from porous oxide layers on NiTi[J].Applied Surface Science,2013,274(1):266.
36 Cheng F T,Shi P,Pang G K H,et al.Microstructural characterization of oxide film formed on NiTi by anodization in acetic acid[J].Journal of Alloys and Compounds,2007,438(1-2):238.
37 Cheng Zhanbao,Su Xiangdong,Zhu Weidong,et al.Preparation of TiO2 film by electrochemical oxidation on the surface of NiTi SMA[J].Surface Technology,2008,37(4):4(in Chinese).
程占保,苏向东,朱维东,等.NiTi合金表面电化学氧化制备TiO2膜[J].表面技术,2008,37(4):4.
38 Yang C L,Chen F L,Chen S W.Anodization of the dental arch wires[J].Materials Chemistry and Physics,2006,100(2-3):268.
39 Wong M H,Cheng F T,Man H C.Comparison of corrosion resistance and apatite-forming ability of NiTi treated by different low-temperature methods[J].Journal of Alloys and Compounds,2008,466(1-2):L5.
40Cheng F T,Shi P,Man H C.Nature of oxide layer formed on NiTi by anodic oxidation in methanol[J].Materials Letters,2005,59(12):1516.
41Chu C L,Wang R M,Hu T.XPS and biocompatibility studies of titania film on anodized NiTi shape memory alloy[J].Journal of Materials Science:Materials in Medicine, 2009,20(1):223.
42Liu Fu,Xin Tiezhu,Wang Fuping,et al.Study on TiO2 film formation and structure on NiTi shape memory alloy[J].Journal of Yanshan University,2008,32(3):214(in Chinese).
刘福,辛铁柱,王福平,等.NiTi形状记忆合金表面TiO2薄膜的制备和结构研究[J].燕山大学学报,2008,32(3):214.
43 Chu C L,Wang R M,Yin L H,et al.Effects of anodic oxidation in H2SO4 electrolyte on the biocompatibility of NiTi shape memory alloy[J].Materials Letters,2008,62(20):3512.
44 Kawakita J,Stratmann M,Hassel A W.High voltage pulse anodization of a NiTi shape memory alloy[J].Journal of the Electrochemical Society,2007,154(6):C294.
45 Qin R,Ding D Y,Ning C Q,et al.Ni-doped TiO2 nanotube arrays on shape memory alloy[J].Applied Surface Science,2011,257(14):6308.
46 Hang R,Huang X,Tian L,et al.Preparation,characterization,corrosion behavior and bioactivity of Ni2O3-doped TiO2 nanotubes on NiTi alloy[J].Electrochimica Acta,2012,70(3):382.
47 Li Zhaohui,Ding Dongyan,Ning Congqin,et al.Fabrication and hydrogen sensing properties of Ni-Ti-O nanotube arrays[J].Semiconductor Technology,2014,39(10):774(in Chinese).
黎朝晖,丁冬雁,宁聪琴,等.Ni-Ti-O纳米管阵列的制备与氢敏性能[J].半导体技术,2014,39(10):774.
48 Qin Rui,Ding Dongyan,Ning Congqin,et al.Fabrication and characterization of nanotube arrays on shape memory alloy[J]. Micronanoeletronic Technology,2011,48(3):159(in Chinese).
秦锐,丁冬雁,宁聪琴,等.形状记忆合金表面纳米管阵列的制备与表征[J].微纳电子技术,2011,48(3):159.
49 Das K,Bose S,Bandyopadhyay A.TiO2 nanotubes on Ti:Influence of nanoscale morphology on bone cell-materials interaction[J].Journal of Biomedical Materials Research Part A,2009,90(1):225.
50Kim J,Zhu K,Yan Y,et al.Corrections to microstructure and pseu-docapacitive properties of electrodes constructed of oriented NiO-TiO2 nanotube arrays[J].Nano Letters,2010,10(10):4099.
51Hang R,Liu Y,Liu S,et al.Size-dependent corrosion behavior and cytocompatibility of Ni-Ti-O nanotubes prepared by anodization of biomedical NiTi alloy[J].Corrosion Science,2016,103:103.
52Lv J L,Liang T X,Wang C,et al.Surface corrosion enhancement of passive films on NiTi shape memory alloy in different solutions[J].Materials Science and Engineering:C,2016,63(1):192.
53 Sharma S K,Mohan S.Effect of chemical treatment on surface cha-racteristics of sputter deposited Ti-rich NiTi shape memory alloy thin-films[J].Journal of Alloys and Compounds,2014,592:170.
54 Chembath M,Balaraju J N,Sujata M.Surface characteristics,corrosion and bioactivity of chemically treated biomedical grade NiTi alloy[J].Materials Science and Engineering:C,2015,56:417.
55 Sun T,Wang M,Lee W C.Surface characteristics,properties and in vitro biological assessment of a NiTi shape memory alloy after high temperature heat treatment or surface H2O2-oxidation:A comparative study[J].Materials Chemistry and Physics,2011,130(1-2):45.
56 Chu C L,Hu T,Wu S L,et al.Surface structure and properties of biomedical NiTi shape memory alloy after Fenton’s oxidation[J].Acta Biomaterialia,2007,3(5):795.
57 Sun Xuetong,Yang Menglei,Jiang Hongjie,et al.Surface modification of porous NiTi alloy by chemical oxidation[J].Materials Review B:Research Papers,2011,25(7):147(in Chinese).
孙学通,杨萌蕾,江鸿杰,等.多孔NiTi合金的化学氧化处理表面改性研究[J].材料导报:研究篇,2011,25(7):147.
58 Sun Xuetong,Jiang Hongjie,Yang Menglei,et al.A comparative study on surface modification of porous NiTi alloys by chemical oxidation and thermal oxidation[J].Journal of Functional Materials,2011,42(8):1539(in Chinese).
孙学通,江鸿杰,杨萌蕾,等.多孔NiTi形状记忆合金化学氧化和热氧化表面改性的对比研究[J].功能材料,2011,42(8):1539.
59 Wang R M,Chu C L,Hu T,et al.Surface XPS characterization of NiTi shape memory alloy after advanced oxidation processes in UV/H2O2 photocatalytic system[J].Applied Surface Science,2007,253(20):8507.
60Shan D,He X Y,Fang C Q,et al.Effects of surface oxidation behavior of NiTi shape memory alloy on adhesion of epoxy resin/polytetrafluoroethylene composite coating[J].Journal of Alloys and Compounds,2017,699:345.
61Shao H,Liu X,Zhu Z.Preparation and blood compatibility of multilayers on the surface of medical NiTi alloy[J].Materials Science Forum,2016,852:1206.
62Huan Z,Fratila-Apachitei L E,Apachitei I,et al.Synthesis and cha-racterization of hybrid micro/nano-structured NiTi surfaces by a combination of etching and anodizing[J].Nanotechnology,2014,25(5):55602.
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2018, Vol. 32 
