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材料导报  2024, Vol. 38 Issue (12): 22120181-6    https://doi.org/10.11896/cldb.22120181
  高分子与聚合物基复合材料 |
纳米纤维素基复合材料在锂硫电池中的应用研究进展
黄少炎, 修慧娟, 王志雄, 樊莎, 王思敏, 邓自立, 李娜, 李金宝*
陕西科技大学轻工科学与工程学院,西安 710021
Research Progress in Application of Nano-Cellulose Based Composites in Lithium-Sulfur Batteries
HUANG Shaoyan, XIU Huijuan, WANG Zhixiong, FAN Sha, WANG Simin, DENG Zili, LI Na, LI Jinbao*
School of Light Industry Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China
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摘要 锂硫电池因具有高的理论比容量和能量密度,成为极具应用前景的下一代储能器件。纳米纤维素基材料因其独特的多孔网状结构和理化特性,在锂硫电池的开发研究中受到广泛关注。本文在简要介绍锂硫电池基本工作原理的基础上,分析了阻碍其商业化发展的问题和面临的挑战。针对纳米纤维素的独特结构和优异性能,重点综述了纳米纤维素基复合材料在锂硫电池中的最新研究进展,包括作为隔膜、阴极材料和其他组件等,有效缓解“穿梭效应”“体积膨胀”和“锂枝晶”等关键难题,明显提升了电池的电化学性能与使用寿命。此外,还介绍了纳米纤维素基复合材料在未来发展中亟待解决的问题,并对纤维素基锂硫电池器件的发展方向进行了展望。
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黄少炎
修慧娟
王志雄
樊莎
王思敏
邓自立
李娜
李金宝
关键词:  纳米纤维素  锂硫电池  复合材料  电池隔膜  阴极材料    
Abstract: Lithium-sulfur battery has high theoretical specific capacity and energy density, which makes it a promising candidate as the next-generation energy storage device. In the research and development of lithium-sulfur batteries, nanocellulose-based materials have attracted extensive attention due to their unique network structure and the physicochemical properties. The present paper starts by introducing the basics of lithium-sulfur battery, and further analyzes the challenges hindering its commercialization. The paper also reviews the latest research of nanocellulose-based materials in lithium-sulfur batteries, from the perspectives of the unique structure and excellent performance of nanocellulose. It can be concluded that nanocellulose-based materials can serve as separators, cathode materials, and other components, and can alleviate critical problems is Li-S battries including ‘shuttle effect', ‘volume expansion' and ‘lithium dendrite', and also significantly improve the electrochemical performance and service life. Finally, the challenges to nanocellulose-based composites and the outlook for cellulose-based lithium-sulfur batteries are discussed.
Key words:  nano cellulose    lithium sulfur battery    compound material    battery diaphragm    cathode material
出版日期:  2024-06-25      发布日期:  2024-07-17
ZTFLH:  TM912  
  TQ352.7  
基金资助: 浙江省重点研发计划项目(2022C02074)
通讯作者:  *李金宝,陕西科技大学轻工科学与工程学院教授、博士研究生导师。目前主要从事纤维素基功能材料、高性能纤维纸基功能材料、木质纤维素生物质资源高值化利用等方面的研究工作。在国内外学术期刊上发表论文100余篇,被SCI/EI/CPCI收录近40篇。获授权国家发明专利20项,实用新型专利4项。获省部级科学技术一、二等奖5项、厅局级科学技术一、二等奖4项。lijinbao@sust.edu.cn   
作者简介:  黄少炎,2022年7月于陕西科技大学获得工学学士学位。现为陕西科技大学轻工科学与工程学院硕士研究生,在李金宝教授的指导下进行研究。目前主要研究领域为锂硫电池正极与隔膜复合材料的制备及锂离子电池硅负极复合材料的制备。
引用本文:    
黄少炎, 修慧娟, 王志雄, 樊莎, 王思敏, 邓自立, 李娜, 李金宝. 纳米纤维素基复合材料在锂硫电池中的应用研究进展[J]. 材料导报, 2024, 38(12): 22120181-6.
HUANG Shaoyan, XIU Huijuan, WANG Zhixiong, FAN Sha, WANG Simin, DENG Zili, LI Na, LI Jinbao. Research Progress in Application of Nano-Cellulose Based Composites in Lithium-Sulfur Batteries. Materials Reports, 2024, 38(12): 22120181-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22120181  或          http://www.mater-rep.com/CN/Y2024/V38/I12/22120181
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