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材料导报  2020, Vol. 34 Issue (Z1): 507-510    
  高分子与聚合物基复合材料 |
聚噻吩及其衍生物PEDOT在吸波领域的应用现状
刘凡, 赵晓明
天津工业大学纺织科学与工程学院,天津 300387
Application Status of Polythiophene and Its Derivative PEDOT in WaveAbsorption Field
LIU Fan, ZHAO Xiaoming
School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
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摘要 电子科技的飞速发展使得电磁波无处不在,电磁波给人类带来了巨大便利,但电磁污染问题也日益突出,近年来科研工作者致力于研究吸波材料,导电聚合物基吸波材料以合成简单、质量轻、成本低等特点引起了人们的广泛关注。目前在吸波领域应用较为广泛的导电聚合物包括聚苯胺、聚吡咯等,但是以此为基础制备的吸波材料并没有达到非常理想的吸波效果,有效吸收带宽(反射损耗不高于-10 dB)也比较窄,因此人们开始探索对导电聚合物进行掺杂,或与其他材料进行复合,来改善其吸波性能,以获得较为理想的吸波效果。
聚噻吩及其衍生物聚(3,4-乙撑二氧噻吩)(PEDOT)相比其他导电聚合物具有更好的导电性和优异的环境稳定性,易于掺杂,且具有良好的相容性以及与其他材料的附着力,一般应用于传感器以及电致发光等领域。虽然对吸波领域的研究近几年刚刚起步,但并不能否认以聚噻吩及其衍生物PEDOT为基础的复合吸波材料具有较好的吸波能力。单独的聚噻吩及其衍生物PEDOT吸波材料的吸波性能并不突出,因此近年来对聚噻吩及其衍生物PEDOT吸波材料的研究主要是其与其他材料复合制备吸波材料,如聚噻吩与无机粒子,PEDOT与磁性粒子、有机物以及石墨烯等复合制备的吸波材料,均获得了较好的吸波效果。
本文简单阐述了吸波材料的吸波机理,重点介绍了聚噻吩及其衍生物PEDOT的性能特点,以及近年来其在吸波方面的应用进展,并分析了其现存的优点和缺点,预测了其未来的发展趋势。
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刘凡
赵晓明
关键词:  吸波机理  聚噻吩  聚(3,4-乙撑二氧噻吩)  吸波材料    
Abstract: Electromagnetic waves are everywhere because of the rapid development of electronic technology. Electromagnetic wave brings great conve-nience to human beings, but also causes increasingly serious electromagnetic pollution problems. In recent years, researchers have been working on electromagnetic waves absorbing materials. Conductive polymer-based electromagnetic wave-absorbing materials have attracted wide attention due to their simple synthesis, light weight and low cost. Currently, conductive polymers such as polyaniline and polypyrrole are widely used in the field of electromagnetic wave absorbing. However, the electromagnetic wave absorbing materials based on these did not achieve the ideal absorbing effect, and the effective absorption bandwidth (reflection loss ≤10 dB) is also relatively narrow. Therefore, people began to explore the doping of conductive polymer or composite with other materials to improve its absorption performance so as to obtain a better absorption effect. Compared with other conductive polymers, polythiophene and PEDOT have better conductivity, excellent environmental stability, easy doping, good compatibility and adhesion with other materials. It's generally used in sensor and electroluminescence fields. Although the research on polythiophene and PEDOT in the field of wave absorption has just started in recent years, it cannot be denied that composite absorbing materials based on polythiophene or PEDOT have good absorbing ability. The microwave absorbing properties of the single polythiophene or PEDOT are not outstanding, so the recent study mainly focused on the preparation of microwave absorbing materials by compounding with other materials, such as polythiophene and inorganic particles, PEDOT and magnetic particles, organic compounds or graphene, which have obtained better microwave absorbing effects. In this paper, the mechanism of absorbing materials is described in brief. The characteristics of polythiophene and PEDOT are emphatically introduced. The research status of absorbing materials based on polythiophene or PEDOT in recent years is summarized. The advantages and disadvantages are analyzed, the future development trend is predicted.
Key words:  absorbing mechanism    polythiophene    poly (3,4-ethylene dioxythiophene)    absorbing material
                    发布日期:  2020-07-01
ZTFLH:  TB34  
基金资助: 2018年天津市自然科学基金重点项目(18JCZDJC99900);2018年天津市自然科学基金面上项目(18JCYBJC86600);2017年度天津市教委科研计划项目(2017KJ070);2018年度天津市科委科技特派员项目(18JCTPJC62500);2017年度天津工业大学天津市高等学校基本科研业务资助项目(TJPU2K20170105);天津市研究生科研创新项目(2019YJSS018)
作者简介:  刘凡,天津工业大学纺织科学与工程学院研究生,在赵晓明教授指导下进行研究,主要研究领域为电磁波吸收材料;赵晓明,天津工业大学纺织学院教授、博士研究生导师。英国赫尔瓦特大学博士,天津市千人计划专家,中国产业用纺织品行业协会特种纺织品分会秘书长,主要从事柔性防护材料性能方面的研究,近5 年在国内外重要期刊发表文章 100多篇,申报发明专利 20 余项。
引用本文:    
刘凡, 赵晓明. 聚噻吩及其衍生物PEDOT在吸波领域的应用现状[J]. 材料导报, 2020, 34(Z1): 507-510.
LIU Fan, ZHAO Xiaoming. Application Status of Polythiophene and Its Derivative PEDOT in WaveAbsorption Field. Materials Reports, 2020, 34(Z1): 507-510.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2020/V34/IZ1/507
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