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材料导报  2018, Vol. 32 Issue (16): 2763-2767    https://doi.org/10.11896/j.issn.1005-023X.2018.16.011
  无机非金属及其复合材料 |
La2O3对高钛高炉渣制备微晶泡沫玻璃的影响
严子迪, 冯可芹, 陈长鸿, 税玥
四川大学制造科学与工程学院,成都 610065
Influence of La2O3 on Foam Glass-Ceramics Prepared from High Titanium Blast Furnace Slag
YAN Zidi, FENG Keqin, CHEN Changhong, SHUI Yue
School of Manufacturing Science and Engineering, Sichuan University, Chengdu 610065
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摘要 利用高钛高炉水淬渣和废玻璃粉为基础原料,以CaCO3为发泡剂,Na2B4O7·10H2O为助熔剂,Na3PO4·12H2O为稳泡剂,通过“一步法”烧结制备微晶泡沫玻璃,研究了La2O3的添加对微晶泡沫玻璃物相、结构及性能的影响。结果表明,添加La2O3对晶相种类改变不明显,但会提高晶化程度。随着La2O3添加量由0%(质量分数,下同)增至1.5%,微晶泡沫玻璃的气孔孔径减小,晶粒由粒状变为短棒状,微晶泡沫玻璃的体积密度、抗压强度升高,气孔率、吸水率和导热系数降低。La2O3添加量继续由1.5%增至3.5%,微晶泡沫玻璃的气孔孔径增大,晶粒尺寸逐渐变小直至呈现无规则形状,微晶泡沫玻璃的体积密度、抗压强度降低,气孔率、吸水率和导热系数升高。当La2O3添加量为1.5%时,所制得的微晶泡沫玻璃的综合性能最佳。
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严子迪
冯可芹
陈长鸿
税玥
关键词:  微晶泡沫玻璃  高钛高炉渣  氧化镧  稀土    
Abstract: Foam glass-ceramics were prepared by “one step” sintering method, using high titanium blast furnace slag and glass cullet as the main materials, with adding calcium carbonate as foaming agents, borax as flux-agents, and trisodium phosphate as foam stabilizers. The effects of La2O3 (0wt%-3.5wt%) on the crystalline phases, microstructure, and properties of foam glass-ceramics were studied in this research. The results showed that the crystal phase species of foam glass-ceramics barely changed with La2O3 adding, while the crystallinity increased. With La2O3 increasing from 0wt% to 1.5wt%, the diameter of the bubble decreased. Besides the shape of crystals changed from particulate into short columned. The bulk density and compressive strength of foam glass-ceramics increased. The porosity, water absorption and thermal conductivity decreased. However, with increasing La2O3 from 1.5wt% to 3.5wt%, the diameter of the bubble increased. The shape of crystals turned to irregular shape. The bulk density and compressive strength of foam glass-ceramics decreased, the porosity, water absorption and thermal conductivity increased. The optimum comprehensive property of foam glass-ceramics was achieved at 1.5wt% La2O3.
Key words:  foam glass-ceramics    high titanium blast furnace slag    La2O3    rare earth
               出版日期:  2018-08-25      发布日期:  2018-09-18
ZTFLH:  TQ171.72  
基金资助: 四川省科技支撑项目(2014GZ0011);攀枝花市高新技术及产业化项目(2013CY-C-2)
通讯作者:  冯可芹:通信作者,女,1970年生,博士,教授,博士研究生导师,研究方向为材料合成与制备 E-mail:kqfeng@scu.edu.cn   
作者简介:  严子迪:男,1994年生,硕士研究生,研究方向为材料加工工程 E-mail:934291714@qq.com
引用本文:    
严子迪, 冯可芹, 陈长鸿, 税玥. La2O3对高钛高炉渣制备微晶泡沫玻璃的影响[J]. 材料导报, 2018, 32(16): 2763-2767.
YAN Zidi, FENG Keqin, CHEN Changhong, SHUI Yue. Influence of La2O3 on Foam Glass-Ceramics Prepared from High Titanium Blast Furnace Slag. Materials Reports, 2018, 32(16): 2763-2767.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.16.011  或          http://www.mater-rep.com/CN/Y2018/V32/I16/2763
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