Study on Cyclic Oxidation Behavior of Y and La Modified Ni-10Cr-5Al Alloys
SHANG Genfeng1, HUANG Jiapeng1, WANG Hang2
1 School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000; 2 Institute of Engineering, Jiangxi University of Science and Technology, Ganzhou 341000
Abstract: The cyclic oxidation behavior of Ni-10Cr-5Al (mass fraction,%) alloys containing 0.1% (mass fraction) La or Y-La at 1 100 ℃ and 1 200 ℃ was studied. The kinetics of cyclic oxidation of the alloys were studied by means of thermogravimetric analysis, and the evolution rules of phase, microstructure and composition of the oxides were studied by X-ray diffraction and scanning electron microscopy with energy-dispersive X-ray spectroscopy. The difference of the adhesion of the surface scale of Ni-10Cr-5Al alloys containing La or Y-La at different oxidation temperature was analyzed. The results indicated that the addition of 0.1% (mass fraction) La or Y-La in Ni-10Cr-5Al alloy could not only reduce the thickness of the oxide film, but also improve the adhesion of the oxide film due to the formation of “pinning”, thus the anti-oxidation performance at 1 100 ℃ of the alloys were improved. While the effect of co-doping Y-La was better than that of single adding of La. However, the anti-oxidation performance at 1 200 ℃ of the alloys was deteriorate owing to the severe internal oxidation along the grain boundary.
尚根峰, 黄嘉鹏, 汪航. Y,La改性Ni-10Cr-5Al合金的循环氧化行为研究[J]. 《材料导报》期刊社, 2018, 32(4): 584-588.
SHANG Genfeng, HUANG Jiapeng, WANG Hang. Study on Cyclic Oxidation Behavior of Y and La Modified Ni-10Cr-5Al Alloys. Materials Reports, 2018, 32(4): 584-588.
1 Anderson I E, Gleeson B, Terpstra R L. Development of metallic hot gas filters[C]//Office of Fossil Energy.Washington District of Columbia,United States,2003:1. 2 Peng X, Wang F. High-temperature oxidation of aerospace materials[M].Boca Raton:Chemical Rubber Company Press,2012:237. 3 Naumenko D, Pint B A, Quadakkers W J. Current thoughts on reactive element effects in alumina-forming systems: In memory of John Stringer[J].Oxidation of Metals,2016,86(1):1. 4 Pint B A. Progress in understanding the reactive element effect since the Whittle and Stringer literature review[C]//Proc. John Stringer Symposium on High Temperature Corrosion.ASM International Materials Park,OH:American Society for Microbiology,2003:9. 5 Heuer A H, Hovis D B, Smialek J L, et al. Alumina scale formation: A new perspective[J].Journal of the American Ceramic Society,2011,94(s1):s146. 6 Xu K D, Ren Z M, Li C J. Progress in application of rare metals in superalloys[J].Rare Metals,2014,33(2):111. 7 Li M S, Zhang Y M. A review on effect of reactive elements on oxidation of metals[J].Corrosion Science and Protection Technology,2001,13(6):333(in Chinese). 李美栓,张亚明.活性元素对合金高温氧化的作用机制[J].腐蚀科学与防护技术,2001,13(6):333. 8 Whittle D P, Stringer J. Improvements in high temperature oxidation resistance by additions of reactive elements or oxide dispersions[J].Philosophical Transactions of the Royal Society of London.Series A,Mathematical and Physical Sciences,1980,295:309. 9 Ramanarayanan T A,Ayer R,Petkovic-Luton R,et al.The influence of yttrium on oxide scale growth and adherence[J].Oxidation of Metals,1988,29(5-6):445. 10 Khanna A S, Wasserfuhr C, Quadakkers W J, et al. Addition of yttrium, cerium and hafnium to combat the deleterious effect of sulphur impurity during oxidation of an Ni-Cr-Al alloy[J].Materials Science and Engineering A,1989,120(1):185. 11 Ul-Hamid A. TEM study of scale microstructures formed on Ni-10Cr and Ni-10Cr-5Al alloys with and without Y addition[J].Oxidation of Metals,2002,58(1-2):41. 12 Bennett I J, Sloof W G. The influence of reactive element additions to β-NiAlCr alloys on the morphology of thermally grown oxides[J].Materials at High Temperatures,2003,20(3):395. 13 Tawancy H M.On the behaviour of minor active elements during oxidation of selected Ni-base high-temperature alloys[J].Materials at High Temperatures,2017,34(1):22. 14 Khanna A S, Jonas H, Quadakkers W J. Use of acoustic emission technique to study the spallingbehaviour of oxide scales on Ni-10Cr-8Al containing sulphur and/or yttrium impurity[J].Materials & Corrosion,1989,40(9):552. 15 Kumar A, Nasrallah M, Douglass D L. The effect of yttrium and thorium on the oxidation behavior of Ni-Cr-Al alloys[J].Oxidation of Metals,1974,8(4):227. 16 Pint B A. Experimental observations in support of the dynamic-segregation theory to explain the reactive-element effect[J].Oxidation of Metals,1996,45(1):1. 17 Ul-Hamid A. TEM study of the effect of Y on the scale microstructures of Cr2O3-and Al2O3-forming alloys[J].Oxidation of Metals,2002,58(1-2):23. 18 Ramanathan L V. Role of rare-earth elements on high temperature oxidation behavior of FeCr, NiCr and NiCrAlalloys[J].Corrosion Science,1993,35(s5):871. 19 Sarioglu S, Blachere J R, Pettit F S, et al. The effects of reactive element additions, sulfur removal, and specimen thickness on the oxidation behaviour of alumina-forming Ni-and Fe-base alloys[J].Materials Science Forum,1997,251-254:405. 20 Hou P Y. Segregation phenomena at thermally grown Al2O3/alloy interfaces[J].Annual Review of Materials Research,2008,38(38):275. 21 Golightly F A, Stott F H, Wood G C. The influence of yttrium additions on the oxide-scale adhension to an iron-chromium-aluminum alloy[J].Oxidation of Metals,1976,10(3):163. 22 Song L. Effect of Y on high temperature oxidation resistance of a directionally solidified superalloy[J].Journal of Rare Earths,2004,22(6):794. 23 Chen S F, Ma H P, Ju Q, et al. Effect of rare earth element lanthanum on oxidation behavior of GH230 at 1 000 ℃ in air[J].Journal of Iron and Steel Research International,2009,21(11):45(in Chinese). 陈石富,马惠萍,鞠泉,等.稀土元素La对GH230合金1 000 ℃抗氧化性能的影响[J].钢铁研究学报,2009,21(11):45. 24 Pint B A, Alexander K B. Grain boundary segregation of cation dopants in α-Al2O3scales[J].Journal of the Electrochemical Society,1996,145(6):1819. 25 Guo H B, Li D Q, Zheng L, et al. Effect of co-doping of two reactive elements on alumina scale growth of β-NiAl at 1 200 ℃[J]. Corrosion Science,2014,88(88):197. 26 Pint B A. Optimization of reactive-element additions to improve oxidation performance of alumina-forming alloys[J].Journal of the American Ceramic Society,2003,86(4):686. 27 Pint B A, Tortorelli P F, Wright I G. Effect of cycle frequency on high-temperature oxidation behavior of alumina-forming alloys[J].Oxidation of Metals,2002,58(1):73.