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《材料导报》期刊社  2018, Vol. 32 Issue (4): 584-588    https://doi.org/10.11896/j.issn.1005-023X.2018.04.015
  材料研究 |
Y,La改性Ni-10Cr-5Al合金的循环氧化行为研究
尚根峰1, 黄嘉鹏1, 汪航2
1 江西理工大学材料科学与工程学院,赣州 341000;
2 江西理工大学工程研究院,赣州 341000
Study on Cyclic Oxidation Behavior of Y and La Modified Ni-10Cr-5Al Alloys
SHANG Genfeng1, HUANG Jiapeng1, WANG Hang2
1 School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000;
2 Institute of Engineering, Jiangxi University of Science and Technology, Ganzhou 341000
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摘要 通过添加0.1%(质量分数)的单一稀土La和复合稀土Y-La,研究了两种含稀土的Ni-10Cr-5Al(质量分数,%)合金在1 100 ℃和1 200 ℃下的高温循环氧化行为。采用热重法并结合X射线衍射、扫描电子显微镜、能谱仪等,研究了合金的循环氧化动力学、氧化物的物相和组织成分等演变规律,分析了含稀土Ni-10Cr-5Al合金的氧化膜粘附性能在不同氧化温度下的差异及机制。结果表明,在1 100 ℃时,Ni-10Cr-5Al合金中添加0.1%(质量分数)的La或Y-La,不仅减少了氧化膜的厚度,而且因形成“钉扎”作用提高了氧化膜的粘附性,从而改善了合金的抗循环氧化性能。且复合添加Y-La的效果优于单一添加La的效果。但在1 200 ℃时,合金沿晶界的内氧化加快,反而恶化了合金的抗循环氧化性能。
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尚根峰
黄嘉鹏
汪航
关键词:  NiCrAl合金  循环氧化  稀土元素  活性元素效应    
Abstract: The cyclic oxidation behavior of Ni-10Cr-5Al (mass fraction,%) alloys containing 0.1% (mass fraction) La or Y-La at 1 100 ℃ and 1 200 ℃ was studied. The kinetics of cyclic oxidation of the alloys were studied by means of thermogravimetric analysis, and the evolution rules of phase, microstructure and composition of the oxides were studied by X-ray diffraction and scanning electron microscopy with energy-dispersive X-ray spectroscopy. The difference of the adhesion of the surface scale of Ni-10Cr-5Al alloys containing La or Y-La at different oxidation temperature was analyzed. The results indicated that the addition of 0.1% (mass fraction) La or Y-La in Ni-10Cr-5Al alloy could not only reduce the thickness of the oxide film, but also improve the adhesion of the oxide film due to the formation of “pinning”, thus the anti-oxidation performance at 1 100 ℃ of the alloys were improved. While the effect of co-doping Y-La was better than that of single adding of La. However, the anti-oxidation performance at 1 200 ℃ of the alloys was deteriorate owing to the severe internal oxidation along the grain boundary.
Key words:  NiCrAl alloy    cyclic oxidation    rare earth elements    reactive element effect (REE)
出版日期:  2018-02-25      发布日期:  2018-02-25
ZTFLH:  TG146  
  V252.2  
基金资助: 国家自然科学基金(51401095); 江西省自然科学基金(20171BAB216004); 江西省科技厅留学归国人员扶助计划(20161BBH80030); 江西理工大学博士启动基金(jxxjbs15001)
通讯作者:  汪航:,男,1984年生,博士,副教授,研究方向为合金相图热力学、相变动力学及高温合金设计与优化 E-mail:wanghang84@hotmail.com   
作者简介:  尚根峰:男,1992年生,硕士研究生,研究方向为镍基高温合金的凝固与氧化行为 E-mail:2461626989@qq.com
引用本文:    
尚根峰, 黄嘉鹏, 汪航. Y,La改性Ni-10Cr-5Al合金的循环氧化行为研究[J]. 《材料导报》期刊社, 2018, 32(4): 584-588.
SHANG Genfeng, HUANG Jiapeng, WANG Hang. Study on Cyclic Oxidation Behavior of Y and La Modified Ni-10Cr-5Al Alloys. Materials Reports, 2018, 32(4): 584-588.
链接本文:  
https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.04.015  或          https://www.mater-rep.com/CN/Y2018/V32/I4/584
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