腐殖酸基石墨化材料的制备及其电化学性能

doi:10.11896/j.issn.1005-023X.2018.03.004

《材料导报》期刊社

2018, Vol. 32

Issue (3): 368-372 https://doi.org/10.11896/j.issn.1005-023X.2018.03.004

材料与可持续发展(一)—— 面向洁净能源的先进材料｜

腐殖酸基石墨化材料的制备及其电化学性能

司东永,黄光许,张传祥,邢宝林,陈泽华,陈丽薇,张浩然

河南理工大学化学与化工学院,焦作 454003

Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials

Dongyong SI,Guangxu HUANG,Chuanxiang ZHANG,Baolin XING,Zehua CHEN,Liwei CHEN,Haoran ZHANG

College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454003

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摘要

以腐殖酸为前驱体,通过高温热处理制备锂离子电池负极材料。采用扫描电子显微镜(SEM)、X射线衍射(XRD)和电化学测试系统对该材料的形貌、微晶结构和电化学性能进行表征。结果表明,腐殖酸基石墨化材料呈现出较为规整的石墨片层结构,且随着石墨化温度的升高,所得材料的石墨化度也越来越高。腐殖酸基石墨化材料均表现出良好的电化学性能,石墨化温度为2 800 ℃所制备的石墨化材料的首次放电比容量为356.7 mAh/g,充电比容量为277.6 mAh/g,首次充放电的库仑效率为77.81%,在1C和2C倍率下50次充放电循环后的容量保持率分别高达99.4%、95.9%,是一种理想的锂离子电池负极材料。

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关键词: 腐殖酸石墨化材料锂离子电池负极材料电化学性能

Abstract:

The lithium-ion battery anode material have been prepared from humic acid through high-temperature heat treatment. The morphology, microcrystalline structure and electrochemical properties of as-prepared activated material were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and electrochemical testing system. The results indicated that the humic acid-based graphitized materials showed a more regular graphite lamellar structure, and the degree of graphitization of the materials was also getting higher and higher with the increase of graphitization temperature. The humic acid-based graphitized mate-rials all presented good electrochemical performance. The graphitized material with the temperature of 2 800 ℃ had a first discharge specific capacity of 356.7 mAh/g and a charge capacity of 277.6 mAh/g, and the initial coulombic efficiencies was 77.81%. The capacity retention rate after 50 cycles at 1C and 2C rates was as high as 99.4% and 95.9%, respectively. The above results suggest that the humic acid-based graphitized material is an ideal lithium ion battery anode material.

Key words: humic acid graphitized material lithium-ion batteries anode material electrochemical performance

出版日期: 2018-02-10 发布日期: 2018-02-10

ZTFLH:

TQ424.1

基金资助: 国家自然科学基金(U1361119);国家自然科学基金(41472127);国家自然科学基金(41372161);河南省高校科技创新团队(16IRTSTHN005);河南省教育厅自然科学研究计划项目(2011B44006);河南理工大学博士基金(B2010-82)

作者简介: 司东永:男,1990年生,硕士研究生,研究方向为锂离子电池负极材料 E-mail: 849294938@qq.com|张传祥:通信作者,男,1970年生,博士,教授,博士研究生导师,从事煤基炭材料及电化学应用等方面的教学及研究工作 E-mail: zcx223@hpu.edu.cn

引用本文:

司东永, 黄光许, 张传祥, 邢宝林, 陈泽华, 陈丽薇, 张浩然. 腐殖酸基石墨化材料的制备及其电化学性能[J]. 《材料导报》期刊社, 2018, 32(3): 368-372.
Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials. Materials Reports, 2018, 32(3): 368-372.

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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.03.004 或 http://www.mater-rep.com/CN/Y2018/V32/I3/368

图1 山西腐殖酸石墨化材料的SEM图(2 000×)

图2 山西腐殖酸石墨化材料的XRD谱

图3 山西腐殖酸石墨化电极材料在0.1C下的首次充放电曲线

表1 山西腐殖酸石墨化电极材料在不同电流密度下的放电比容量和容量保持率

图4 山西腐殖酸石墨化电极材料的循环及倍率性能曲线(电子版为彩图)

图5 山西腐殖酸石墨化电极材料的循环伏安曲线

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