高熵材料在锂/钠离子电池中的应用研究进展

doi:10.11896/cldb.23040299

材料导报

2024, Vol. 38

Issue (22): 23040299-8 https://doi.org/10.11896/cldb.23040299

无机非金属及其复合材料

高熵材料在锂/钠离子电池中的应用研究进展

王培远¹, 邓根成¹, 朱登贵¹, 李永浩¹, 孙淑敏^1,*, 方少明^1,2,*

1 郑州轻工业大学材料与化学工程学院,郑州 450001
2 郑州轻工业大学河南省表界面科学重点实验室,郑州 450001

Research Progress of High-entropy Materials for Lithium/Sodium Ions Batteries

WANG Peiyuan¹, DENG Gencheng¹, ZHU Denggui¹, LI Yonghao¹, SUN Shumin^1,*, FANG Shaoming^1,2,*

1 College of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China
2 Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450001, China

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摘要高熵材料(HEMs)包括高熵合金(HEAs)、高熵氧化物(HEOs)和其他高熵化合物,是多种元素以等物质的量比或近等物质的量比组成的新型多主元材料,以其独特的晶体结构特征,表现出许多不同于传统材料的组织和性能特点,已经成为国际材料学术界的重要研究热点之一,在新能源相关领域也引起了极大的关注。本文从高熵材料的概念及发展历程出发,主要综述了高熵金属氧化物、高熵普鲁士蓝类似物、高熵磷酸盐等在锂离子电池与钠离子电池正极材料方面,高熵金属氧化物、高熵金属硫化物、高熵合金、高熵MXene等在锂/钠离子电池负极材料方面,以及无序盐晶材料、高熵锂石榴石和高熵氧化物陶瓷粉末在固态电解质方面的研究进展。并对高熵材料在锂/钠离子电池中未来研究发展趋势进行了展望,为新能源材料的研发提供新思路。

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	王培远
	邓根成
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	李永浩
	孙淑敏
	方少明

关键词: 高熵材料锂离子电池钠离子电池电化学储能

Abstract: High-entropy materials(HEMs) including high-entropy alloys(HEAs), high-entropy oxides(HEOs), and other high-entropy compounds are new multi-principal materials composed of various elements with equal or nearly equal molar ratio. HEMs, with their unique crystal structure characteristics, exhibit many different organizational and performance characteristics from conventional materials, have become one of the important research hotspots in the international materials academia. They have also attracted great attention in the field of new energy and related fields. The concept and development process of high entropy materials were first introduced. This article reviews the research progress of high-entropy metal oxides, high-entropy Prussian blue analogues, and high-entropy phosphates in the cathode materials of lithium-ion batteries and sodium ion batteries. It also reviews the research progress of high-entropy metal oxides, high-entropy metal sulfides, high-entropy alloys, and high-entropy MXene in the anode materials of lithium-ion batteries and sodium ion batteries, as well as the research progress of disordered rock-salt materials, high-entropy lithium garnet, and high-entropy oxide ceramic powders in solid electrolytes. Finally, the future research trends of high entropy materials in lithium-ion batteries and sodium ion batteries were prospected, providing new ideas for the research and development of new energy materials.

Key words: high-entropy materials lithium ion battery sodium ion battery electrochemical energy storage

出版日期: 2024-11-25 发布日期: 2024-11-22

ZTFLH:

TM911.3

基金资助: 国家自然科学基金(52272243);河南省重点研发与推广专项(221111240600;222102240030);河南省自然科学基金(222300420581)

通讯作者: *孙淑敏,郑州轻工业大学材料与化学工程学院副教授、硕士研究生导师。2002年7月于郑州大学获得理学学士学位,2009年7月于中国科学院大连化学物理研究所物理化学专业获得博士学位。目前主要研究领域为电催化、能源转换与存储材料。已发表ACS Nano、J. Mater. Chem. A、J. Power Sources、Dalton. Trans.等SCI论文30余篇。
方少明,郑州轻工业大学材料与化学工程学院教授、博士研究生导师、河南省表界面科学重点实验室主任。1983年北京航空航天大学复合材料专业本科毕业,1988年河北工业大学高分子材料专业硕士毕业后到郑州轻工业大学工作至今,2005年河北工业大学材料物理与化学专业博士毕业。目前主要从事功能材料、材料物理与化学等方面的研究工作。已发表论文300余篇,包括Angew. Chem.、Adv. Funct. Mater.、Adv. Energy Mater.、ACS Nano等。smsun@zzuli.edu.cn;mingfang@zzuli.edu.cn

作者简介: 王培远,郑州轻工业大学材料与化学工程学院副教授、硕士研究生导师。2002年7月、2005年7月于郑州大学获得理学学士学位和硕士学位,2009年7月于中国科学院大连化学物理研究所物理化学专业获得博士学位。目前主要研究领域为电化学、能源转换与存储材料。已发表ACS Nano、J. Mater. Chem. A、J. Power Sources.Chem. Commun.等SCI论文40余篇。

引用本文:

王培远, 邓根成, 朱登贵, 李永浩, 孙淑敏, 方少明. 高熵材料在锂/钠离子电池中的应用研究进展[J]. 材料导报, 2024, 38(22): 23040299-8.
WANG Peiyuan, DENG Gencheng, ZHU Denggui, LI Yonghao, SUN Shumin, FANG Shaoming. Research Progress of High-entropy Materials for Lithium/Sodium Ions Batteries. Materials Reports, 2024, 38(22): 23040299-8.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23040299 或 http://www.mater-rep.com/CN/Y2024/V38/I22/23040299

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