Synthesis and Application of DopedⅠ-Ⅲ-Ⅵ Multiple Quantum Dots
CHEN Yuanhong1, CHEN Ting1,*, XIE Zhixiang2, XU Yanqiao3, HU Zehao3, LIN Jian1
1 Institute of Materials Science & Devices, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China 2 School of Chemical and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China 3 School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, Jiangxi, China
Abstract: The Ⅰ-Ⅲ-Ⅵ multiple quantum dots (QDs) have excellent physicochemical properties such as small particle size, broad half-peak width, large Stokes shift, anti-photobleaching stability, environment friendliness, and their emission range can be continuously tuned in the visible to near-infrared light region by changing the chemical composition. Moreover, they can avoid the use of heavy metal elements such as Cd, Hg and Pb and highly toxic anions, i.e.Se, Te, P and As. These advantages make them promising candidates to replace traditional binary QDs in the fields of solar cells, light-emitting diodes, photodetectors, bioimaging, etc. Compared with the binary QDs, the multiple QDs contain many different types of metal ions and have the problem of different reaction rates between metal ions, causing more defects inside the crystal. Therefore, its fluorescence performance still needs to be improved. The doping of transition metal ions (e.g.Zn2+, Mn2+ or Cu+) can effectively modulate the band gap width of multiple QDs, which can not only increase the Stokes shift of QDs, but also promote the radiation recombination, thus effectively broadening the luminescence range and increasing the quantum yield. This paper elaborates the luminescence mechanism of doped Ⅰ-Ⅲ-Ⅵ multiple QDs, and introduces the characteristics of organic phase and aqueous phase preparation of this type of QDs, respectively. Multiple QDs synthesized by organic phase have the advantages of good crystallinity and high fluorescence quantum yield, while those synthesized by aqueous phase also have obvious advantages such as safety, environmental friendliness and good biocompatibility. Meanwhile, the paper reviews the effects of transition metal ion doping and co-doping on the band gap width, visible light absorption range and fluorescence intensity of multiples QDs. Finally, the progress of doped multiple QDs in the fields of optoelectronic, biomedical applications and fluorescences is also summarized.
1 Veeramani V, Bao Z, Chan M H, et al. Journal of Solid State Chemistry, 2018, 270, 71. 2 Panfil Y E, Oded M, Banin U. Angewandte Chemie International Edition, 2017, 57(16), 4274. 3 Movlarooy T. Materials Research Express, 2018, 5(3), 035032. 4 Bai Z, Ji W, Han D, et al. Chemistry of Materials, 2016, 28(4), 1085. 5 Wu R, Wang T, Wu M, et al. Chemical Engineering Journal, 2018, 348, 447. 6 Luo S, Ke J, Zhang Q, et al. Applied Catalysis B Environmental, 2018, 221, 215. 7 Rossetti R, Nakahara S, Brus L E. Journal of Chemical Physics, 1983, 79(2), 1086. 8 Murray C B, Norris D J, Bawendi M G. Journal of Luminescence, 1993, 115(19), 8706. 9 Colvin V L, Schlamp M C, Alivisatos A P. Nature, 1994, 370(6488), 354. 10 Bhargava R N, Gallagher D, Hong X, et al. Physical Review Letters, 1994, 72(3), 416. 11 Bruchez M, Moronne M, Gin P, et al. Science, 1998, 281(5385), 2013. 12 Chan W, Nie S. Science, 1998, 281(5385), 2016. 13 Peng Z A, Peng X G. Journal of the American Chemical Society, 2001, 123(7), 1389. 14 Peng Z A, Peng X G. Journal of the American Chemical Society, 2001, 123(1), 183. 15 Derfus A M, Chan W C, Bhatia S N. Nano Letters, 2004, 4(1), 11. 16 Castro S L, Bailey S G, Raffaelle R P, et al. Chemistry of Materials, 2003, 15(16), 3142. 17 Dai M, Ogawa S, Kameyama T, et al. Journal of Materials Chemistry, 2012, 22(25), 12851. 18 Aldakov D, Aurélie L, Reiss P, et al. Journal of Materials Chemistry C, 2013, 1(24), 3756. 19 Pan D C, An L J, Sun Z G, et al. Journal of the American Chemical Society, 2008, 130(17), 5620. 20 Nose K, Soma Y, Omata T, et al. Chemistry of Materials, 2009, 21(13), 2607. 21 Batabyal S K, Tian L, Venkatram N, et al. Journal of Physical Chemistry C, 2009, 113(33), 15037. 22 Xiang W D, Yang H L, Liang X J, et al. Journal of Materials Chemistry C, 2013, 1(10), 2014. 23 Brus L E. In:Quantum size effects in the electronic properties of small semiconductor crystallites, Pullman B, Jortner J, Nitzan A, Gerber B, ed. , Dynamics on Surfaces, USA, 1984, pp. 431. 24 Chen T, Ren Y L, Xu Y Q, et al. Journal of Alloys and Compounds, 2020, 858(18), 158084. 25 Kolny-Olesiak J, Weller H. ACS Applied Materials & Interfaces, 2013, 5(23), 12221. 26 Stam W, Berends A C, Cdm Donegá. ChemPhysChem, 2016, 17(5), 550. 27 Li W J, Pan Z X, Zhong X H. Journal of Materials Chemistry A, 2015, 3(4), 1649. 28 Kuzuya O T. Journal of Luminescence, 2013, 133, 121. 29 Peng X G. Chemistry, 2002, 8(2), 334. 30 Chen S Q, Ahmadiantehrani M, Zhao J L, et al. Journal of Alloys and Compounds, 2016, 665, 137. 31 Nakamura H, Kato W, Uehara M, et al. Chemistry of Materials, 2006, 18(14), 3330. 32 Torimoto T, Adachi T, Okazaki K I, et al. Journal of the American Chemical Society, 2007, 129(41), 12388. 33 Feng J, Sun M, Yang F, et al. Chemical Communications, 2011, 47(22), 6422. 34 Zhang W, Zhong X. Inorganic Chemistry, 2011, 50(9), 4065. 35 Tang X, Ho W, Xue J M. Journal of Physical Chemistry C, 2012, 116(17), 9769. 36 Fahmi M Z, Chang J Y. Procedia Chemistry, 2016, 18, 112. 37 Mazing D S, Korepanov O A, Aleksandrova O A, et al. Optics and Spectroscopy, 2018, 125(5), 773. 38 Yang Y, Mao B, Gong G, et al. International Journal of Hydrogen Energy, 2019, 44(30), 15882. 39 Regulacio M D, Win K Y, Lo S L, et al. Nanoscale, 2013, 5(6), 2322. 40 Yang W T, Guo W S, Zhang T B, et al. Journal of Materials Chemistry B, 2015, 3(43), 8518. 41 Liu Y, Chen X Q, Ma Q. New Journal of Chemistry, 2018, 46(2), 4102. 42 Deng D W, Qu L G, Cheng Z Q, et al. Journal of Luminescence, 2014, 146(1), 364. 43 Liu Y F, Tang X S, Deng M, et al. Journal of Luminescence, 2018, 202, 71. 44 Deng D W, Cao J, Qu L Z, et al. Physical Chemistry Chemical Physics, 2013, 15(14), 5078. 45 Chen S, Demillo V, Lu M, et al. RSC Advances, 2016, 6(56), 51161. 46 Xu Y Q, Chen T, Hu X B, et al. Journal of Colloid and Interface Science, 2017, 496, 479. 47 Zhang B T, Yang C B, Gao Y, et al. Nanotheranostics, 2017, 1(1), 131. 48 Jiang T T, Song J L Q, Wang H J, et al. Journal of Materials Chemistry B, 2015, 3(11), 2402. 49 Cao S, Ji W Y, Zhao J L, et al. Journal of Materials Chemistry C, 2016, 4(3), 581. 50 Liu Z P, Liu S S. Analytical & Bioanalytical Chemistry, 2018, 410(17), 4145. 51 Sousa V, Gonçalves B F, Franco M, et al. Chemistry of Materials, 2019, 31(1), 260. 52 Ghanbari K, Roushani M, Soheyli E, et al. Materials Science and Engineering:C, 2019, 102, 653. 53 Norris D J, Yao N, Charnock F T, et al. Nano Letters, 2001, 1(1), 3. 54 Hanif K M, Meulenberg R W, Strouse G F. Journal of the American Chemical Society, 2002, 124(38), 11495. 55 Mikulec F V, Kuno M, Bennati M, et al. MRS Online Proceeding Library Archive, 2000, 582(11), 2532. 56 Erwin S C, Zu L, Haftel M I, et al. Nature, 2005, 436(7047), 91. 57 Mao B, Chuang C H, Wang J, et al. Journal of Luminescence, 2011, 115(18), 8945. 58 Luo Z S, Zhang H, Huang J, et al. Journal of Colloid and Interface Science, 2012, 377(1), 27. 59 Komarala V K, Xie C, Wang Y Q, et al. Journal of Applied Physics, 2012, 111(12), 124314. 60 Zhu J T, Mei S L, Yang W, et al. Journal of Colloid and Interface Science, 2017, 506, 27. 61 Li C, Wu P. Luminescence, 2019, 324, 782. 62 Chang C C, Chen J K, Chen C P, et al. ACS Applied Materials & Interfaces, 2013, 5(21), 11296. 63 Sun M M, Chen Z Y, Li J R, et al. Electrochimica Acta, 2018, 269, 429. 64 Hamanaka Y, Ozawa K, Kuzuya T. Journal of Physical Chemistry Letters, 2014, 118(26), 14562. 65 Zhang J, Xie R G, Yang W S. Chemistry of Materials, 2011, 23(14), 3357. 66 Chi T, Thuy U, Huyen T, et al. Journal of Electronic Materials, 2016, 45(5), 2449. 67 Rogach A L, Franzl T, Klar T A, et al. Journal of Physical Chemistry C, 2007, 111(40), 14628. 68 Wang Y, Tang Z Y, Correa-Duarte M A, et al. Journal of Physical Chemistry B, 2004, 108(40), 15461. 69 Xiang W D, Xie C P, Wang J, et al. Journal of Alloys and Compounds, 2014, 588, 114. 70 Chen T, Xu Y Q, Wang L J, et al. Chemistry-A European Journal, 2018, 24(61), 16407. 71 Tang X S, Yu K, Xu Q H, et al. Journal of Materials Chemistry, 2011, 21, 11239. 72 Tang X S, Ho W B A, Xue J M. Journal of Physical Chemistry C, 2012, 116(17), 9769. 73 Wang X, Xie C P, Zhong J S, et al. Journal of Alloys and Compounds, 2015, 648, 127. 74 Kong W G, Zhang B P, Li R F, et al. Applied Surface Science, 2015, 327, 394. 75 Schimpf A M, Knowles K E, Carroll G M, et al. Accounts of Chemical Research, 2015, 48(7), 1929. 76 Vlaskin V A, Janssen N, Van R J, et al. Nano Letters, 2010, 10(9), 3670. 77 Alivisatos A P. Science, 1996, 271(5251), 933. 78 Pradhan N, Adhikari S D, Nag A, et al. Angewandte Chemie International Edition, 2017, 56(25), 7038. 79 Yang Y A, Chen O, Angerhofer A, et al. Journal of the American Chemical Society, 2017, 128(38), 12428. 80 Cao S, Li C M, Wang L, et al. Scientific Reports, 2014, 4, 7510. 81 Silva A S, Loureno S A, Dantas N O. Physical Chemistry Chemical Phy-sics, 2016, 18(8), 6069. 82 Abate M A, Dehvari K, Chang J Y, et al. Dalton Transactions, 2019, 48(42), 16115. 83 Hua J, Zhang Y, Yuan X, et al. Superlattices and Microstructures, 2014, 73, 214. 84 Sabri N S, Deni M S, Zakaria A, et al. Physics Procedia, 2012, 25, 233. 85 Cao S, Zheng J J, Dai C C, et al. Journal of Materials Science, 2018, 53, 1286. 86 Kim J H, Kim K H, Yoon S Y, et al. ACS Applied Materials & Interfaces, 2019, 11(8), 8250. 87 Jana S, Srivastava B B, Pradhan N. Journal of Physical Chemistry Letters, 2011, 2(14), 1747. 88 Srivastava B B, Jana S, Pradhan N. Journal of the American Chemical Society, 2011, 133(4), 1007. 89 Raevskaya A, Rozovik O, Novikova A, et al. RSC Advances, 2018, 8, 7550. 90 Zeng R S, Shen R A, Zhao Y Q, et al. CrystEngComm, 2014, 16(16), 3414. 91 Guchhait A, Pal A J. ACS Applied Materials & Interfaces, 2013, 5(10), 4181. 92 Zhou P, Zhang X S, Li L, et al. Optical Materials Express, 2015, 5(9), 2069. 93 Galiyeva P, Alem H, Rinnert H, et al. Inorganic Chemistry Frontiers, 2019, 6(6), 1422. 94 Zhu M B, Li Y X, Tian S Q, et al. Journal of Colloid and Interface Science, 2018, 534, 509. 95 Pradhan N. ChemPhysChem, 2016, 17(8), 1087. 96 Carey G H, Abdelhady A L, Ning Z, et al. Chemical Reviews, 2015, 115(23), 12732. 97 Cai C Q, Zhai L L, Ma Y H, et al. Journal of Power Sources, 2017, 341, 11. 98 Zhang H, Fang W J, Zhong Y Y, et al. Journal of Colloid and Interface Science, 2019, 547, 267. 99 Yue L, Rao H S, Du J, et al. RSC Advances, 2018, 8(7), 3637. 100 Park J, Sajjad M T, Jouneau P H, et al. Journal of Materials Chemistry A, 2016, 4(3), 827. 101 Pan Z X, Mora-Seró I, Shen Q, et al. Journal of the American Chemical Society, 2014, 136(25), 9203. 102 Pan Z, Zhao K, Wang J, et al. ACS Nano, 2013, 7(6), 5215. 103 Du J, Du Z L, Hu J S, et al. Journal of the American Chemical Society, 2016, 138(12), 4201. 104 Zhang L L, Pan Z X, Wang W, et al. Journal of Materials Chemistry A, 2017, 5(40), 21442. 105 Zhang H, Fang W J, Wang W R, et al. ACS Applied Materials & Interfaces, 2019, 11(7), 6927. 106 Li T L, Lee Y L, Teng H. Energy & Environmental Science, 2012, 5(1), 5315. 107 Wang R B, Peng Z Y, Chen W, et al. Journal of Materials Science Materials in Electronics, 2015, 26(4), 2016. 108 Wang W, Feng W L, Du J, et al. Advanced Materials, 2018, 30(11), 1705746. 109 Jiao S, Du J, Du Z L, et al. Journal of Physical Chemistry Letters, 2017, 8(3), 559. 110 Li B X, Lu M X, Feng J T, et al. Journal of Materials Chemistry C, 2020, 8(31), 10676. 111 Da Q Q, Duty C E, Hu M Z. Small, 2010, 6(15), 1577. 112 Lin C C, Liu R S. Journal of Physical Chemistry Letters, 2011, 2(11), 1268. 113 Hu Y S, Zhuang W D, Ye H Q, et al. Journal of Alloys and Compounds, 2005, 390(1-2), 226. 114 Wood V, Bulovi V. Nano Reviews, 2010, 1, 5202. 115 Jung H, Chung W, Lee C H, et al. Applied Optics, 2013, 52(10), 1992. 116 Chung W, Jung H, Lee C H, et al. Journal of Materials Chemistry C, 2014, 2(21), 4227. 117 Peng L C, Li D, Zhang Z, et al. Nano Research, 2015, 8(10), 3316. 118 Wei J X, Hu Z, Zhou W J, et al. Journal of Colloid and Interface Science, 2021, 602, 307. 119 Guan H L, Zhao S Y, Wang H X, et al. Nano Energy, 2017, 67, 104219. 120 Xu Y Q, Chen T, Xie Z X, et al. Chemical Engineering Journal, 2021, 403, 126372. 121 Li Z T, Li J X, Deng Z H, et al. IEEE Transactions on Electron Devices, 2021, 68(4), 1738. 122 Achilefu S. Chemical Reviews, 2010, 110(5), 2575. 123 Frangioni J V. Current Opinion in Chemical Biology, 2003, 7(5), 626. 124 Pons T, Pic E, Lequeux N, et al. ACS Nano, 2010, 4(5), 2531. 125 Deng D W, Qu L Z, Zhang J, et al. ACS Applied Materials & Interfaces, 2013, 5(21), 10858. 126 Matysiak E, Bujak P, Augustin E, et al. Nanoscale, 2017, 10(3), 1286. 127 Zang Z G, Zeng X F, Wang M, et al. Sensors and Actuators B:Chemical, 2017, 252, 1179. 128 Song J, Ma C, Zhang W, et al. ACS Applied Materials & Interfaces, 2016, 8(37), 24826. 129 MansurA, Mansur H S, Carvalho S M, et al. Contrast Media & Molecular Imaging, 2017, 2017, 3896107. 130 Pooja D, Saini S, Thakur A, et al. Journal of Hazardous Materials, 2017, 328, 117. 131 Ackerman C M, Chang C J. Journal of Biological Chemistry, 2017, 293, 4628. 132 Seok Y, Byun J Y, Shim A W B, et al. Analytica Chimica Acta, 2015, 886(30), 182. 133 Szpunar J, Bettmer J, Robert M, et al. Talanta, 1997, 44(8), 1389. 134 Zhu Y, Inagaki K, Chiba K. Journal of Analytical Atomic Spectrometry, 2009, 24(9), 1179. 135 Liu Y F, Zhu T, Deng M, et al. Journal of Luminescence, 2018, 201, 182. 136 Liu Y F, Deng M, Tang X, et al. Sensors & Actuators B Chemical, 2016, 233, 25. 137 Yin H, Truskewycz A, Cole I S. Microchimica Acta, 2020, 187(6), 336.