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材料导报  2023, Vol. 37 Issue (9): 21040018-6    https://doi.org/10.11896/cldb.21040018
  高分子与聚合物基复合材料 |
基于刚果红的高分子染料制备及pH响应变色性能
冒海燕1, 朱淼1, 朱雪峰1, 郭子怡1, 廖成成1, 何雪梅1, 宋晓蕾2,*
1 盐城工学院纺织服装学院,江苏 盐城 224051
2 福建省新型功能性纺织纤维及材料重点实验室,福州 350108
Preparation of Congo Red Based Polymeric Dye and Its pH Responsive Property
MAO Haiyan1, ZHU Miao1, ZHU Xuefeng1, GUO Ziyi1, LIAO Chengcheng1, HE Xuemei1, SONG Xiaolei2,*
1 School of Textile & Clothing, Yancheng Institute of Technology, Yancheng 224051, Jiangsu, China
2 Fujian Key Laboratory of Novel Functional Textile Fibers and Materials, Fuzhou 350108, China
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摘要 为开发pH响应变色智能纺织品,以异佛尔酮二异氰酸酯为硬段、聚乙二醇1000为软段、1,4-丁二醇为扩链剂、刚果红为发色体,制备了具有pH响应变色功能的水性聚氨酯高分子染料,并将其用于棉织物涂层。通过傅里叶红外光谱、紫外-可见光光谱等表征该高分子染料的结构及颜色特征,并详细探讨了该高分子染料及其涂层织物的pH响应变色性能。结果表明,刚果红高分子化后的最大吸收波长存在12 nm的红移。随着pH值降低,由于刚果红中氨基质子化并转变为醌式结构,高分子染料溶液的最大吸收波长由510 nm迁移至605 nm,吸收峰峰形变宽,颜色由红色变成蓝紫色。另外,该高分子染料涂层棉织物在pH值小于3的环境中逐渐变成蓝色,呈现出显著的pH响应变色行为、较高的变色灵敏度、良好的可逆性及pH响应长期稳定性,且能够循环使用于染色废水检测。
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冒海燕
朱淼
朱雪峰
郭子怡
廖成成
何雪梅
宋晓蕾
关键词:  刚果红  水性聚氨酯  高分子染料  pH响应变色  可逆    
Abstract: A waterborne polyurethane polymeric dye was prepared with isophorone diisocyanate as hard segment, polyethylene glycol 1000 as soft segment, 1, 4-butanediol as chain extender, and congo red as chromophore, respectively. And then, the waterborne polyurethane polymeric dye was applied onto cotton fabrics via coating to develop a smart textile with pH responsive property. The structures and color properties of the polymer dye were investigated by Fourier transform infrared spectroscopy and UV-Vis spectrum. Also, the pH responsive properties of the polymer dye and its coated cotton fabrics were discussed in detail. Results show that the maximum absorption wavelength of the polymeric dye shows a bathochromic shift of 12 nm. As the pH of the polymeric dye solution decreases, its maximum absorption wavelength shifts from 510 nm to 605 nm and the peak widens, accompanied with the color changing from red to bluish violet, because the structure of congo red after amino protonation transfers into quinoid structure. In addition, the polymeric dye coated cotton fabric gradually turns blue at pH<3, shows significant pH responsive behavior, high sensitivity, good reversibility and long-term stability, and can be repeatedly applied in testing dyeing wastewater.
Key words:  congo red    waterborne polyurethane    polymeric dye    pH response    reversibility
出版日期:  2023-05-10      发布日期:  2023-05-04
ZTFLH:  TS190.2  
基金资助: 江苏省自然科学基金(BK20191045);盐城工学院校级科研项目(xjr2019030);纺织服装福建省高校工程研究中心开放基金(MJXY-KF-201906);福建省自然科学基金(2020J0849)
通讯作者:  *宋晓蕾,闽江学院服装与设计工程学院副教授、硕士研究生导师。2004年纺织工程专业本科毕业,2004年苏州大学服装设计与工程专业硕士毕业后参加工作,2017年纺织科学与工程专业博士毕业。目前主要从事微纳米材料、低频电磁屏蔽方面的研究工作,发表论文20余篇。sxlyanc@126.com   
作者简介:  冒海燕,盐城工学院纺织服装学院讲师。2000年江南大学轻化工程专业本科毕业,2012年江南大学纺织工程专业硕士毕业,2016年江南大学纺织科学与工程专业博士毕业后到盐城工学院工作至今。目前主要从事刺激响应性聚氨酯的制备及应用等方面的研究工作。发表论文10余篇,包括Sensors Actuators B:Chemical、Materials Letters、RSC Advances等。
引用本文:    
冒海燕, 朱淼, 朱雪峰, 郭子怡, 廖成成, 何雪梅, 宋晓蕾. 基于刚果红的高分子染料制备及pH响应变色性能[J]. 材料导报, 2023, 37(9): 21040018-6.
MAO Haiyan, ZHU Miao, ZHU Xuefeng, GUO Ziyi, LIAO Chengcheng, HE Xuemei, SONG Xiaolei. Preparation of Congo Red Based Polymeric Dye and Its pH Responsive Property. Materials Reports, 2023, 37(9): 21040018-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21040018  或          http://www.mater-rep.com/CN/Y2023/V37/I9/21040018
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