Effect of Electrochemical Corrosion on Oxygen Transport Resistance in Gas Diffusion Layer
HONG Kang1,2, ZHU Kai1,2, LIU Shengchu1,2, LI Shang1,2,3,*, PAN Mu1,2,3
1 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology, Wuhan 430070, China 2 Key Laboratory of Hubei Province for Fuel Cells, Wuhan University of Technology, Wuhan 430070, China 3 Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Foshan 528200, Guangdong, China
Abstract: The off-line accelerated stress tests were used to conduct the electrochemical corrosion of gas diffusion layer for different hours, and the effect of the electrochemical corrosion time on the oxygen transport resistance of gas diffusion layer was evaluated by limiting current methods. The results show that the dry region of gas diffusion layer is narrower, and the oxygen transport resistance increases significantly after electrochemical corrosion. When the relative pressure is 150 kPa and the oxygen mole fraction is 21%, the oxygen transport resistance values of gas diffusion layer after 48 h and 72 h electrochemical corrosion increase by approximately 61.82 s/m and 95.62 s/m, respectively. The morphology of the gas diffusion layer was studied by scanning electron microscopy (SEM). The reason why the water management ability of gas diffusion layer decreases after electrochemical corrosion was analyzed by SEM image and contact angles.
作者简介: 洪亢,武汉理工大学硕士研究生。2018年于南京工业大学获得学士学位。曾以第一作者在Journal of the Electrochemical Society上发表论文1篇。研究内容主要关于质子交换膜燃料电池耐久性及氧传质问题。 李赏,武汉理工大学研究员、硕士研究生导师。先后于1997年、2000年、2003年在南开大学获得学士学位、硕士学位和博士学位,2003—2005年进入清华大学核能与新能源技术研究院,2005年后在武汉理工大学材料复合新技术国家重点实验室工作,2009—2010年在加拿大国家研究院做访问学者。主要研究方向包括质子交换膜燃料电池关键材料制备及性能、质子交换膜燃料电池关键材料结构表征、质子交换膜燃料电池关键材料耐久性。负责国家重点研发计划、国家自然科学基金等项目五项,发表论文20余篇,申请国家发明专利七项,授权一项。
引用本文:
洪亢, 朱凯, 刘声楚, 李赏, 潘牧. 电化学腐蚀对气体扩散层氧传质的影响[J]. 材料导报, 2022, 36(20): 21030161-5.
HONG Kang, ZHU Kai, LIU Shengchu, LI Shang, PAN Mu. Effect of Electrochemical Corrosion on Oxygen Transport Resistance in Gas Diffusion Layer. Materials Reports, 2022, 36(20): 21030161-5.
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