氨硼烷水解制氢催化剂及其限域载体的形貌可控合成研究进展

doi:10.11896/cldb.20100246

材料导报

2022, Vol. 36

Issue (22): 20100246-9 https://doi.org/10.11896/cldb.20100246

无机非金属及其复合材料

氨硼烷水解制氢催化剂及其限域载体的形貌可控合成研究进展

李想¹, 张军^2,*

1 河南科技大学材料科学与工程学院,河南洛阳 471023
2 河南科技大学化工与制药学院,河南洛阳 471023

Research Progress of Shape-controlled Synthesis of Catalysts and Domain Limited Supports for Ammonia Borane Dehydrogenation

LI Xiang¹, ZHANG Jun^2,*

1 School of Material Science and Engineering, Henan University of Science & Technology, Luoyang 471023, Henan, China
2 Chemical Engineering & Pharmaceutics School, Henan University of Science & Technology, Luoyang 471023, Henan, China

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摘要氨硼烷具有高储氢含量(19.6%,质量分数),在普通贮存条件下稳定,被认为是最具有潜力的储氢材料之一。氨硼烷在常温下不易放氢,金属催化剂可显著提高水解放氢速度,是影响氨硼烷水解放氢的关键因素,然而金属催化剂纳米颗粒易氧化、易团聚,使用载体可使催化剂金属纳米颗粒分散于载体表面或孔道内部,防止氧化和团聚。催化剂及其载体的整体形貌很大程度决定了催化剂的比表面积、催化剂活性颗粒分布状态,从而影响了反应活性位点的数量及分布状态,对氨硼烷水解催化活性和催化剂的使用寿命具有重要影响,因此本文对氨硼烷水解催化剂及其限域载体的整体形貌按空间维度进行分类归纳,并对其可控合成方法和其对氨硼烷水解催化效果进行综述。

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关键词: 氨硼烷水解催化剂形貌载体

Abstract: Ammonia borane (AB) has been considered as one of the most promising hydrogen storage materials due to its high hydrogen-storage content (19.6wt%) and stability under ordinary storage conditions. Catalyst is the core technology which can significantly increase the rate of dehydroge-nation of AB as ammonia borane is not easy to release hydrogen at room temperature without catalysts. However, metal catalyst particles are generally easy to be oxidized and agglomerate. In order to overcome this problem, a variety of supports have been chosen to disperse the catalyst on their surface or in their poresto suppress the agglomeration and oxidation. The overall morphology of the catalysts and their support greatly determines the specific surface area of the catalyst and distribution of catalyst active particles, thereby affecting the number and distribution of reactive sites, and has a significant impact on the catalytic activity and the service life of the catalyst. Therefore, this article has classified the overall morphology of catalyst and their support for hydrogen generation of ammonia borane and their support according to spatial dimensions, and haavesummarized their controllable synthesis methods and their catalytic effects on hydrogen generation of ammonia borane.

Key words: ammonia borane dehydrogenation catalyst morphology support

出版日期: 2022-11-25 发布日期: 2022-11-25

ZTFLH:

O643

基金资助: 河南省教育厅高等学校重点科研项目(21A150018)

通讯作者: * j-zhang@126.com

作者简介: 李想,2012年毕业于中南大学材料科学与工程专业,2012至2017年于中国科学院成都有机化学研究所进行硕博连读,并于2017年取得应用化学博士学位,现为河南科技大学讲师,主要从事锂离子电池正极材料的制备及改性。2019年至今在河南科技大学任教,主要研究方向为氨硼烷水解释氢催化剂的制备及改性研究。迄今发表锂离子电池高镍正极材料相关学术论文10余篇、储氢材料及其催化剂相关学术论文5篇。
张军,1984年于河南师范大学取得化学学士学位,1987年于中科院盐湖所取得无机化学硕士学位,2004年于兰州大学取得无机化学博士学位,2006年赴日本横滨国立大学做访问学者。现为河南科技大学教授、博士研究生导师。主要研究方向为氨硼烷水解释氢催化剂的合成与催化机理研究、氨硼烷的电化学法制备等。迄今发表储氢材料及其催化剂相关学术论文10余篇。

引用本文:

李想, 张军. 氨硼烷水解制氢催化剂及其限域载体的形貌可控合成研究进展[J]. 材料导报, 2022, 36(22): 20100246-9.
LI Xiang, ZHANG Jun. Research Progress of Shape-controlled Synthesis of Catalysts and Domain Limited Supports for Ammonia Borane Dehydrogenation. Materials Reports, 2022, 36(22): 20100246-9.

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http://www.mater-rep.com/CN/10.11896/cldb.20100246 或 http://www.mater-rep.com/CN/Y2022/V36/I22/20100246

1 Shore S G, Parry R W. Journal of the American Chemical Society, 1955, 77, 6084.
2 Xu W Q, Li Q Q, Huang M J. International Journal of Hydrogen Energy, 2015, 40, 16578.
3 Zou S S, Tao Z L, Chen J. Acta Chimica Sinica, 2011, 69(18), 2117(in Chinese).
邹少爽,陶占良,陈军,化学学报,2011,69(18),2117.
4 Murty B S, Shankar P, Raj B, et al. Textbook of Nanoscience and Nanotechnology, Universities Press, India, 2014.
5 Alpaydın C Y, Gülbay S K, Colpan C O.International Journal of Hydrogen Energy, 2020, 45, 3414.
6 Gong L H, Ye C, An M Z. Chinese Journal of Applied Chemistry, 2011, 28(2), 164(in Chinese).
宫丽红, 叶彩, 安茂忠,应用化学, 2011, 28(2),164.
7 Davis B L, Dixon D A, Garner E B, et al.Angewandte Chemie International, 2009, 48, 6812.
8 Filiz B C, Figen A K. International Journal of Hydrogen Energy, 2016, 41, 15433.
9 Barakat N A M.Applied Catalysis A-General, 2013, 451, 21.
10 Barakat N A M.Materials Letters, 2013, 106, 229.
11 Tong Y, Lu X F, Sun W N, et al.Journal of Power Sources, 2014, 261, 221.
12 Korkut S E, Küçükkeçeci H, Metin O.ACS Applied Material & Interfaces, 2020, 12, 8130.
13 Xu P, Lu W, Zhang J, et al.ACS Sustainable Chemistry & Engineering, 2020, 8, 12366.
14 Akbayrak S, Özkar S.Dalton Transactions, 2014, 43, 1797.
15 Akbayrak S, Tanyıldızı S, Morkan I, et al.International Journal of Hydrogen Energy, 2014, 39, 9628.
16 Deka J R, Saikia D, Hsia K S, et al.Catalysts, 2020, 10, 1.
17 Yousef A, El-Halwany M M, Barakat N A M, et al.Ceramics Internatio-nal, 2015, 41, 6137.
18 Yousef A, Barakat N A M, Kim H Y.Applied Catalysis A-General, 2013, 467, 98.
19 Al-Enizi A M, Brooks R M, Ahmad M M, et al.Journal of Nanoscience and Nanotechnology, 2018, 18, 4714.
20 Wang C, Sun D, Yu X, et al.Inorganic Chemistry Frontiers, 2018, 5, 2038.
21 Wang C, Yu X, Zhang X, et al.Journal of Alloys and Compounds, 2020, 815, 152431.
22 Hu M, Wang H, Wang Y, et al.International Journal of Hydrogen Energy, 2017, 42, 24142.
23 Ma Y, Li X, Zhang Y, et al.Journal of Alloys and Compounds, 2017, 708, 270.
24 Fang Y B, Yan X H, Sun J Q.Chemial Industry and Engineering Progress, 2004, 23(12), 1296(in Chinese).
房永彬,严新焕,孙军庆. 化工进展,2004, 23(12), 1296.
25 Zhang J K, Chen C Q, Chen S, et al.Catalysis Science & Technology, 2016, 7, 322.
26 Wang Q T, Zhang Z, Liu J, et al.Materials Chemistry and Physics, 2018, 204, 58.
27 Arthur E E, Li F, Momade F W Y, et al.Energy, 2014, 76, 822.
28 Wu Z, Duan Y, Ge S, et al.Catalysis Communications, 2017, 91, 10.
29 Yang C, Gao F Y, Tang X L, et al. Materials Reports A:Review Papers, 2020, 34(7), 13005(in Chinese).
杨晨, 高凤雨, 唐晓龙, 等. 材料导报:综述篇,2020,34(7),13005.
30 Tang Z, Chen H, Chen X, et al.Journal of the American Chemical Society, 2012, 134, 5464.
31 Sun W, Lu X, Tong Y, et al.International Journal of Hydrogen Energy, 2014, 39, 9080.
32 Feng K, Zhong J, Zhao B H, et al.Angewandte Chemie International, 2016, 55, 11950.
33 Qiu F, Li L, Liu G, et al.International Journal of Hydrogen Energy, 2013, 38, 7291.
34 Cao N, Luo W, Cheng G.International Journal of Hydrogen Energy, 2013, 38, 11964.
35 Çiftci N S, Metin Ö.International Journal of Hydrogen Energy, 2014, 39, 18863.
36 Yu C, Guo X F, Shen M Q, et al.Angewandte Chemie International, 2018, 57, 451.
37 Zheng W, Sun Z M, Zhang P G, et al. Materials Reports, 2017, 31(9),1(in Chinese).
郑伟, 孙正明, 张培根, 等. 材料导报,2017, 31(9), 1.
38 Guo Z W, Liu T, Wang Q T, et al.RSC Advances, 2018, 8, 843.
39 Cheng S H, Liu Y C, Zhao Y N, et al. Dalton Transactions, 2019, 48, 17499.
40 Wu Y W, Wu X, Liu Q W, et al.International Journal of Hydrogen Energy, 2017, 42, 16003.
41 Liu Q B, Zhang S J, Liao J Y, et al.Catalysis Science & Technology, 2017, 7, 3573.
42 Zhang L X.Application technology of core-shell structure micro-nanomate-rials, National Defense Industry Press, 2010, pp.1(in Chinese).
张立新. 核壳结构微纳米材料应用技术(第一版), 国防工业出版社,2010, pp.1.
43 Yan J M, Zhang X B, Akita T. Journal of the American Chemical SocietyCommunications, 2010, 132, 5326.
44 Yang L, Su J, Meng X Y, et al. Journal of Materials Chemistry A, 2013, 1, 10016.
45 Cao N, Su J, Luo W, et al.Catalysis Communications, 2014, 43, 27.
46 Qiu F Y, Liu G, Li L, et al. Chemistry, 2014, 20, 505.
47 Qiu F Y, Dai Y L, Li L, et al. International Journal of Hydrogen Energy, 2014, 39, 436.
48 Xu P, Lu W W, Zhang J J, et al.ACS Sustainable Chemistry & Enginee-ring, 2020, 8, 12366.
49 Yao Q L, Lu Z H, Zhang Z J, et al.Scientific Reports, 2014, 4, 7597.
50 Xu D, Wang W D, Tian M, et al.Journal of Colloid and Interface Science, 2018, 516, 407.
51 Cheng F Y, Ma H, Li Y M. Chen J.Inorganic Chemistry, 2007, 46, 788.
52 Umegaki T, Takei C, Xu Q, et al. International Journal of Hydrogen Energy, 2013, 38, 1397.
53 Toyama N, Umegake T, Kojima Y.International Journal of Hydrogen Energy, 2014, 39, 17136.
54 Umegaki T, Watanabe K, Ogawa H, et al.International Journal of Hydrogen Energy, 2020, 45, 19531.
55 Zhang J, Dong Y N, Liu Q X, et al.International Journal of Hydrogen Energy, 2019, 44, 30226.
56 Yang L, Cao N, Du C, et al.Materials Letters, 2014, 115, 113.
57 Yang Y, Lu Z H, Hu Y, et al.RSC Advances, 2014, 4, 13749.
58 Güngörmez K, Metin Ö.Applied Catalysis A-General, 2015, 494, 22.
59 Du X, Yang C, Zeng X, et al.International Journal of Hydrogen Energy, 2017, 42, 14181.
60 Kalidindi S B, Sanyal U, Jagirdar B R.Physical Chemistry Chemical Physics, 2008, 10, 5870.

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