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材料导报  2022, Vol. 36 Issue (13): 20100242-8    https://doi.org/10.11896/cldb.20100242
  高分子与聚合物基复合材料 |
金属-有机杂化材料用于有机磷毒剂检测与洗消的研究进展
梁妃攀1,†, 吴思1,†, 夏宇正1, 石淑先1,*, 聂志勇2,*
1 北京化工大学材料科学与工程学院,北京 100029
2 军事医学研究院毒物药物研究所,北京 100850
Research Progress of Metal-Organic Hybrid Materials for Detection and Decontamination of Organophosphate Agents
LIANG Feipan1,†, WU Si1,†, XIA Yuzheng1, SHI Shuxian1,*, NIE Zhiyong2,*
1 College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
2 Institute of Pharmacology and Toxicology, Academy of Military Medical Sciences, Beijing 100850, China
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摘要 神经性毒剂和大部分有机磷酸酯农药均属于有机磷毒剂,可抑制人体内乙酰胆碱酯酶活性,导致过量乙酰胆碱在体内的积累,从而引发一系列健康问题甚至死亡。传统大型仪器对有机磷毒剂的检测准确度高,但检测周期长、样品处理复杂且需要专业仪器和技术人员。如何进行快捷检测、鉴定并及时对有机磷毒剂进行洗消,对中毒的提早防治和生命的挽救具有重要的现实意义。本文总结了基于贵金属纳米粒子与有机化合物的复合以及金属有机框架材料这两种金属-有机杂化材料对有机磷毒剂的检测与洗消,综述了可在短时间内直接通过颜色变化或荧光变化对有机磷毒剂进行快捷检测的比色法和荧光法的研究进展,总结了利用金属有机框架材料实现对有机磷毒剂检测与吸附降解的效果,并对未来的发展进行了展望。
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梁妃攀
吴思
夏宇正
石淑先
聂志勇
关键词:  神经性毒剂  有机磷酸酯农药  金属有机杂化材料  检测  洗消    
Abstract: Nerve agents and most organophosphate pesticides belong to organophosphate agent, which can inhibit acetylcholinesterase activity in the human body, leading to the accumulation of excessive acetylcholine in the body, causing a series of health problems and even death. Although the detection of organophosphorus agent by traditional large-scale instruments has high accuracy, the detection should spend more time, sample processing is complicated, and professional instruments and technical personnel are required. How to quickly detect, identify and decontaminate organophosphorus agent in a timely manner has important practical significance for the early prevention and treatment of poisoning, even saving lives. This paper summarizes the detection and decontamination of organophosphorus agents by two metal-organic hybrid materials based on the compounds of precious metal nanoparticles and organic chemicals, metal-organic framework materials. The progress of fluorescence and colorimetric methods used to detect organophosphorus agents directly by color or fluorescence change quickly in a short time. The effect of adsorption and degradation of organophosphorus poisons caused by metal-organic framework materials, and the prospect of future development in this field are introduced.
Key words:  nerve agents    organophosphorus pesticides    metal-organic hybrid materials    detection    decontamination
出版日期:  2022-07-10      发布日期:  2022-07-12
ZTFLH:  TB33  
基金资助: 军内科研项目
通讯作者:  * shisx@mail.buct.edu.cn;niezhiyong2008@163.com   
作者简介:  梁妃攀,北京化工大学硕士研究生,2019年毕业于北京化工大学,获工学学士学位。目前主要研究方向为金属有机框架材料对有机磷毒剂的检测与洗消。
吴思,北京化工大学硕士研究生,2018年起于北京化工大学材料科学与工程学院攻读硕士学位,目前主要研究方向为金属纳米材料-聚合物复合材料及其在催化方向的应用。
石淑先,北京化工大学材料科学与工程学院副教授、硕士研究生导师。先后于1995年、2000年和2007年分别于北京化工大学获得学士、硕士和博士学位。先后承担或参与多项国家部委及企事业项目。迄今发表文章百余篇,主编/参编多部专业书籍。目前主要研究方向是功能涂层/表面、刺激响应型高分子材料、聚合物杂化材料的制备及应用。
聂志勇,副研究员,于2011年在军事医学科学院获药物分析学博士学位。近年来在Food Chemistry、Talanta、《中国科学》等国内外期刊发表论文30余篇,参与专著及教材编写多部,获科技奖2项,因抗震救灾、应急救援等荣立个人三等功共3次。目前主要从事毒剂毒物检测鉴定、吸入毒理分析及中毒对抗措施研究。
†共同第一作者
引用本文:    
梁妃攀, 吴思, 夏宇正, 石淑先, 聂志勇. 金属-有机杂化材料用于有机磷毒剂检测与洗消的研究进展[J]. 材料导报, 2022, 36(13): 20100242-8.
LIANG Feipan, WU Si, XIA Yuzheng, SHI Shuxian, NIE Zhiyong. Research Progress of Metal-Organic Hybrid Materials for Detection and Decontamination of Organophosphate Agents. Materials Reports, 2022, 36(13): 20100242-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20100242  或          http://www.mater-rep.com/CN/Y2022/V36/I13/20100242
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