块体非晶合金的低温性能研究进展

doi:10.11896/cldb.20100255

材料导报

2022, Vol. 36

Issue (13): 20100255-8 https://doi.org/10.11896/cldb.20100255

金属与金属基复合材料

块体非晶合金的低温性能研究进展

王顺平^1,2, 李春燕^1,2,*, 李金玲², 王海博², 寇生中^1,2

1 兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050
2 兰州理工大学材料科学与工程学院,兰州 730050

Research Progress on Cryogenic Temperature Properties of Bulk Amorphous Alloys

WANG Shunping^1,2, LI Chunyan^1,2,*, LI Jinling², WANG Haibo², KOU Shengzhong^1,2

1 State Key Laboratory of Advanced Processing and Reuse of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
2 School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China

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摘要非晶合金的结构与性能在极端条件下会发生大的改变,且其变形机理目前尚不统一。为了明确低温极端条件对块体非晶合金力学性能的影响机制,本文综述了块体非晶合金在低温条件下微观形貌、力学性能的变化。主要阐述了低温对其拉伸与压缩力学性能的影响,列举了块体非晶合金在低温下具有高屈服强度等优异的力学性能,如低温下块体非晶合金的屈服强度可达2 217 MPa。此外,还评述了块体非晶合金在不同低温条件下电性能和磁性能的变化,发现块体非晶合金在磁制冷方面也有突出的表现,比如Co₄₅Er₅₅和Co₃₅Er₆₅两种块体非晶合金从铁磁到顺磁的转变温度分别为26 K和15 K。根据热力学麦克斯韦关系可确定块体非晶合金的磁熵变值,当Er元素浓度增加时,磁熵变值会减小。在5 T的磁场下,Co₄₅Er₅₅和Co₃₅Er₆₅的磁熵变峰值分别约为10.8 J·kg^-1·K^-1和9.8 J·kg^-1·K^-1,这说明Co₃₅Er₆₅合金更有望成为磁制冷的候选材料。本文对进一步理解块体非晶合金低温下微观形貌与力学性能的关联具有重要意义,为块体非晶合金在极端低温条件下的应用提供了理论基础,对推动块体非晶合金这一新型材料的工程化应用有重要的理论和实际意义。

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	王顺平
	李春燕
	李金玲
	王海博
	寇生中

关键词: 非晶合金低温微观形貌力学性能

Abstract: The structure and properties of amorphous alloys undergo significant changes under extreme conditions, and the deformation mechanism is not uniform. This paper reviews the changes in the microscopic morphology and mechanical properties of bulk amorphous alloys at extreme cryogenic conditions to clarify the thermal effects on the mechanical properties of amorphous alloys. It mainly elaborates the influence of cryogenic temperature on tensile and compressive mechanical properties for bulk amorphous alloys and lists the excellent mechanical properties of bulk amorphous alloys at cryogenic temperatures, such as a high yield strength of 2 217 MPa. In addition, the electrical and magnetic properties of bulk amorphous alloys under different cryogenic temperature conditions are also reviewed, and it is found that bulk amorphous alloys also have outstanding performance in magnetic refrigeration. For example, the transition temperatures from ferromagnetic to paramagnetic for Co₄₅Er₅₅ and Co₃₅Er₆₅ are 26 K and 15 K, respectively. The change in magnetic entropy is determined according to the thermodynamic Maxwell relationship. With an increase in Er concentration, the magnetic entropy change value also decreases. Under a magnetic field of 5 T, the magnetic entropy change peaks of Co₄₅Er₅₅and Co₃₅Er₆₅ are about 10.8 J·kg^-1·K^-1and 9.8 J·kg^-1·K^-1, respectively, indicating that the Co₃₅Er₆₅ alloy is more likely to be a candidate for magnetic refrigeration. The discussion in this paper is of great significance in further understanding the relationship between microscopic morphology and mechanical properties of amorphous alloys at cryogenic temperatures, and provides a theoretical basis for the application of bulk amorphous alloys under extreme cryogenic temperature conditions, which shows important theoretical and practical significance for engineering applications of bulk amorphous alloys as new materials as well.

Key words: amorphous alloys cryogenic temperature micromorphology mechanical properties

出版日期: 2022-07-10 发布日期: 2022-07-12

ZTFLH:

TG139

基金资助: 国家自然科学基金(51861021;51661016);兰州理工大学红柳一级学科建设计划资助

通讯作者: * licywz@163.com

作者简介: 王顺平,2018年6月毕业于北华大学,获得材料物理专业学士学位。现为兰州理工大学硕士研究生,在李春燕教授的指导下进行研究。目前主要研究领域为Zr基块体非晶合金。
李春燕,兰州理工大学材料学院教授、硕士研究生导师。2006年获得兰州理工大学材料学专业硕士学位并留校任教,2013年获得兰州理工大学材料加工工程专业博士学位。2019年获得“西部地区人才培养特别项目”出国访学资助。中国材料研究学会高级会员,甘肃省材料学会会员,《精密成形工程》期刊编委。Applied Surface Science、Rare Metals、Journal of Non-Crystalline Solids、Physics B等国际权威期刊审稿人。长期从事非晶合金、高熵合金等相关领域的研究。近年来,在非晶合金和高熵合金领域发表论文50余篇,包括Intermetallics、Journal of Materials Science、Journal of Non-Crystalline Solids、Surface Engineering、Progress in Nature Science等。申请国家发明专利10项。

引用本文:

王顺平, 李春燕, 李金玲, 王海博, 寇生中. 块体非晶合金的低温性能研究进展[J]. 材料导报, 2022, 36(13): 20100255-8.
WANG Shunping, LI Chunyan, LI Jinling, WANG Haibo, KOU Shengzhong. Research Progress on Cryogenic Temperature Properties of Bulk Amorphous Alloys. Materials Reports, 2022, 36(13): 20100255-8.

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http://www.mater-rep.com/CN/10.11896/cldb.20100255 或 http://www.mater-rep.com/CN/Y2022/V36/I13/20100255

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