Abstract: Mesoporous silica nano-materials (MSNs) have been widely used in various fields, e.g., adsorption, catalysis, and biomedicine, due to their large specific surface area as well as stable physical and chemical properties. In recent years, relevant niches of the academia have been committing themselves to regulating and controlling the morphology and structure of MSNs (particle size, particle shape, channel structure, and readily-functionalized surface), because the fineness of the material's structure has a significant impact on its physical and chemical properties, which will in turn translates to its performance and application. Pure silica materials, however, have their application scopes limited due to their lack of specificity. In this sense, how to improve their specificity and open up more fields of application have become popular research topics. Compared with the conventional two-dimensional mesoporous silica materials, dendritic fibrous nano-silica (DFNS) has a more open and more permeable dendritic pore structure. The modifiable surface and special radial channel structure of the dendritic fibrous nano-silica can combine the excellent physical and chemical properties of the silica nano-material with the modified functional specificity arising from the actual need. This signifies a qualitative leap in the application prospect of the MSNs, allowing more and more applications to gradually emerge across various fields. This paper concludes and reviews the synthesis and morphological regulation of DFNS based on the work of the research team. Furthermore, the applications of functional materials prepared by coating magnetic core-shell structures, grafting functional groups and chemical monomers, or with the use of supported metals or metallic oxides in adsorption, catalysis, biomedicine, chromatographic stationary phase, gas capture and other fields have also been summarized.
1 Stober W, Fink A, Bohn E. Journal of Colloid & Interface Science, 1968, 26(1),62. 2 Kresge C T, Leonowicz M E, Rrth W J, et al. Nature, 1992, 359(6397),710. 3 Xiaotian G, Sibo W, Biao Y, et al. Journal of Colloid and Interface Science, 2020, 561, 801. 4 Ling J, Huan P. Chinese Chemical Letters, 2020, 31(9), 300. 5 Zhao D Y, Feng J L, Huo Q S, et al. Science, 1998, 279(5350), 548. 6 Polshettiwar V, Cha D, Zhang X, et al. Angewandte Chemie Internatio-nal Edition, 2010, 49(50), 9652. 7 Maity A,Das A, Sen D, et al. Langmuir, 2017, 33(48), 3774. 8 Du X, Qiao S Z. Small, 2015, 11(4), 392. 9 Maity A, Polshettiwar V. Chemsuschem, 2017, 10(20), 75. 10 Wang Y B, Du X, Shi S H, et al. Journal of Materials Chemistry A,2019,7, 5111. 11 Wang Y B, Liu Z, Shi S H, et al. Journal of Inorganic Materials, 2018,33(12), 18 (in Chinese) 王亚斌, 刘忠, 史时辉,等.无机材料学报, 2018, 33(12), 18. 12 Yang H, Huang C, Liao S J. Progress in Chemical Industry, 2014, 33(8), 2089 (in Chinese) 杨惠, 黄超, 廖世军.化工进展, 2014, 33(8), 2089. 13 Bayal N, Singh B, Singh R, et al. Scientific Reports, 2016, 6, 24888. 14 Febriyanti E, Suendo V, Mukti R R, et al. Langmuir, 2016, 32(23), 5802. 15 Wang Y, Hu K, He J, et al. RSC Advances, 2019, 9(43), 24783. 16 Yu K J, Zhang X B,Tong H W, et al. Materials Letters,2013,106(9), 151. 17 Zhang W, Li S, Zhang J, et al. Microporous and Mesoporous Materials, 2019, 282, 15. 18 Ali Z, Tian L, Zhang B, et al. New Journal of Chemistry, 2017, 41(16), 8222. 19 Hassankhani A, Sadeghzades M, Zhiant R. RSC Advances, 2018, 8(16), 8761. 20 Maryam M, Nasrin S, Fateman A M H. Journal of Electroanalytical Che-mistry, 2019, 848, 113272. 21 Chen P P, Qiao X Y, Liu J H, et al. Sensors & Actuators B Chemical, 2018, 267, 525. 22 Qu Q. Analytical Chemistry, 2015, 87(19), 9631. 23 Qu Q, Si Y, Xuan H, et al. Journal of Chromatography A, 2018,1540, 31. 24 Tian H J, Xue Y, Chen Q M, et al. Chromatography, 2017, 35(5), 473 (in Chinese) 田华君, 薛芸, 陈巧梅,等.色谱, 2017, 35(5), 473. 25 Wang H, Suo J Q, Wang C Y, et al. Journal of Advanced Chemistry, 2020, 41(8), 1731 (in Chinese) 王欢, 所金泉, 王春艳,等.高等学校化学学报, 2020, 41(8), 1731. 26 Hamid M, Muhamed Y, Triwahyono S, et al. Inorganic Chemistry, 2018, 57(10), 5859. 27 Singh R, Belgamwar R, Dhiman M,et al. Journal of Materials Chemistry: B, 2018, 6(11), 1600. 28 Hang L G, Zheng Y Y. Materials Engineering,2018, 46(10), 135 (in Chinese) 黄连根,郑玉婴.材料工程, 2018, 46(10), 135. 29 Tian Y, Yan L, Sun Z, et al. RSC Advances, 2015, 5, 106068. 30 Hasan R, Bukhari S N, Jusoh R, et al. Materials Today: Proceedings, 2018,5(10), 21574. 31 Kushwaha A K, Guptan N. Arabian Journal of Chemistry, 2017, 10(S1), S81. 32 Heidari A, Younesi H, Mehraban Z. The Chemical Engineering Journal, 2009, 153(1-3), 70. 33 Soltani R D C, Khorramabadi G S, Khataee A R, et al. Journal of the Taiwan Institute of Chemical Engineers, 2014, 45(3), 973. 34 Guo Y, Liu D, Zhao Y, et al. Journal of the Taiwan Institute of Chemical Engineers, 2017, 71, 537. 35 Ge L, Wang B D, Sun Q, et al. Microporous & Mesoporous Materials, 2017, 252, 105. 36 Zarei F, Marjani A, Soltani R. European Polymer Journal, 2019, 119, 400. 37 Roozbeh S, Azam M, Mina H, et al. Chemosphere, 2020, 239, 124735. 38 Lee Y R, Zhang S, Yu K, et al. Chemical Engineering Journal, 2019, 378, 122. 39 Yang P, Liu Q, Liu J, et al. Journal of Hazardous Materials, 2018, 363, 248. 40 Roozbeh S, Azam M, Mohamad R S M, et al. Journal of Molecular Liquids, 2019, 294, 111617. 41 Huang W Y, Yu X, Tang J P, et al. Microporous and Mesoporous Mate-rials, 2015, 217, 225. 42 Dong Z, Le X, Li X, et al. Applied Catalysis B Environmental, 2014, 158, 129. 43 Guo J H,Liu Y C,Ma H, et al. Catalysis Letters, 2020, 150(7), 2003. 44 Zahar M, Alireza N C. Renewable Energy, 2020, 147, 2229. 45 Zahar M, Alireza N C. Chemical Engineering Journal, 2019, 361, 450. 46 Zhang S, Qian Y, Ahn W S. Chinese Journal of Catalysis, 2019, 40, 1704. 47 Javaid S, Swati R, Manisha S,et al. RSC Advances, 2020, 10(14), 8140. 48 Singh B, Polshettiwar V. Journal of Materials Chemistry A, 2016, 4(18), 7071. 49 Li S, Jiang X, Sun H, et al. Journal of Membrane Science, 2019, 586, 185. 50 Huang X, Tao Z, Praskavich J C, et al. Langmuir, 2014, 30(36), 10886. 51 Follmann H D M, Oliveira O N, Martins A C, et al. Journal of Colloid and Interface Science, 2020, 567, 92. 52 Cha B G, Jeong J H, Kim J. ACS Central Science, 2018, 4(4), 484. 53 Soleymani J, Hasanzadeh M, Shadjou N, et al. Journal of Pharmaceutical and Biomedical Analysis, 2020, 180, 113077. 54 Abbasay L, Mohammadzadeh A, Hasanzadeh M, et al. International Journal of Biological Macromolecules, 2020, 154, 584.
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2022, Vol. 36 
