Advances in Experimental Research on Irradiation Damage of High-entropy Alloys
JIN Ke1,2, LU Chenyang3, DOU Yankun4, HE Xinfu4, YANG Wen4
1 School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China 2 Advance Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China 3 School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an 710049, China 4 Reactor Engineering Technology Research Division, China Institute of Atomic Energy, Beijing 102413, China
Abstract: Long before the proposal of the concept of high-entropy alloy, researchers have observed the strong dependence of ion irradiation induced swelling on the concentration of principal elements in the Fe-Cr-Ni alloy system in 1970s. Nonetheless, the underlying physics of such dependence was not systematically investigated, and principal elements were rarely targeted in design of irradiation resistant alloys, until the recent development of high-entropy alloys. This new family of alloys greatly expands the compositional space for alloy design, and provides an ideal playground of studying the impact of principal alloy elements on the irradiation response. In the recent years, significant experimental effort has been made to understand the impact of number, type, and concentration of alloying elements on the irradiation (by ions, electrons, and neutrons) induced microstructural evolution and property degradation. The up-to-date results have revealed that, defect evolution process is retarded in the alloys with high chemical complexity, through tuning the energy dissipation and the defect formation and migration energies. For example, the size of interstitial clusters is reduced, and the formation and growth of voids and helium bubbles are suppressed. It has been evidenced that proper modification of principal elements can indeed improve the irradiation resistance of alloys, however, considerable discrepancies have also been observed regarding the irradiation-induced phase instability, swelling, and hardening for different alloy systems and irradiation conditions. Therefore, a conclusive evaluation cannot be made on whether the irradiation resistance of high-entropy alloys is overall superior. We review the major progress in experimental studies on irradiation effects of high-entropy alloys, and summarize the current understanding and evaluation of the irradiation resistance. The limitations or contradictions of experimental results are discussed, and perspectives are provided for the future studies in this field.
作者简介: 靳柯,北京理工大学教授、博士研究生导师。2010年本科毕业于北京大学物理学院,2011年硕士毕业于美国佛罗里达大学材料科学与工程系,2015年博士毕业于美国田纳西大学材料科学与工程系。2015—2018年于美国橡树岭国家实验室进行博士后研究工作。2018年6月回国后,入选国家“海外高层次人才引进计划”青年项目。主要从事离子与固体相互作用、材料辐照损伤和新型抗辐照材料研发、离子束技术等方面的研究工作。近年来在Acta Mater., J. Nucl. Mater., Nat. Commun.等期刊上发表论文50余篇,其中一作/通讯17篇。 卢晨阳,西安交通大学核科学与技术学院教授、博士研究生导师,入选国家“海外高层次人才引进计划“青年项目。2014年毕业于东北大学获材料学博士学位,2014—2018年在密西根大学核工程与放射科学系先后从事博士后和助理研究员工作,于2018年底全职加入西安交通大学。主要研究方向包括先进核结构材料制备、材料中的辐照损伤,以及材料微观结构的先进表征手段等。共发表SCI论文40余篇,其中包括4篇Nature Communications,4篇Acta Materialia,11篇Journal of Nuclear Materials及其他多篇具有领域影响力的相关论文,文章总引用1 400余次,H因子19。2013年在电子显微镜和电子显微分析国际大会上获得美国显微镜学会颁发的总统学者奖。 贺新福,中国原子能科学研究院副研究员。首届中核集团“青年科技英才”,《核科学与工程》编委。主要从事反应堆材料辐照效应多尺度模拟及高性能计算技术研究。近5年作为项目负责人主持863课题1项、重点研发计划课题1项、核技术创新联合基金重点项目1项、国家财政部稳定基础科研课题1项、中核集团“菁英项目”和“领创项目”各1项。发表论文30余篇,获软件著作权4项,发明专利2项,申请专利4项;国防科学技术三等奖1项,中核集团科学技术奖二等奖1项,中国原子能科学研究院科技成果奖一等奖3项。
引用本文:
靳柯, 卢晨阳, 豆艳坤, 贺新福, 杨文. 高熵合金辐照损伤的实验研究进展[J]. 材料导报, 2020, 34(17): 17018-17030.
JIN Ke, LU Chenyang, DOU Yankun, HE Xinfu, YANG Wen. Advances in Experimental Research on Irradiation Damage of High-entropy Alloys. Materials Reports, 2020, 34(17): 17018-17030.
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