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材料导报  2020, Vol. 34 Issue (20): 20086-20090    https://doi.org/10.11896/cldb.19100059
  金属与金属基复合材料 |
Ti2AlC陶瓷弥散增强Al基复合材料的制备及剪切性能
张强1, 蔡璋文1, 董兰静1, 柏跃磊2, 朱春城1
1 哈尔滨师范大学化学化工学院,光电带隙材料省部共建教育部重点实验室,哈尔滨 150025
2 哈尔滨工业大学特种环境复合材料技术国防科技重点实验室,哈尔滨 150001
Preparation and Shear Properties of Ti2AlC Ceramic Dispersion Reinforced Al Matrix Materials
ZHANG Qiang1, CAI Zhangwen1, DONG Lanjing1, BAI Yuelei2, ZHU Chuncheng1
1 Kay Laboratory for Electronic Bandgap Materials, Ministry of Education, College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China
2 National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin 150001, China
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摘要 采用自蔓延高温合成法制备高纯Ti2AlC粉体材料,以CuSO4·5H2O为Cu源在Ti2AlC粉体表面进行化学镀,并将镀铜后的陶瓷颗粒与Al粉进行混合,采用热压烧结法制备了Ti2AlC陶瓷弥散增强Al基材料。结果表明,Ti2AlC具有自催化效应,无需进行任何表面预处理,即可得到均匀稳定的纳米Cu镀层,增强相颗粒对金属基体起到了有效的钉扎作用;制备的Cu包覆Ti2AlC陶瓷弥散增强Al基材料主相为Al、Ti2AlC、Al2Cu。Al2Cu的存在可以很好地桥连Al基体与Ti2AlC陶瓷颗粒,引入Cu镀层后复合材料的抗剪切性能提高了65.7%。
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张强
蔡璋文
董兰静
柏跃磊
朱春城
关键词:  Ti2AlC  化学镀  热压烧结  Al基复合材料    
Abstract: High purity Ti2AlC powder was prepared by self-propagating high temperature method. The Cu coated Ti2AlC powder was synthesized by electroless plating method,and Cu source was provided by CuSO4·5H2O. After electroless plating copper, ceramic particles were mixed with Al powder.Ti2AlC ceramic reinforced Al matrix materials were fabricated by hot-pressing sintering.The results show that Ti2AlC has autocatalytic effect, uniform and stable nano Cu coating can be obtained without any surface pretreatment.The reinforcement phase plays an effective role in binding Al matrix. According to X-ray diffraction analysis, the main phases of Cu-coated Ti2AlC ceramic reinforced Al matrix materials were Al, Ti2AlC and Al2Cu.The Al2Cu can bridge Al matrix and Ti2AlC ceramic. After the Cu coating was introduced, the shear resistance of the compo-sites was improved by 65.7%.
Key words:  Ti2AlC    electroless plating    hot-pressing sintering    Al matrix materials
               出版日期:  2020-10-25      发布日期:  2020-11-06
ZTFLH:  TB331  
基金资助: 国家自然科学基金(51572064);国防基础科研计划项目(JCKYS2019603C005);黑龙江省自然科学基金重点项目(ZD2017011)
通讯作者:  zhuccshs@163.com   
作者简介:  张强,硕士研究生,主要从事陶瓷基以及金属基复合材料的制备研究。
朱春城,教授,硕士研究生导师,研究方向为陶瓷基复合材料,主持国家自然科学基金面上项目2项,主持多项省级科研项目,获得10余项国家授权发明专利,获得黑龙江省科技二等奖,发表50余篇科研论文。
引用本文:    
张强, 蔡璋文, 董兰静, 柏跃磊, 朱春城. Ti2AlC陶瓷弥散增强Al基复合材料的制备及剪切性能[J]. 材料导报, 2020, 34(20): 20086-20090.
ZHANG Qiang, CAI Zhangwen, DONG Lanjing, BAI Yuelei, ZHU Chuncheng. Preparation and Shear Properties of Ti2AlC Ceramic Dispersion Reinforced Al Matrix Materials. Materials Reports, 2020, 34(20): 20086-20090.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19100059  或          http://www.mater-rep.com/CN/Y2020/V34/I20/20086
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