Research Progress of Dendritic Fibrous Nano-spheres Catalysts
WANG Yabin1, GUO Min2,3, SHI Shihui1, HU Keke1, ZHANG Yaoxia1, LIU Zhong2,3
1 Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an 716000 2 Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008 3 Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Xining 810008
Abstract: Dendritic fibrous silica-based nanospheres (denoted as KCC-1, similar to naming rule of MCM-41) have been regarded as another milestone in the history of mesoporous materials since MCM-41 and SBA-15. Compared with conventional mesoporous silica materials, KCC-1 with three-dimensional (3D) center-radial channels and hierarchical pores feature unique structural characteristics, including more open pore nanochannels, more highly accessible internal spaces, larger pore volumes, etc. Diverse guest species (such as noble metal nano-particles or functional biological macromolecules) could be easily transported through the radial porous architectures, achieving their efficient loading or reacting with the chemically active sites on these nanochannels as promising scaffolds/platforms to construct novel nanocatalysts. A majority of investigations have demonstrated that KCC-1 are ideal alternatives over traditional mesoporous MCM-41 or SBA-15, owing to their inherent structure superiorities. The successful creation of KCC-1 has aroused a wave of research upon dendritic fibrous nanospheres and the derivative catalysts. Researchers made fruitful attempts to develop dendritic fibrous nanospheres with other bulk elements, and obtained a series of analogues such as titania, silica-titania hybrid, carbon, carbon-nitrogen hybrid, silica-aluminum hybrid, silica-aluminum-copper hybrid, etc. nanospheres with dendritic fibrous structure. On the other hand, as the research further progressed, nanocatalysts with novel structures (e.g. core-shell, hollow, yolk-shell, etc.) on the basis of the original dendritic fibrous porous structure were also constructed and found to have excellent catalytic performances in specific catalyst-support systems. Starting with bulk elements which were utilized to construct dendritic fibrous nanospheres with 3D center-radial channels plus hierarchical pores, this article will review the worldwide recent research progress of this type of nanocatalysts, mainly classifying them, as well as summarizing individual structural characteristics, catalytic objects and performances. Last but not the least, research ideas and development trends will be analyzed and outlooked.
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