利用双子表面活性剂辅助制备纳米材料和介孔材料的研究进展

doi:10.11896/cldb.18050316

材料导报

2019, Vol. 33

Issue (21): 3678-3685 https://doi.org/10.11896/cldb.18050316

高分子与聚合物基复合材料

利用双子表面活性剂辅助制备纳米材料和介孔材料的研究进展

鲍艳, 刘盼, 郭佳佳

陕西科技大学轻工科学与工程学院,西安 710021

Research Progress on the Preparation of Nanomaterials and MesoporousMaterials Using Gemini Surfactants

BAO Yan, LIU Pan, GUO Jiajia

College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an 710021

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 11183KB )
输出: BibTeX | EndNote (RIS)

摘要纳米材料的特殊结构决定了其具有大的比表面积、高的表面活性等特点,因而在力学、热学、光学、电磁学等方面都具有广泛的应用。以表面活性剂形成的胶束和乳液等为模板制备纳米材料是一种常见的方法,该方法可以大大降低溶剂的表面张力并改变体系的界面组成和结构,已经引起了研究者们的高度重视。有序介孔材料具有规则可调的纳米级孔道,可用作吸附剂、催化剂、催化剂载体或模板。以表面活性剂自组装形成的聚集体为模板合成有序介孔材料由于操作简单,且材料的孔道分布更为均一,因而成为了最常见的制备方法。但目前在纳米材料及介孔材料的制备中,普遍使用传统的单链表面活性剂作为模板剂,由于该种表面活性剂结构单一,因而以其为模板所生成的纳米材料及介孔材料暴露出形貌单一且结构不易调控等缺点。
双子表面活性剂由于具有特殊的胶束自组装行为、高的表面活性及分子结构中疏水链段与联结基组成可调等特点,可实现纳米材料更加良好的分散及制备具有独特形貌的纳米材料和介孔材料。根据国内外研究进展,本文从双子表面活性剂在溶液中形成的各种有序聚集体——胶束(反胶束)、囊泡及液晶等角度出发,综述了以其为模板或者微反应器制备纳米材料的研究进展,同时对以双子表面活性剂为稳定剂辅助制备纳米材料的研究进展进行了阐述,并总结了双子表面活性剂辅助制备介孔材料过程中其结构参数变化对介孔材料形貌的影响,最后对双子表面活性剂辅助制备纳米材料及介孔材料的前景进行了展望。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	鲍艳
	刘盼
	郭佳佳

关键词: 双子表面活性剂模板剂稳定剂纳米材料介孔材料

Abstract: The special structure of nanomaterials determines their large specific surface area and high surface activity. They are widely used in mecha-nics, thermals, optics and electromagnetism. It is a common method to prepare nanomaterials by using micelles and emulsions formed by surfactants as a template. This method can greatly reduce the surface tension of the solvent and change the interface composition and structure, which has attracted the researchers' attention. Ordered mesoporous materials have regularly adjustable nanoscale pores, so they can be used as adsorbents, catalysts, catalyst supports or templates. Using the aggregates self-assembled by surfactant molecules as template to synthesis the ordered mesoporous materials, the process is more simple and the channel distribution is more uniform. Therefore, this method become very po-pular. However, traditional single-chain surfactants are commonly used as template in the preparation of nanomaterials and mesoporous materials. The as-prepared nanomaterials and mesoporous materials have many defects, such as single appearance and difficulty in controlling structure, due to the single structure of traditional single-chain surfactants.
Gemini surfactants have special micellar self-assembly behavior, high surface activity and adjustablity of the composition of hydrophobic chain and spacer. Thus, the preparation of nanomaterial and mesoporous materials with good dispersion and unique morphologies can be realized using gemini surfactants as dispersing agent and template. In this paper, the preparation of nanomaterials using gemini surfactants as template or microreactor was reviewed, from the perspective of various ordered aggregates of gemini surfactants in the solution, such as micelles (reverse micelles), vesicles and liquid crystals. And the progress of the preparation of nanomaterials with gemini surfactants as stabilizers was overviewed. Then, the influence of structural parameters of gemini surfactants on the morphology of mesoporous materials was summarized. Finally, some perspectives on the future research of nanomaterials and mesoporous materials prepared by gemini surfactants were put forward.

Key words: gemini surfactant template stabilizer nanomaterials mesoporous materials

出版日期: 2019-11-10 发布日期: 2019-09-12

ZTFLH:

TQ314

基金资助: 国家自然科学基金(21878181);西安市科技计划项目(201805023YD1CG7(2))

作者简介: 鲍艳,陕西科技大学轻工科学与工程学院三级教授、博士研究生导师、研究生院副院长。2008年6月毕业于陕西科技大学,获皮革化学与工程工学博士学位,鲍艳教授为教育部新世纪优秀人才支持计划、陕西省“高层次人才特殊支持计划”青年拔尖人才入选者,获陕西省中青年科技创新领军人才、陕西省青年科技新星、陕西省青年科技奖等荣誉称号。主要从事有机/无机纳米复合功能化学品的研究及绿色皮革化学品的合成及与胶原纤维的作用等研究工作,近年来发表学术论文80余篇(其中被SCI收录30余篇)。

引用本文:

鲍艳, 刘盼, 郭佳佳. 利用双子表面活性剂辅助制备纳米材料和介孔材料的研究进展[J]. 材料导报, 2019, 33(21): 3678-3685.
BAO Yan, LIU Pan, GUO Jiajia. Research Progress on the Preparation of Nanomaterials and MesoporousMaterials Using Gemini Surfactants. Materials Reports, 2019, 33(21): 3678-3685.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.18050316 或 http://www.mater-rep.com/CN/Y2019/V33/I21/3678

1 Seybolt, Sheila E J.Schizophrenia Research, 2014, 160 (1-3),222.
2 Jr B M, Moronne M, Gin P, et al. Science, 2013, 281(5385),2013.
3 Maynar A D. Nature, 2011, 475 (7354),31.
4 Malgars V, Ji Q, Kamamchi Y, et al. Bulletin of the Chemical Society of Japan, 2015, 88(9),1171.
5 Hsueh H Y, Yao C T, Ho R M. Chemical Society Reviews, 2015, 44 (7),1974.
6 Zhao T, Xin L, Li Y, et al. Journal of Colloid & Interface Science, 2016, 490,436.
7 Zhang X, Li Y, Cai Y, et al. Science of Advanced Materials, 2017, 490, 436.
8 Zhai L, Zhang J, Li X K, et al.Journal of Inorganic Materials, 2016, 31(6),588.
9 Yu X J. Synthesis, characterization and formation mechanism of mesoporous molybdenum and tungsten oxides based on gemini surfactants.Ph.D. Thesis,Shandong University, China, 2009(in Chinese).
于小娟. 基于Gemini表面活性剂的介孔钼、钨氧化物材料的制备、表征及机理研究.博士学位论文,山东大学, 2009.
10 Nandiyanto A B D, Kim S G, Iskandar F, et al. Microporous & Mesoporous Materials, 2009, 120 (3),447.
11 Bao Yan, Guo Jiajia, Ma Jianzhong, et al. Journal of Industrial & Engineering Chemistry, 2017, 53,51.
12 Wang Xiaoqin, Tong Debin, Peng Yufeng,et al. Chongqing University of Technology (Natural Science),2019, 33(3),150(in Chinese).
汪晓琴,童德彬,彭玉凤,等.重庆理工大学学报(自然科学),2019, 33(3),150.
13 Cheng Fa, Wang Jun, Zhu Sen. Fine Chemicals, 2005,22 (4),261(in Chinese).
程发,王军,朱森.精细化工,2005,22(4),261.
14 Alargova R G, Kochijashky I I. Sierra M L, et al. Journal of Colloid and Interface Science, 2001, 235, 119.
15 Zhu Deyu, Cheng Fa, Chen Yu, et al.Colloids and Surfaces A: Physicochem Engeering Aspects, 2012, 397,1.
16 Peng Zhongli, Wu Qing, Cai Tao,et al.Colloids and Surfaces A: Physicochem and Engeering Aspects, 2009, 342,127.
17 Brown G H. CRC Critical Reviews in Solid State Sciences, 1970, 1(3), 303.
18 Bangham A D, Standdish M M, et al.Journal of Molecular Biology, 1965, 13,328.
19 Kaler E W, KamalakaraM A, Rodiguez B E, et al.Science, 1989, 245,4924.
20 Xu Jian, Han Xia, Zhou Lihui, et al. The Chinese Journal of Process Engineering, 2006, 6 (2),323(in Chinese).
徐建,韩霞,周丽绘,等.过程工程学报, 2006, 6(2),323.
21 Xu F, Hou H, Gao Z. Chemphyschem A European Journal of Chemical Physics & Physical Chemistry, 2014, 15 (18),3979.
22 Sau T K, Murphy C J.Journal of American Chemical Society, 2004, 126,8648.
23 Gomezgrana S, Hububert F, Testard F, et al. Langmuir the ACS Journal of Surfaces & Colloids, 2012, 28 (2),1453.
24 Alami E, Levy H, Zana R, et al. Langmuir, 1993, 9 (4),940.
25 Oda R, Hue I, Candau S J. ChemCommun, 1997, (21),2105.
26 Bakshi M S, Sharma P, Banipal T S. Materials Letters, 2007, 61 (28),5004.
27 Li M, Zhang C, Yang X L, et al.RSC Advances,2013, 3(37),16304.
28 Li Bing, Zhang Qi, Xia Yan, et al. Colloids and Surfaces A: Physicochem and Engeenring Aspects, 2015, 470,211.
29 Wang Guoyong, Li Xiang, Du Zhiping, et al. Journal of Molecular Li-quids, 2014, 197,197.
30 Lawrence M J.European Journal of Drug Metabolism & Pharmacokinetics, 1994, 19 (3),257.
31 Wang W, Han Y, Tian M, et al.ACS Applied Materials & Interfaces, 2013, 5 (12),5709.
32 Murawska M, Wiatr M, Nowakowski P, et al. Radiation Physics & Che-mistry, 2013, 93 (93),160.
33 Anne B G, Raoul Z A, Yeshayahu T. Journal of Physical Chemistry B, 2000, 104 (17),4005.
34 Beaun P V, Stupp S I. Materials Research Bulletin, 1999, 34 (3),463.
35 Chang W, Shen Y, Xie A, et al. Applied Surface Science, 2010, 256 (13),4292.
36 Bskshi M S, Possmayer F, Petersen N O. Journal of Physical Chemistry C, 2008, 112 (22),8259.
37 Song W W, Li N B, Luo H Q. Analytical Biochemistry, 2012, 422 (422),1.
38 Xu Jian, Zhou Lihui, Liu Honglai, et al. Journal of Experimental Nanoscience, 2006, 1 (1),103.
39 Liu D, Li M, Cheng M. Journal of Jiamusi University, 2005, 23(3), 451.
40 Xu J, Han X, Liu H, et al. Colloids & Surfaces A: Physicochemical and Engineering Aspects, 2006, 273 (1-3),179.
41 Weng B, Shepherd R, Chen J, et al. Journal of Materials Chemistry, 2010, 21(6),1918.
42 Chen Q, Sakamoto Y, Terasaki O, et al.Microporous & Mesoporous Materials, 2007, 105(1),24.
43 Chen L, Shang Y, Liu H, et al. Materials & Design, 2010, 31 (4),1661.
44 Liu Y, Yu L, Zhang S, et al.Colloids & Surfaces A: Physicochemical and Engineering Aspects, 2010, 359 (1-3),66.
45 Li D, Fang W, Wang H, et al.Industrial & Engineering Chemistry Research, 2013, 52 (24),8109.
46 Kuo C F J, Dong M Y.Journal of Surfactants and Detergents, 2012, 15 (4),471.
47 Fereidooni M T, Azizian S, Wetting S. Journal of Colloid & Interface Science, 2017, 486,204.
48 Negm N A, Mohamed D E, et al. Journal of Industrial & Engineering Chemistry, 2014, 24,34.
49 He S, Chen H, Guo Z, et al. Colloids & Surfaces A: Physicochemical and Engineering Aspects, 2013, 429 (10),98.
50 Siddiq A M, Parandhaman T, Begam A F, et al. Enzyme & Microbial Technology, 2016, 95,118.
51 Feng J, Wu S, Wang H, et al.Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2017,516, 94.
52 Huo Q S, Leon R, Petroff P M. et al.Science,1995, 268,13224.
53 Xu J, Han S, Hou W, et al. Colloids & Surfaces A: Physicochemical and Engineering Aspects, 2004, 248 (1-3),75.
54 Han S, Hou W, Xu J, et al.ChemPhysChem, 2006, 7 (2),394.
55 Lyu Y, Seung H Y, Jeong K S, et al.Journal of the American Chemical Society, 2004, 126 (8),2310.
56 Voort V D, Mathieu M, Mees F, et al. Journal of Physical Chemistry B,1998, 102,8847.
57 Kang H, Jun Y, Park J, et al. Cheminform, 2000, 12,3530.
58 Chen S,Wu D, Song C, et al. Materials Review A:Review Papers, 2013, 27(8),47.
陈思,吴东清,宋春芃,等. 材料导报:综述篇, 2013, 27(8), 47.
59 Chen Q R, Sakamoto Y, Terasaki O, et al. Microporous and Microporous Materials, 2007, 105 (1-2), 24.
60 Liang Y, Hanzlik M, Anwander R.Journal of Materials Chemistry, 2005, 15 (35-36),3919.

[1]	张甄, 王宝冬, 徐文强, 秦绍东, 孙琦. 黑色二氧化钛纳米材料研究进展[J]. 材料导报, 2019, 33(z1): 8-15.
[2]	张燕. 一步法制备无表面修饰剂花状金纳米颗粒及其表面增强拉曼散射性能研究[J]. 材料导报, 2019, 33(z1): 314-317.
[3]	高科, 李万万. 近红外二区光声成像造影剂的研究进展[J]. 材料导报, 2019, 33(z1): 481-484.
[4]	侯珊, 刘向春. 新型光催化剂钨酸锌的制备及性能改性研究进展[J]. 材料导报, 2019, 33(9): 1541-1549.
[5]	杨焜, 王春来, 丁晟, 刘长军, 田丰, 李钒. 荧光碳量子点:合成、特性及在肿瘤治疗中的应用[J]. 材料导报, 2019, 33(9): 1475-1482.
[6]	叶凯, 梁风, 姚耀春, 马文会, 杨斌, 戴永年. 直流电弧等离子体法制备纳米材料的研究进展[J]. 材料导报, 2019, 33(7): 1089-1098.
[7]	阮子林, 郝振亮, 张辉, 卢建臣, 蔡金明. Cu_2-xS(0≤x≤1)化合物:制备技术、物理特性及应用[J]. 材料导报, 2019, 33(7): 1141-1155.
[8]	陈娟, 江琦. 自组装技术在特殊形貌无机纳米材料制备中的作用[J]. 材料导报, 2019, 33(3): 454-461.
[9]	王亚斌, 郭敏, 史时辉, 呼科科, 张耀霞, 刘忠. 树枝状纤维形纳米球催化剂的研究进展[J]. 材料导报, 2019, 33(21): 3596-3605.
[10]	安文,马建中,徐群娜. 功能型酪素基复合材料的研究进展[J]. 材料导报, 2019, 33(15): 2602-2609.
[11]	张腾, 唐天宇, 侯仰龙. 面向锂硫电池的高负载量碳硫复合正极材料研究进展[J]. 材料导报, 2019, 33(1): 90-102.
[12]	管庆顺,李建,宋如愿,徐朝阳,吴伟兵,景宜,戴红旗,房桂干. 基于纳米材料的气凝胶制备及应用[J]. 《材料导报》期刊社, 2018, 32(3): 384-390.
[13]	刘云子,张伟,宋占永. 金属纳米颗粒导电墨水制备与后处理工艺的研究进展[J]. 《材料导报》期刊社, 2018, 32(3): 391-397.
[14]	宋晔, 缪远玲, 孟月东, 王奇. 利用等离子体技术制备和改性碳基纳米材料的研究进展[J]. 材料导报, 2018, 32(19): 3295-3303.
[15]	葛胜涛, 邓先功, 毕玉保, 王军凯, 李赛赛, 韩磊, 张海军. 多级孔材料研究进展[J]. 《材料导报》期刊社, 2018, 32(13): 2195-2201.

[1]	Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[2]	Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[3]	Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[4]	ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[5]	WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[6]	GUO Hongjian, JIA Junhong, ZHANG Zhenyu, LIANG Bunu, CHEN Wenyuan, LI Bo, WANG Jianyi. Microstructure and Tribological Properties of VN/Ag Films Fabricated by Pulsed Laser Deposition Technique[J]. Materials Reports, 2017, 31(2): 55 -59 .
[7]	WANG Wenjin, WANG Keqiang, YE Shenjie, MIAO Weijun, CHEN Zhongren. Effect of Asymmetric Block Copolymer of PI-b-PB on Phase Morphology and Properties of IR/BR Blends[J]. Materials Reports, 2017, 31(2): 96 -100 .
[8]	HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[9]	YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
[10]	TAN Cao, DUAN Hongjuan, WANG Junkai, ZHANG Haijun, LIU Jianghao. Preparation of ZrB₂ Ultrafine Powders via Molten-salt-mediated Magnesiothermic Reduction[J]. Materials Reports, 2017, 31(8): 109 -112 .

Viewed

Full text

Abstract

Cited

Shared

Discussed