Cr掺杂NiCo LDH/NF的制备及OER催化性能

doi:10.11896/cldb.25030003

材料导报

2026, Vol. 40

Issue (6): 25030003-5 https://doi.org/10.11896/cldb.25030003

金属与金属基复合材料

Cr掺杂NiCo LDH/NF的制备及OER催化性能

雷琬莹^*, 谭自强, 杨鑫鑫, 张新曙, 杜易, 李世盛, 高智

西安建筑科技大学材料科学与工程学院,西安 710055

Preparation of Cr Doped NiCo LDH/NF and Its OER Catalytic Performance

LEI Wanying^*, TAN Ziqiang, YANG Xinxin, ZHANG Xinshu, DU Yi, LI Shisheng, GAO Zhi

College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China

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摘要设计高效且经济的析氧反应(OER)电催化剂是当前电解水领域亟待解决的核心问题。本研究制备了一种原位生长于泡沫镍(NF)表面的Cr掺杂NiCo LDH(Cr-NiCo LDH)复合材料,其是由纳米线阵列组装形成的多级结构,有利于暴露更多的活性位点;Cr掺杂有助于NiCo LDH的近表面形成高价态离子(三价钴离子和三价镍离子),可以促进OER过程。其中,Cr-NiCo LDH-120/NF表现出最好的OER性能,在10和100 mA·cm^-2下的过电位分别为273 和329 mV,Tafel斜率为59.83 mV·dec^-1,并具有超过48 h的稳定性。本工作为开发高效的非贵金属电催化剂提供了新的思路。

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	雷琬莹
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	李世盛
	高智

关键词: 电解水析氧反应 NiCo LDH Cr掺杂

Abstract: A central topic in electrocatalysis is the development of an efficient and cost-effective electrocatalyst for the oxygen evolution reaction (OER). Herein, we developed a Cr-doped NiCo LDH (Cr-NiCo LDH) nanocomposites on nickel foam (NF). The resultant nanohybrid exhibits a hierarchical structure composed of numerous nanowires which facilitates the exposure of a large number of reactive sites. Cr doping benefits for the formation of high-valence ions (Co³⁺ and Ni³⁺) near the surface of the electrocatalyst. The Cr-NiCo LDH-120/NF electrocatalyst presents the outstanding OER performance, with the lowest overpotentials of 273 and 329 mV at current densities of 10 and 100 mA·cm^-2 respectively, the smallest Tafel slope of 59.83 mV·dec^-1, and a remarkable stability over 48 h. This work presents a new approach for rationally designing highly-efficient and non-noble metal electrocatalysts.

Key words: water electrolysis oxygen evolution reaction NiCo LDH Cr doping

出版日期: 2026-03-25 发布日期: 2026-04-03

ZTFLH:

TB331

基金资助: 国家自然科学基金(519002243); 陕西省自然科学基础研究计划(2024JC-YBQN-0155);陕西省教育厅重点科研计划(22JY039)

通讯作者: ^*雷琬莹,博士,西安建筑科技大学材料科学与工程学院副教授。主要从事低维纳米催化材料的设计与构建、裂解水和环境污染治理等方面的研究。leiwy@xauat.edu.cn

引用本文:

雷琬莹, 谭自强, 杨鑫鑫, 张新曙, 杜易, 李世盛, 高智. Cr掺杂NiCo LDH/NF的制备及OER催化性能[J]. 材料导报, 2026, 40(6): 25030003-5.
LEI Wanying, TAN Ziqiang, YANG Xinxin, ZHANG Xinshu, DU Yi, LI Shisheng, GAO Zhi. Preparation of Cr Doped NiCo LDH/NF and Its OER Catalytic Performance. Materials Reports, 2026, 40(6): 25030003-5.

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https://www.mater-rep.com/CN/10.11896/cldb.25030003 或 https://www.mater-rep.com/CN/Y2026/V40/I6/25030003

1 Kansal S, Rahul R, Anshu S, et al. ACS Sustainable Chemistry & Engineering, 2024, 12, 13511.
2 Jia F H, Wei X L, Bao W W, et al. Materials Reports, 2024, 38(4), 22040365(in Chinese).
贾飞宏, 卫学玲, 包维维, 等. 材料导报, 2024, 38(4), 22040365.
3 Shen Y, Zhang X L, Qu M R, et al. Nature Communications, 2024, 15, 7861.
4 Xue S, Zhou T, Wu P, et al. International Journal of Hydrogen Energy, 2024, 51, 1349.
5 Sun M, Wang J. Journal of Materials Chemistry A, 2023, 11, 21420.
6 Zhang Q, Xiao W, Fu H C, et al. ACS Catalysis, 2023, 13, 14975.
7 Singh B, Patel A K, Indra A. Materials Today Chemistry, 2022, 25, 100930.
8 Zhao Y, Dongfang N, Huang C, et al. Nature Communications, 2025, 16, 580.
9 Jin H, Lin D, Zhou L, et al. Scientific Reports, 2025, 15, 3480.
10 Fan R, Mu Q, Wei Z, et al. Journal of Materials Chemistry A, 2020, 8, 9871.
11 Qian Z X, Liang G H, Shen L F, et al. Journal of the American Chemical Society, 2024, 147, 1334.
12 Wu Y, Chen M, Sun H, et al. Applied Catalysis B:Environment and Energy, 2025, 360, 124548.
13 Chen Y, Yao H, Kong F, et al. Applied Catalysis B:Environmental, 2021, 297, 120474.
14 Zhang Z, Zhao H, Xi S, et al. Nature Communications, 2025, 16, 1301.
15 Niu H J, Ran N, Zhou W, et al. Journal of the American Chemical Society, 2025, 147, 2607.
16 Bera K, Karmakar A, Kumaravel S, et al. Inorganic Chemistry, 2022, 61, 4502.
17 Zhang Y, Zhang Z, Zhang X, et al. International Journal of Hydrogen Energy, 2025, 102, 304.
18 Xiao Z, Tang X, Gao F, et al. DeCarbon, 2025, 7, 100097.
19 Jamesh M I, Harb M. Journal of Energy Chemistry, 2021, 56, 299.
20 Qi Q, Zhang C, Hu J. Coordination Chemistry Reviews, 2025, 522, 216235.
21 Liu T, Lu J, Chen Z, et al. Chemical Engineering Journal, 2024, 496, 153719.
22 He W, Zhang R, Liu H, et al. Small, 2023, 19, 2301610.
23 Dhandapani H N, Mahendiran D, Karmakar A, et al. Journal of Materials Chemistry A, 2022, 10, 17488.
24 Zhang B J, Chang B, Qiu S P, et al. Rare Metals, 2024, 43, 2613.
25 Wang Z, Liu W, Hu Y, et al. Applied Catalysis B:Environmental, 2020, 272, 118959.
26 Xu D, Stevens M B, Rui Y, et al. Electrochimica Acta, 2018, 265, 10.
27 Gao X, Jia Z, Wang B, et al. Chemical Engineering Journal, 2021, 419, 130019.
28 Li T, Li G H, Li L H, et al. ACS Applied Materials & Interfaces, 2016, 8, 2562.
29 Kang H, He D, Yan X, et al. ACS Catalysis, 2024, 14, 5314.
30 Li W H, Lv J, Li Q, et al. Journal of Materials Chemistry A, 2019, 7, 10431.
31 Liu M, Min K A, Han B, et al. Advanced Energy Materials, 2021, 11, 2101281.
32 Wang H Y, Hsu Y Y, Chen R, et al. Advanced Energy Materials, 2015, 5, 1500091.
33 Gan J C, Jiang Z F, Fang K M, et al. Journal of Colloid and Interface Science, 2025, 677, 221.
34 Ren J T, Chen L, Tian W W, et al. Small, 2023, 19, 2300194.
35 Liang R, Zhang B, Du Y, et al. ACS Catalysis, 2023, 13, 8821.
36 Li L, Cao X, Huo J, et al. Journal of Energy Chemistry, 2023, 76, 195.
37 Ye P, Fang K, Wang H, et al. Nature Communications, 2024, 15, 1012.
38 Li S, Wang X, Tan S, et al. Fuel, 2017, 191, 511.
39 Marelli E, Gazquez J, Poghosyan E, et al. Angewandte Chemie International Edition, 2021, 60, 14609.
40 Chala S A, Tsai M C, Su W N, et al. ACS Nano, 2020, 14, 1770.
41 Ren J T, Chen L, Wang H Y, et al. Applied Catalysis B:Environment and Energy, 2024, 347, 123817.
42 Wang S, Wang T, Wang X, et al. International Journal of Hydrogen Energy, 2020, 45, 12629.
43 Teng L, Zhao L Journal of Electroanalytical Chemistry, 2023, 949, 1572.
44 Han B, Feng S C, Xu J, et al. Materials Reports, 2021, 35(14), 14001(in Chinese).
韩斌, 冯思琛, 徐俊, 等. 材料导报, 2021, 35(14), 14001.

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