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材料导报  2024, Vol. 38 Issue (19): 22120095-8    https://doi.org/10.11896/cldb.22120095
  金属与金属基复合材料 |
生物基MOFs衍生Co9S8/N,O-C电催化剂的析氧性能
柴瑞瑞, 桑欣欣*, 欧世国, 李家豪, 王大伟*
江南大学化学与材料工程学院合成与生物胶体教育部重点实验室,江苏 无锡 214122
Oxygen Evolution Performance of Bio-based MOFs Derived Co9S8/N, O-C Electrocatalysts
CHAI Ruirui, SANG Xinxin*, OU Shiguo, LI Jiahao, WANG Dawei*
The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China
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摘要 高性能氧析出反应(OER)催化剂对提高电解水性能至关重要。金属-有机框架(MOFs)衍生的金属-碳(M-C)材料因具有比表面积高、组成和结构易于调变等优势而被广泛用作OER催化剂。本工作制备以没食子酸为连接配体的钴-没食子酸MOFs材料(Co-gallate),通过配体交换合成钴-没食子酸@三聚硫氰酸(Co-gallate@TTCA),经高温碳化得到Co9S8/N,O-C电催化剂。在OER催化性能测试中,与Co-gallate直接碳化得到的Co/O-C相比,在电流密度为10 mA·cm-2时,Co9S8/N,O-C材料的过电位仅为270 mV,塔菲尔斜率为71.5 mV·dec-1,OER性能显著提升,且所合成的Co9S8/N,O-C材料具有良好的催化稳定性。本工作以廉价易得的生物基MOFs为牺牲模板,采用配体交换在MOFs结构中引入含N、S杂原子,通过改变碳化产物的组成和结构,有效提升电催化剂的催化活性和动力学性能。
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柴瑞瑞
桑欣欣
欧世国
李家豪
王大伟
关键词:  没食子酸  金属-有机框架  Co9S8  析氧反应  电解水    
Abstract: It is crucial to develop efficent oxygen evolution reaction (OER) catalysts for improving the performance of water-splitting devices. Metal-organic frameworks (MOFs)-derived metal-carbon (M-C) materials are widely used as OER catalysts due to their high specific surface area, easy adjustment of composition and structure. In this work, cobalt-gallic acid MOFs (Co-gallate) were assembled from gallic acid as the organic linkers. Via ligands exchange of thiocyanuric acid (TTCA), Co-gallate@TTCA was prepared. After carbonization of Co-gallate@TTCA, Co9S8/N, O-C electrocatalyst was obtained and the OER catalytic performance was evaluated. Compared with Co/O-C prepared by direct carbonization of Co-gallate, the overpotential of Co9S8/N, O-C material was only 270 mV with a Tafel slope of 71.5 mV·dec-1 at a current density of 10 mA·cm-2, and the OER performance was significantly improved. Moreover, the synthesized Co9S8/N, O-C material exhibits long-term catalytic stability. In this work, a readily available bio-based MOF was used as a sacrificial template, and N and S-containing ligands were introduced into the MOFs structure through ligand exchange. By changing the composition and structure of the carbonized products, the catalytic activity and kinetic performance of the catalysts are effectively improved.
Key words:  gallic acid    metal-organic frameworks    Co9S8    oxygen evolution reaction    water splitting
出版日期:  2024-10-10      发布日期:  2024-10-23
ZTFLH:  TQ426  
基金资助: 国家自然科学基金(21803025)
通讯作者:  *桑欣欣,通信作者,江南大学化学与材料工程学院副教授、硕士研究生导师。2010年济南大学应用化学专业本科毕业,2016年中国科学院化学研究所材料学专业博士毕业后到江南大学工作至今。目前主要从事金属-有机框架材料、非均相催化反应等方面的研究工作。发表论文20余篇,包括Nature Communications、Green Chemistry、ACS Sustainable Chemistry & Engineering等。
王大伟,通信作者,江南大学化学与材料工程学院教授、博士研究生导师,上海市化学化工学会副秘书长。2009年于中国科学院大连化学物理研究所获得博士学位,后加入美国西弗吉尼亚大学(West Virginia University)从事博士后研究。2012年6月进入江南大学工作,目前主要从事多氮配体的设计合成及在借氢催化反应中的应用方面的研究工作。在Journal of the American Chemical Society、Green Chemistry、Chemical Engineering Journal等发表80余篇SCI论文。sangxx@jiangnan.edu.cn;wangdw@jiangnan.edu.cn   
作者简介:  柴瑞瑞,2020年6月毕业于山东农业大学,获得理学学士学位。现为江南大学化学与材料工程学院硕士研究生,主要研究领域为金属-有机框架衍生碳材料的制备及应用。
引用本文:    
柴瑞瑞, 桑欣欣, 欧世国, 李家豪, 王大伟. 生物基MOFs衍生Co9S8/N,O-C电催化剂的析氧性能[J]. 材料导报, 2024, 38(19): 22120095-8.
CHAI Ruirui, SANG Xinxin, OU Shiguo, LI Jiahao, WANG Dawei. Oxygen Evolution Performance of Bio-based MOFs Derived Co9S8/N, O-C Electrocatalysts. Materials Reports, 2024, 38(19): 22120095-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22120095  或          http://www.mater-rep.com/CN/Y2024/V38/I19/22120095
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