Abstract: The polycrystalline cubic boron nitride (PcBN) composites were sintered for 20 min at high temperature (1 500 ℃) under high pressure (5 GPa) using cubic boron nitride, Ti, Al and Si powders as raw materials. The X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and X-ray dispersive energy dispersive spectroscopy (EDS) were performed to study the phase, microstructure and element distrubiton of the samples. Simultaneously, the porosity, relative density, flexural strength and hardness of the samples were also inveitigated. The characterization results indicated that the new phase emerged in the cBN-Ti-Al-Si system were TiB2, AlN, TiSi2, Ti5Si3 and Si3N4. In addition, when the Si content was 15wt%, PcBN presented the best comprehensive performance, where the porosity, relative density, hardness and bending strength were 0.21%,98.5%,34.58 GPa and 799 MPa, respectively. However, when the Si content was increased to 20wt%, the corresponding performance of PcBN will be decreased rapidly.
莫培程, 吴一, 于文霖, 王吉林, 邹正光, 钟生林, 王鹏. cBN-Ti-Al-Si原位合成PcBN复合材料及其力学性能[J]. 《材料导报》期刊社, 2018, 32(14): 2355-2359.
MO Peicheng, WU Yi, YU Wenlin, WANG Jilin, ZOU Zhengguang, ZHONG Shenglin, WANG Peng. In Situ Synthesis of PcBN Composites by cBN-Ti-Al-Si and Their Mechanical Property. Materials Reports, 2018, 32(14): 2355-2359.
1 Chen Y J, Wang H K, Peng J, et al. Production methods and application of polycrystalline cubic boron nitride[J]. Diamond Abrasives and Engineering,2015,35(2):74(in Chinese). 陈永杰,王海阔,彭进,等.聚晶立方氮化硼的制备方法及应用进展[J].金刚石与磨料磨具工程,2015,35(2):74. 2 Zhao X L. New polycrystalline cubic boron nitride (PcBN) cutting tool material development and its mechanism[D]. Jinan: Shandong University,2011(in Chinese). 赵兴利.新型聚晶立方氮化硼(PcBN)刀具材料研制及其切削机理研究[D].济南:山东大学,2011. 3 Ren Z H. Preparation and characterization of low melting vitrified bond cBN composites by pressureless sintering[D]. Zhengzhou: Zhengzhou University,2010(in Chinese). 任振火.常压下低融结合剂cBN复合材料的制备与性能表征[D].郑州:郑州大学,2010. 4 Liu Y J, He D W, Wang P, et al. Microstructural and mechanical properties of cBN-Si composites prepared from the high pressure infiltration method[J]. International Journal of Refractory Metals and Hard Materials,2016,61:1. 5 Zhang L L, Kou Z L, Xu C, et al. Sintering behaviors of fine-grained cBN-10wt.% Al3.21Si0.47 system under high pressure[J]. Diamond & Related Materials,2012,29:84. 6 Li D, Liu J, Hu J, et al. Performance and application of polycrystalline cubic boron nitride[J]. Journal of Tool Technology,2006(12):11(in Chinese). 李丹,刘进,胡娟,等.聚晶立方氮化硼材料的性能及其应用[J].工具技术,2006(12):11. 7 Mettaya Kitiwan,Akihiko Ito,Jiangfeng Zhang,et al. Densification and mechanical properties of cBN-TiN-TiB2 composites prepared by spark plasma sintering of SiO2-coated cBN powder[J].Journal of the European Ceramic Society,2014,34:3619. 8 Jiang W, Zhou W N, Ling F. Sintered cBN-Ti-B-Al-SiC under high temperature and high pressure[J]. Journal of Superhard Material Engineering,2010,22(4):24(in Chinese). 姜伟,周卫宁,林峰.cBN-Ti-B-Al-SiC系在高温高压下的烧结[J].超硬材料工程,2010,22(4):24. 9 Yu L,Zi L K,Wang H K,et al. High pressure sintering behavior and mechanical properties of cBN-Ti3Al and cBN-Ti3Al-Al composite materials[J].High Pressur Reserearch,2012,32(4):524. 10 Rong X Z, Tsurumi T, Fukunaga O, et al. High-pressure sintering of cBN-TiN-Al composite for cutting tool application[J]. Diamond and Related Materials,2002,11(2):280. 11 Zhao Y C, Wang M Z. Interaction of Al and cBN under high tempe-rature and high pressure[J]. Journal of Inorganic Materials,2008,23(2):253(in Chinese). 赵玉成,王明智.Al与cBN在高温高压下的相互作用[J].无机材料学报,2008,23(2):253. 12 Yuan Y G, Cheng X Z, Chang R, et al. Reactive sintering cBN-Ti-Al composites by spark plasma sintering[J]. Diamond & Related Materials,2016,69:138. 13 Klimczyk P, Benko E, Lawniczak-Jablonska K, et al. Cubic boron nitride-Ti/TiN composites: Hardness and phase equilibrium as function of temperature[J]. Journal of Alloys and Compounds,2004,382(2004):195. 14 Wang Y F. High toughness polycrystalline cubic boron nitride (PcBN) compound preparation technology and performance study[D]. Zhengzhou: Henan University of Technology,2012(in Chinese). 王勇峰.高韧性聚晶立方氮化硼(PcBN)复合片制备技术及性能研究[D].郑州:河南工业大学,2012. 15 Xue Y. Interaction of cBN and bonds in PcBN[D]. Qinhuangdao: Yanshan University,2008(in Chinese). 薛勇.PcBN中cBN与结合剂的相互作用研究[D].秦皇岛:燕山大学,2008. 16 Liu W Y. Fabrication and characterization of porous product cera-mics with high porosity and high strength[D]. Beijing: Tsinghua University,2009(in Chinese). 刘伟渊.高气孔率、高强度多孔氧化铝陶瓷的制备及表征[D].北京:清华大学,2009. 17 Zhang C P, Gao X W, Ru H Q, et al. Effect of forming pressure on microstructure and mechanical properties of SiC/TiB2 composites[J]. Journal of Inorganic Materials,2017,32(5):502(in Chinese). 张翠萍,高向伟,茹红强,等.成形压力对SiC/TiB2复合材料组织与性能的影响[J].无机材料学报,2017,32(5):502. 18 Hu H L, Yao D X, Xia Y F, et al. Mechanical properties of reaction-bonded Si3N4/SiC composite ceramics[J]. Journal of Inorganic Materials,2014,29(6):594(in Chinese). 胡海龙,姚冬旭,夏咏锋,等.反应烧结制备Si3N4/SiC复相陶瓷及其力学性能研究[J].无机材料学报,2014,29(6):594.